Abstract: The invention provides a process for producing polyurethane foams or hydrogels, in which compositions including A) isocyanate-functional prepolymers obtainable by the reaction of A1) low molecular weight diisocyanates of molar mass from 140 to 278 g/mol, with A2) polyalkylene oxides having an OH functionality of two or more, A3) more than 1% by weight of C2 to C12 diols based on total amount of isocyanate-reactive components wherein component A3) differs from component A2), B) water or a nonaqueous isocyanate-reactive component in an amount of at least 2% by weight, based on the total weight of the composition are provided, optionally foamed and cured wherein the isocyanate containing components do not exceed a residual diisocyanate content of 8% by weight, based on the total amount of the polyurethane foam or hydrogel. These foams or hydrogels are used in wound dressings, cosmetic articles or incontinence products.

Abstract: Polyurethane coating compositions are disclosed that include an isocyanate-reactive component that includes a polycyclic polyether polyol that is the reaction product of a reaction mixture that includes a polycyclic polyol starter, and an alkylene oxide, as well as an isocyanate-functional component that includes a non-aromatic polyisocyanate. The polyurethane coating compositions may be particularly useful as a gel coat in the manufacture of glass fiber reinforced plastics.

Abstract: Provided is a process for producing a polyisocyanurate comprising: trimerizing an aliphatic polyisocyanate with a trimerization catalyst in the presence of a thermally decomposable acid at a molar ratio of acid to catalyst of from 0.1 to 10, wherein the polyisocyanurate has a greater pot life than the pot life of the polyisocyanurate not containing the thermally decomposable acid. Polyisocyanurates made according to the inventive process lengthen the pot life of pultrusion composite formulations made therefrom without affecting the reactivity of the formulations.

Abstract: A method for simulating oligomer or polymer growth includes: receiving a reaction recipe including a plurality of reactive molecules; for each reactive molecule of the plurality of reactive molecules, determining at least one functional group associated with the reactive molecule; assigning a functional group type to each of the functional groups associated with the plurality of reactive molecules; determining at least one reaction rule associated with each functional group type; simulating a plurality of oligomer or polymer forming reactions from the plurality of reactive molecules based on the at least one reaction rule to form a plurality of simulated oligomers or polymers; and determining at least one oligomer or polymer structure associated with a first oligomer or polymer of the plurality of simulated oligomers or polymers.

Abstract: Provided is a process for producing a polyisocyanurate comprising: trimerizing an aliphatic polyisocyanate with a trimerization catalyst in the presence of a thermally decomposable acid at a molar ratio of acid to catalyst of from 0.1 to 10, wherein the polyisocyanurate has a greater pot life than the pot life of the polyisocyanurate not containing the thermally decomposable acid. Polyisocyanurates made according to the inventive process lengthen the pot life of pultrusion composite formulations made therefrom without affecting the reactivity of the formulations.

Abstract: A system, method, and computer program product for predicting a polymer. A method may include determining one or more prediction scores for a target polymer based on at least one descriptor of the target polymer from at least three descriptor groups, wherein the one or more prediction scores include a prediction of one or more physical properties for the target polymer. A method may include determining one or more prediction scores for a target polymer based on at least one desired physical property of the target polymer, wherein the one or more prediction scores include a prediction of one or more raw materials of the target polymer.

Abstract: Polyurethane coating compositions are disclosed that include an isocyanate-reactive component that includes a polycyclic polyether polyol that is the reaction product of a reaction mixture that includes a polycyclic polyol starter, and an alkylene oxide, as well as an isocyanate-functional component that includes a non-aromatic polyisocyanate. The polyurethane coating compositions may be particularly useful as a gel coat in the manufacture of glass fiber reinforced plastics.

Abstract: Disclosed are seed treatment compositions that include: (a) an aqueous polyurethane dispersion; and (b) an insecticide, a fungicide, a nematicide, and/or other pesticides. Also disclosed are seeds treated with such a treatment compositions and methods for treating a seed using such treatment composition.

Abstract: Disclosed are seed treatment compositions that include: (A) an aqueous polyurethane dispersion; and (B) an insecticide, a fungicide, a nematicide, and/or other pesticides. Also disclosed are seeds treated with such a treatment compositions and methods for treating a seed using such treatment composition.

Abstract: Disclosed are methods for treating seeds with a seed treatment composition that includes: (A) an aqueous polyurethane dispersion; and (B) an insecticide, a fungicide, a nematicide, and/or other pesticides. Also disclosed are seeds treated with such a treatment compositions and methods for treating a seed using such treatment composition.

Abstract: The present invention provides a composition comprising an isocyanate, and a functional chemical, wherein the functional chemical is attached to the isocyanate at an active hydrogen atom of the functional chemical. The present invention offers a way of assuring that the isocyanate-attached functional chemical is released slowly over time at any stage of the oil and gas well lifecycle.

