Abstract: A system for transporting perishable goods. The system for transporting perishable goods provides a perishable goods transportation device for containing and transporting perishable goods having a phase change material (PCM) disposed in a first thermodynamic state disposed therein, a heat source, at least one passive electromotive force (EMF) generator, and a PCM re-constitution system operably coupled to the PCM.

Abstract: Aqueous solutions of halogenides (oxyhalides) of zirconium and hafnium (M) with values of ?=X/M near one, for X=Cl, Br and I form amorphous solids or glasses, designated as M,X, in contrast to important crystalline oxyhalide end members with ?=2 (designated as MOX). The present disclosure describes methods for producing amorphous thin films comprising halogenides upon evaporation, and provides some measured physical properties, with attention to compositions for ?<2. The value of a below which only glasses are formed is about one for oxychlorides and oxybromides of both Zr and Hf. The chemical formulas for all the halogenide thin films prepared as noted above can be written as a function of the single parameter ?, according to M(OH)4-?X?.(4?-1)H2O. This is valid for e.g., crystalline zirconium oxychloride octahydrate, and for the glassy solids found for ?<2 and down to the onset of hydrolysis, ??0.5.

Abstract: Aqueous solutions of halogenides (oxyhalides) of zirconium and hafnium (M) with values of ?=X/M near one, for X=Cl, Br and I form amorphous solids or glasses, designated as M,X, in contrast to important crystalline oxyhalide end members with ?=2 (designated as MOX). The present disclosure describes methods for producing amorphous thin films comprising halogenides upon evaporation, and provides some measured physical properties, with attention to compositions for ?<2. The value of a below which only glasses are formed is about one for oxychlorides and oxybromides of both Zr and Hf. The chemical formulas for all the halogenide thin films prepared as noted above can be written as a function of the single parameter ?, according to M(OH)4-?X?.(4?-1)H2O. This is valid for e.g., crystalline zirconium oxychloride octahydrate, and for the glassy solids found for ?<2 and down to the onset of hydrolysis, ??0.5.

Abstract: Methods for making brines may generally comprise forming a mixture comprising: (i) a solid material produced as a by-product of the Kroll process including solid anhydrous magnesium chloride and solid elemental magnesium; (ii) an amount of a previously-produced brine; and (iii) an amount of water sufficient to provide a predetermined brine concentration. At least a portion of the solid material in the mixture is dissolved while simultaneously controlling the temperature of the mixture. At least a portion of insoluble matter is separated from the mixture.

Abstract: Methods for making brines may generally comprise forming a mixture comprising: (i) a solid material produced as a by-product of the Kroll process including solid anhydrous magnesium chloride and solid elemental magnesium; (ii) an amount of a previously-produced brine; and (iii) an amount of water sufficient to provide a predetermined brine concentration. At least a portion of the solid material in the mixture is dissolved while simultaneously controlling the temperature of the mixture. At least a portion of insoluble matter is separated from the mixture.

Abstract: A table with a working surface has a parallel rail on each side of the working surface. A slide assembly includes a shaft with ends and a pair of brackets. Each bracket has a hole. The holes receive the ends of the shaft. The slide assembly includes cylindrical tunnels. The tunnels slidably receive the rails. An operating assembly has primary and secondary arms. Each arm has a free exterior end and an interior portion. The interior portion is coupled to the shaft. A router is secured to, and depends from, the free end of the secondary arm. Control mechanisms include a scribe. The scribe is secured to, and depends from, the free end of the primary arm. Movement of the primary arm and scribe with respect to a template will cause corresponding movement of the secondary arm and router with respect to work pieces to be routed.

Abstract: A method is provided to optimize separation of zirconium from hafnium by extraction of a feed mix including (Zr+Hf)OCl2 with a thiocyanate-containing organic phase. The method includes maintaining the TA/MO2 ratio in a range from greater than about 2.55 to about 3.5.

Abstract: A method is provided to optimize separation of zirconium from hafnium by extraction of a feed mix including (Zr+Hf)OCl2 with a thiocyanate-containing organic phase. The method includes maintaining the TA/MO2 ratio in a range from greater than about 2.55 to about 3.5.

