Abstract: Silylethynyl pentacenes and compositions containing silylethynyl pentacenes are disclosed. Exemplary pentacene compounds have 6,13-silylethynyl substitution with one or more groups (e.g., R, R? and R?) covalently bonded to each Si atom of the silylethynyl groups. Methods of making and using silylethynyl pentacenes and compositions containing silylethynyl pentacenes are also disclosed. Substrates and devices comprising the silylethynyl pentacenes and compositions are also disclosed.

Abstract: Silylethynyl pentacenes and compositions containing silylethynyl pentacenes are disclosed. Exemplary pentacene compounds have 6,13-silylethynyl substitution with one or more groups (e.g., R, R? and R?) covalently bonded to each Si atom of the silylethynyl groups. Methods of making and using silylethynyl pentacenes and compositions containing silylethynyl pentacenes are also disclosed. Substrates and devices comprising the silylethynyl pentacenes and compositions are also disclosed.

Abstract: A coated optical fiber adjusted to operate at a predetermined temperature range. The coated fiber includes an optical fiber, a first polymer coating generally concentrically surrounding the optical fiber and a second polymer coating generally concentrically surrounding the first polymer coating, wherein the first polymer coating includes substantially no coefficient of thermal expansion stresses when the optical fiber is placed at a lower end of the temperature range.

Abstract: A method for manufacturing a coated optical fiber including the step of determining a desired temperature operating range of a coated optical fiber having at least one critical limit. The intercoating delamination stresses at the critical limit of said temperature range are determined. A zero-stress temperature region using the critical limit and the delamination stresses is then selected. An optical fiber is provided and the optical fiber is coated with a first polymer coating. The first polymer coating is exposed to a source of actinic radiation, wherein the source of actinic radiation generates heat. A second polymer coating including a photopolymerizable composition is applied to the optical fiber directly on the first polymer coating. The second polymer coating is cured, where at the time the second polymer coating is cured the first polymer coating is at the zero-stress temperature region.

Abstract: A coated optical fiber adjusted to operate at a predetermined temperature range. The coated fiber includes an optical fiber, a first polymer coating generally concentrically surrounding the optical fiber and a second polymer coating generally concentrically surrounding the first polymer coating, wherein the first polymer coating includes substantially no coefficient of thermal expansion stresses when the optical fiber is placed at a lower end of the temperature range.

Abstract: A method for manufacturing a coated optical fiber including the step of determining a desired temperature operating range of a coated optical fiber having at least one critical limit. The intercoating delamination stresses at the critical limit of said temperature range are determined. A zero-stress temperature region using the critical limit and the delamination stresses is then selected. An optical fiber is provided and the optical fiber is coated with a first polymer coating. The first polymer coating is exposed to a source of actinic radiation, wherein the source of actinic radiation generates heat. A second polymer coating including a photopolymerizable composition is applied to the optical fiber directly on the first polymer coating. The second polymer coating is cured, where at the time the second polymer coating is cured the first polymer coating is at the zero-stress temperature region.

Abstract: An optical fiber element includes an optical fiber having a numerical aperture ranging from 0.08 to 0.34 and a protective coating affixed to the outer surface of the optical fiber. The protective coating has a Shore D .?.hardnees.!. .Iadd.hardness .Iaddend.value of 65 or more and remains on the optical fiber during connectorization so that the fiber is neither damaged by the blades of a stripping tool nor subjected to chemical or physical attack.