Abstract: A composite metal membrane for use in hydrogen purification includes a body-centered cubic metal layer, one or more catalyst layers, and one or more hydrogen-permeable, intermetallic diffusion barriers deposited between the body-centered cubic metal layer and the one or more catalyst layers. The body-centered cubic metal layer can include a group 5 metal. The one or more hydrogen-permeable, intermetallic diffusion barriers can each include a group 4 nitride, which may be applied via reactive sputtering. The one or more catalyst layers can each include a platinum group metal. The composite metal membrane may be symmetric in configuration, with a first hydrogen-permeable, intermetallic diffusion barrier between the body-centered cubic metal layer and a first catalyst layer, and a second hydrogen-permeable, intermetallic diffusion barrier between the body-centered cubic metal layer and a second catalyst layer.

Abstract: The present invention relates to catalysts, methods of making catalysts, and methods of using catalysts, where the catalysts include: at least one of a transition metal and a transition metal oxide supported by yttria-stabilized zirconia (YSZ), where the transition metal is promoted by at least one of an alkali metal and an alkaline-earth metal.

Abstract: A catalytic membrane reactor and methods of operating and producing the same are provided that efficiently produces highly pure hydrogen (H2) from ammonia (NH3) as well as operates according to other chemical conversion processes. In one embodiment, a tubular ceramic support made from porous yttria-stabilized zirconia has an outer surface that is impregnated with a metal catalyst such as ruthenium and then plated with a hydrogen permeable membrane such as palladium. An inner surface of the ceramic support is impregnated with cesium to promote conversion of ammonia to hydrogen and nitrogen (N2). The resulting catalytic membrane reactor produces highly pure hydrogen at low temperatures and with less catalytic loading. Therefore, ammonia can be used to effectively transport hydrogen for use in, for example, fuel cells in a vehicle.

Abstract: The present invention relates to catalysts, methods of making catalysts, and methods of using catalysts, where the catalysts include: at least one of a transition metal and a transition metal oxide supported by yttria-stabilized zirconia (YSZ), where the transition metal is promoted by at least one of an alkali metal and an alkaline-earth metal.

Abstract: A catalytic membrane reactor and methods of operating and producing the same are provided that efficiently produces highly pure hydrogen (H2) from ammonia (NH3) as well as operates according to other chemical conversion processes. In one embodiment, a tubular ceramic support made from porous yttria-stabilized zirconia has an outer surface that is impregnated with a metal catalyst such as ruthenium and then plated with a hydrogen permeable membrane such as palladium. An inner surface of the ceramic support is impregnated with cesium to promote conversion of ammonia to hydrogen and nitrogen (N2). The resulting catalytic membrane reactor produces highly pure hydrogen at low temperatures and with less catalytic loading. Therefore, ammonia can be used to effectively transport hydrogen for use in, for example, fuel cells in a vehicle.

Abstract: The present invention relates to a method to synthesize ammonia at moderate conditions. The present invention also relates to a new chemical reactor configuration to achieve ammonia synthesis at moderate pressures and temperatures, and methods to make membranes for use in ammonia synthesis.

Abstract: The present invention relates to a method to synthesize ammonia at moderate conditions. The present invention also relates to a new chemical reactor configuration to achieve ammonia synthesis at moderate pressures and temperatures, and methods to make membranes for use in ammonia synthesis.

Abstract: This disclosure relates to palladium-alloyed membranes, and more specifically to palladium-alloyed membranes for high temperature applications and to methods for making and using the same.