Abstract: The present invention provides for the use of polyurethane dispersions to adhere functional chemicals on to proppants. The present invention offers a way of assuring that the chemical is released in the formation and is released slowly over time.

Abstract: Disclosed are seed treatment compositions that include: (A) an aqueous polyurethane dispersion; and (B) an insecticide, a fungicide, a nematicide, and/or other pesticides. Also disclosed are seeds treated with such a treatment compositions and methods for treating a seed using such treatment composition.

Abstract: Disclosed are seed treatment compositions that include: (a) an aqueous polyurethane dispersion; and (b) an insecticide, a fungicide, a nematicide, and/or other pesticides. Also disclosed are seeds treated with such a treatment compositions and methods for treating a seed using such treatment composition.

Abstract: Disclosed are methods for treating seeds with a seed treatment composition that includes: (A) an aqueous polyurethane dispersion; and (B) an insecticide, a fungicide, a nematicide, and/or other pesticides. Also disclosed are seeds treated with such a treatment compositions and methods for treating a seed using such treatment composition.

Abstract: The present invention provides water swellable one-component sealants prepared by incorporation of polyols containing ethylene oxide (“EO”) into the backbone of the polymer. The inventive one-component hydrophilic polyurethane sealant contains a silane-terminated polyurethane prepolymer, a compound having an ethylene oxide content of at least about 40 wt. %, based on the weight of the compound and a catalyst, optionally, one or more of plasticizers, fillers, pigments, drying agents, light stabilizers, antioxidants, thixotropic agents and bonding agents. The one-component hydrophilic polyurethane sealant increases at least about 1.4% by weight and at least about 2.5% by volume upon exposure to water for 24 hours and are capable of curing in a high humidity environment (including underwater) without foaming and maintain physical characteristics such as hardness.

Abstract: The present invention provides compositions such as a polymer grout, a molded plastic part, a void-filling plastic material, a concrete-anchoring material and a polymeric casting made from a thermosetting polymer chosen from vulcanized rubbers, polyoxybenzylmethylen-glycolanhydride (“Bakelite”), novolac resins, resole phenolic resins, duroplast, bismaleimide resins, polyimide resins, melamine, acrylic resins, polyester resins, cyanate ester resins, phenolic triazine resins, paracyclophane resins and epoxy resins and at least one phase change material (“PCM”). The compositions of the present invention have a lowered exotherm compared to compositions made from the same thermosetting polymer without the addition of a phase change material. Also provided are improved processes for producing the inventive compositions.

Abstract: The present invention provides water swellable one-component sealants prepared by incorporation of polyols containing ethylene oxide (“EO”) into the backbone of the polymer. The inventive one-component hydrophilic polyurethane sealant contains a silane-terminated polyurethane prepolymer, a compound having an ethylene oxide content of at least about 40 wt. %, based on the weight of the compound and a catalyst, optionally, one or more of plasticizers, fillers, pigments, drying agents, light stabilizers, antioxidants. thixotropic agents and bonding agents. The one-component hydrophilic polyurethane sealant increases at least about 1.4% by weight and at least about 2.5% by volume upon exposure to water for 24 hours and are capable of curing in a high humidity environment (including underwater) without foaming and maintain physical characteristics such as hardness.

Abstract: The present invention provides compositions such as a polymer grout, a molded plastic part, a void-filling plastic material, a concrete-anchoring material and a polymeric casting made from a thermosetting polymer chosen from vulcanized rubbers, polyoxybenzylmethylen-glycolanhydride (“Bakelite”), novolac resins, resole phenolic resins, duroplast, bismaleimide resins, polyimide resins, melamine, acrylic resins, polyester resins, cyanate ester resins, phenolic triazine resins, paracyclophane resins and epoxy resins and at least one phase change material (“PCM”). The compositions of the present invention have a lowered exotherm compared to compositions made from the same thermosetting polymer without the addition of a phase change material. Also provided are improved processes for producing the inventive compositions.

Abstract: The present invention provides processes for infrastructure repairs and geo-stabilization with a low-exotherm polyurethane foam, grout or elastomer. The inventive process involves at least partially filling a cavity in the infrastructure or earth with a low-exotherm polyurethane foam, grout or elastomer made from at least one polyisocyanate, at least one isocyanate-reactive compound and an organic particulate material capable of absorbing heat, optionally in the presence of one or more chosen from water, surfactants, pigments, catalysts, alkali silicates and fillers and curing the polyurethane foam, grout or elastomer. The inventive processes may improve the repair of buildings, foundations, roads, bridges, highways, sidewalks, tunnels, manholes, sewers, sewage treatment systems, water treatment systems, reservoirs, canals, irrigation ditches, etc.