Abstract: An activated oxygen gas sensor element having an increased voltage output under rich gas conditions, short switching response and reduced internal resistance is produced by chemically treating the inner conductive catalyst electrode of the sensor element with an inorganic acid or acid salt and current activating the outer conductive catalyst electrode by applying a direct current to the sensor element, with the outer electrode as a cathode, while the outer electrode is at an elevated temperature and in the presence of a neutral or inert atmosphere. Air may be used as the atmosphere in contact with the outer electrode during the current activation provided that the sensor is subjected to a subsequent reheating step to provide the desired results.

Abstract: A shield for introducing fluid, such as the gas within the exhaust system of an internal combustion engine, to a sensing means such as a zirconium dioxide element of an oxygen concentration sensor. The shield forms a chamber which surrounds the element and contains a fluid diverter having a plurality of circumferential fluid receiving cavities adapted to divert a portion of fluid from a main stream of flow into a partially closed end of the chamber. The diverted fluid enters the chamber near the tip end of the zirconia element; the closely spaced chamber permits the fluid flow to be generally parallel to the surface of the element and directed from the tip end to the base or housing end of the element. The shield further contains an opening near the base of the element to permit fluid to exit the chamber.

Abstract: A solid electrolyte oxygen gas sensor element 1 comprises an electrolyte body 3 having electrodes 7 and 11 on the outer and inner surfaces 5 and 9 thereof, with the inner surface 9 having a protective means 13 thereon to protect the same from contact with oxygen or oxygen-containing gases so as to provide a substantially zero oxygen reference for the inner surface. The protective means 13 can comprise a coating, or a packing within a tubular electrolyte body, of carbon or a metal which forms an oxide that is stable at the operating temperature of the oxygen sensor element.

Abstract: An activated oxygen gas sensor element having an increased voltage output under rich gas conditions, short switching response and reduced internal resistance is produced by chemically treating the inner conductive catalyst electrode of the sensor element with an inorganic acid or acid salt and current activating the outer conductive catalyst electrode by applying a direct current to the sensor element, with the outer electrode as an anode, while the outer electrode is at an elevated temperature and in the presence of a nonoxidizing atmosphere.

Abstract: A closed loop integral control system for the air/fuel management of an internal combustion engine is disclosed. An oxygen sensor positioned in the exhaust gas of the internal combustion engine is biased with a constant current source to provide a signal indicative of the oxygen content of the exhaust gas over a significant range of air/fuel ratios. The signal waveform from the sensor is compared to a threshold value of a comparator to produce level changes in the comparator output depending on whether the output of the sensor is above or below the threshold. An integrator, receiving these level changes as commands to increase or decrease the fuel pulse widths, controls the air/fuel ratio of the engine in a limit cycle around a scheduled value. By changing the current bias on the sensor and thus modifying the unbiased waveform of the sensor to intercept the threshold value at various points different average air/fuel ratios are obtainable from the system.

Abstract: An oxygen gas sensor having a solid electrolyte oxygen gas sensor element, with an inner conductive catalyst electrode on the interior surface and an outer conductive catalyst electrode on the exterior surface thereof, which has a high voltage output and lower internal resistance is produced by chemically activating said inner conductive catalyst electrode with an inorganic acid or an acid salt. By also subjecting said outer conductive catalyst electrode to a direct current activation under a reducing atmosphere, even more improved properties, such as fast switching response, are achieved.

Abstract: A wide range combustion mixture air/fuel ratio sensor in which an electrochemical cell supplies hydrogen gas to a palladium sensor element at a rate regulated by the output of a Wheatstone bridge circuit incorporating the sensor element. This generated hydrogen gas combines with any oxygen present in the exhaust gas through catalytic action and also maintains the level of absorbed hydrogen, and therefore the electrical resistance of the palladium sensor element, at a preselected value. The magnitude of the current applied to the electrochemical cell necessary to maintain this balance is a measure of the combustion mixture air/fuel ratio.