Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces forming cube corner cavities. A reflective film is disposed at least on the recessed faces, and a fill material fills the cube corner cavities. The fill material comprises radiation-curable materials, adhesives, or both, and preferably transparent radiation-curable pressure-sensitive adhesives. The fill material preferably forms a continuous layer covering both the recessed faces and upper portions of the structured surface. A transparent cover layer preferably contacts the fill material layer.

Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces forming cube corner cavities. A reflective film is disposed at least on the recessed faces, and a fill material fills the cube corner cavities. The fill material comprises radiation-curable materials, adhesives, or both, and preferably transparent radiation-curable pressure-sensitive adhesives. The fill material preferably forms a continuous layer covering both the recessed faces and upper portions of the structured surface. A transparent cover layer preferably contacts the fill material layer.

Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces and top surfaces, the recessed faces forming cube corner cavities. The recessed faces have a high specular reflectivity, while the top surfaces have a low specular reflectivity. In some embodiments a substantially continuous film of reflective material covers the structured surface, and a masking substance is provided over the reflective material at the top surfaces. Alternatively, the top surfaces are given a non-smooth surface finish so that the film of reflective material on those portions has a diffuse reflectivity. In other embodiments the film of reflective material is discontinuous, disposed selectively on the recessed faces and not on the top surfaces. A cover layer is also provided, and can bond at least to the top surfaces. Keeping the top surfaces substantially free of reflective material inhibits corrosion and can enhance the bond integrity.

Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces and top surfaces, the recessed faces forming cube corner cavities. The recessed faces have a high specular reflectivity, while the top surfaces have a low specular reflectivity. In some embodiments a substantially continuous film of reflective material covers the structured surface, and a masking substance is provided over the reflective material at the top surfaces. Alternatively, the top surfaces are given a non-smooth surface finish so that the film of reflective material on those portions has a diffuse reflectivity. In other embodiments the film of reflective material is discontinuous, disposed selectively on the recessed faces and not on the top surfaces. A cover layer is also provided, and can bond at least to the top surfaces. Keeping the top surfaces substantially free of reflective material inhibits corrosion and can enhance the bond integrity.

Abstract: Retroreflective sheeting includes a body layer having a structured surface with recessed faces forming cube corner cavities. A reflective film is disposed at least on the recessed faces, and a fill material fills the cube corner cavities. The fill material comprises radiation-curable materials, adhesives, or both, and preferably transparent radiation-curable pressure-sensitive adhesives. The fill material preferably forms a continuous layer covering both the recessed faces and upper portions of the structured surface. A transparent cover layer preferably contacts the fill material layer.

Abstract: A durable colored article having fluorescent properties comprises a substantially solventless polyvinyl chloride matrix, a thioxanthene fluorescent dye, and a secondary or tertiary hindered amine light stabilizer having a molecular weight less than about 1000 grams/mole. The invention has the advantage in that it provides a flexible polyvinyl chloride film that exhibits durable fluorescent colors.

Abstract: Microstructured articles of the invention comprising, in order: a) a retroreflective microstructured member; b) a sealing layer melt-bonded to the microstructured member; and c) a backing member. The backing member is a fibrous web comprising a plurality of multifilament strands and is melt-bonded to the second surface of the sealing layer.

Abstract: A retroreflective article 10 has a body portion 14 and a multitude of cube-corner elements 12 that project from a rear side 20 of the body portion 14. The body portion 14 includes a body layer 18 that contains a light-transmissible polymeric material having an elastic modulus less than 7.times.10.sup.8 pascals. The cube-corner elements 12 contain a light transmissible polymeric material having an elastic modulus greater than 16.times.10.sup.8 pascals. A retroreflective article of this construction can be highly flexed while maintaining good retroreflective performance.

Abstract: A process and article for a retroreflective polymeric coated flexible fabric material having a retroreflective layer and a polymeric compatibilizing layer welded to a polymeric coated outer surface of a flexible fabric material. The compatibilizing layer provides an intermediate layer between the retroreflective layer and the flexible fabric material creating suitable bond strength between dissimilar polymers.

Abstract: A retroreflective article 10 has a body portion 14 and a multitude of cube-comer elements 12 that project from a rear side 20 of the body portion 14. The body portion 14 includes a body layer 18 that contains a light-transmissible polymeric material having an elastic modulus less than 7.times.10.sup.8 pascals. The cube-corner elements 12 contain a light transmissible polymeric material having an elastic modulus greater than 16.times.10.sup.8 pascals. A retroreflective article of this construction can be highly flexed while maintaining good retroreflective performance.