Abstract: A process for providing a zirconium basic sulfate includes providing a zirconium oxychloride solution, and then dialyzing the solution against a liquid selected from water and an aqueous solution across at least one anion exchange membrane to provide a dialyzate and diffusate. The dialyzate includes at least 90 percent of the zirconium ions of the zirconium oxychloride chloride solution and has a total acidity that is lower than the original zirconium oxychloride solution. A precipitate including zirconium basic sulfate may be formed from at least a portion of the diffusate. The zirconium oxychloride solution may be provided, for example, by dissolving zirconium tetrachloride in one of water and a hydrochloric acid solution. A material including zirconium basic sulfate produced by the process of the invention also is disclosed.

Abstract: Soluble zirconium and hafnium organic acid complexes are made by forming an aqueous mixture of a basic carbonate of either zirconium or hafnium and the organic acid such a propionic acid. The molar ratio of the organic acid to metal in the carbonate is greater than about 1.5. The mixture is heated with stirring to form the complex which is then recovered as a dry, free-flowing powder.

Abstract: An improved carbochlorination process for the production of volatile metal chlorides is disclosed. When chlorine gas contacts a metal oxide or a mixed metal oxide in a reaction zone in the presence of carbon at elevated temperatures, an undesirable carbochlorination residue forms containing carbon in the reaction zone. After the build-up of a carbochlorination residue in the reaction zone occurs, the volume of the carbochlorination residue in the reaction zone is reduced by periodically introducing just chlorine and metal oxide or mixed metal oxide reactants into the reaction zone without introducing any additional carbon. These components react with a portion of the carbon in the carbochlorination residue so as to reduce the amount of the residue.

Abstract: Niobium dioxide is produced by heating particulate niobium nitride in an oxygen atmosphere at a temperature above the melting point of niobium dioxide. The product obtained predominantly contains niobium dioxide.

Abstract: A process for the recovery of metal carbides from ferroalloys and nickel alloys of niobium, tantalum, vanadium, and hydrides thereof is disclosed. The selected ferroalloy or nickel alloy is contacted with a hydrogen containing gas, subdivided, and carbided by contact with a hydrocarbon containing gas at a temperature above 500.degree. C. The carbided reaction product is then leached with an aqueous acid solution for recovery.

Abstract: A process for making metal oxides including niobium or tantalum oxides from ferro and nickel alloys containing these metals involving the multiple steps of hydriding the ferro or nickel alloy selected, under conditions of suitable temperature and pressure to render the alloys friable, subdividing the hydrided product into selected particle sizes, then nitriding with a nitrogen-containing gas at elevated temperatures above 500.degree. C. to form the alloy constituent nitrides, thereafter leaching the nitrides formed with aqueous acid to separate the formed ferro or nickel nitride from the acid soluble nitrides from the acid insoluble nitrides, calcining the acid insoluble nitrides with oxygen-containing gas under conditions suitable for the formation of the metal oxide of the acid soluble nitride.

Abstract: A process for preparing metal oxides from ferrometal and nickel metal alloys is disclosed comprising first providing a ferrometal or nickel metal alloy containing an oxide forming metal, hydriding the alloy to an effective temperature and pressure with hydrogen containing gas, subdividing then carbiding the hydrided product at a temperature above about 500.degree. C. to form carbides, then employing an aqueous acid leach to dissolve the iron or nickel carbide and separating the acid soluble from the acid insoluble carbides. The acid insoluble carbides are reacted with oxygen at an elevated temperature for a time sufficient to form the metal oxides of said carbides.

Abstract: The process for removing tantalum values from niobium values wherein a NbCl.sub.5 /TaCl.sub.5 charge mixture having a molar ratio from about 10/1 to about 10,000/1 is mixed with a 8N to 20N aqueous HCl solution at a total charge concentration of from about 50 to about 150 parts/100 parts by weight of the HCl solution to form a hydrolysis system, and wherein at least the surface of the hydrolysis system is contacted with air or a gas-containing air for a period of time within which a precipitate settles out at an average rate of from about 0.1 to about 6.0% by weight of the initial solids charge per hour.

Abstract: The process for purifying a contaminated chloro, bromo or iodo precursor salt of zirconium, hafnium or aluminum by means of providing a molten thermal body of one or more alkali or alkaline earth metal halides and the precursor salt containing impurities, maintaining the body at a temperature sufficient to volatilize the precursor salt away from its impurities while effecting a reducing condition in the body by means of a fluid, mobile reducing agent which is non-reducing of said precursor salt, and isolating the purified volatilized precursor salt from the body. The ultra purified isolated volatilized precursor salt can then be reacted with a fluorinating agent to produce the highly purified fluoride for use in optical fiber grade glass or the like.