Abstract: A retroreflective article (30, 50) has opaque pigment particles (38, 58) dispersed in a retroreflective region (33, 53) of a front portion (35, 55) of a sheeting (32, 52) that includes a body portion (34, 54) and a multitude of cube-corner elements (36, 56). The opaque pigment particles (38, 58) scatter white, yellow, or light brown light to allow the retroreflective article to demonstrate improved lightness and, if colored fluorescent, improved fluorescence. The improvement in lightness and fluorescence makes the retroreflective articles more conspicuous to persons during the daytime.

Abstract: Cube-corner type retroreflective articles which retroreflect infrared light but do not substantially retroreflect visible light. The cube-corner elements comprise a polymeric matrix selected to be highly transmissive to infrared light but substantially opaque to visible light.

Abstract: The present invention provides improved, flexible retroreflective articles based upon an optically clear, aliphatic polyurethane polymer. The aliphatic polymer has a plurality of hard chain segments of the formula--C(O)N(H)--C.sub.6 H.sub.10 --N(H)C(O)--.

Abstract: A retroreflective tubing adapted to be interwined among spokes of a wheel, comprising a core material, retroreflective microspheres attached to an outer surface of the core material, and a protective encapsulating material surrounding the microspheres. In a preferred embodiment, the cross section of the core material is U-shaped to maximize the retroreflective performance of the tubing, and the encapsulating material provides a multiplicity of sealed airspaces between the outer surface of the retroreflective microspheres and the inner surface of the encapsulating material.

Abstract: Retroreflective sheet material capable of retroreflecting light at high incidence angles is prepared by laminating retroreflective sheeting to a base sheet, slitting the laminated sheet assembly in an array of spaced discontinuous slits, and expanding the laminated sheet assembly so that openings occur at the slits and portions of the laminated sheet assembly between the slits bend out of the plane which they originally occupied.

Abstract: New methods for making "embedded-lens" retroreflective sheeting, and new forms of such sheeting, are provided. The new methods involve embedding microspheres into a web by continuously presenting a mass of the microspheres against the moving web and heating the web so as to soften at least an exterior stratum of the web, and adding a spacing layer to the microsphere-covered surface of the web. The microspheres are embedded on the average to less than 50 percent of their diameter, which has been found to cause the spacing layer to conform around a greater proportion of the back surface of individual microspheres and thereby position a greater portion of the specularly reflective layer carried on the spacing layer at the approximate focal point for light passed through the microspheres. Use of a preformed spacing layer also contributes to maintaining the spacing layer at a constant thickness around the back surface of the microspheres.

Abstract: New methods for making "embedded-lens" retroreflective sheeting, and new forms of such sheeting, are provided. The new methods involve embedding microspheres into a web by continuously presenting a mass of the microspheres against the moving web and heating the web so as to soften at least an exterior stratum of the web, and adding a spacing layer to the microsphere-covered surface of the web. The microspheres are embedded on the average to less than 50 percent of their diameter, which has been found to cause the spacing layer to conform around a greater proportion of the back surface of individual microspheres and thereby position a greater portion of the specularly reflective layer carried on the spacing layer at the approximate focal point for light passed through the microspheres. Use of a preformed spacing layer also contributes to maintaining the spacing layer at a constant thickness around the back surface of the microspheres.

Abstract: Reflective sheeting useful for application to a pesticide-impregnated animal collar, and animal collars made from the sheeting. The sheeting generally comprises a monolayer of transparent microspheres; specularly reflective material underlying the microspheres; a binder layer of polymeric binder material in which the microspheres are partially embedded; a carrier sheet stretchable about 10 percent or more before rupture, in which the portions of the microspheres protruding from the binder layer are embedded; a barrier layer underlying the binder layer, which sorbs plasticizers more slowly than the binder layer sorbs the plasticizers; and a layer of adhesive underlying the barrier layer.

Abstract: New methods for making "embedded-lens" retroreflective sheeting, and new forms of such sheeting, are provided. The new sheetings are retroreflective through an increased angular range, and also provide brighter overall retroreflectivity and other advantageous properties.