Patents by Inventor James E. Spagnoli

James E. Spagnoli has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10774286
    Abstract: The present disclosure provides a grease composition with improved water resistance and mechanical stability at high-temperatures, including: at least one base oil; a water insoluble thickener; and a low molecular weight thixotropic polyamide composition having molecular weight distribution characteristics meeting the requirement described by the relationship: ( A + D ) ( B + C ) ? 0.05 where A=the % mass of the polyamide composition with a molecular weight greater than 1700 AMU; B=the % mass of the polyamide composition with a molecular weight between 1100 AMU and 1300 AMU; C=the % mass of the polyamide composition with a molecular weight between 700 AMU and 1000 AMU; and D=the % mass of the polyamide composition with a molecular weight of 600 AMU or lower (determined by GPC). The grease composition of the present disclosure provides a less than 50 penetration point change as determined by ASTM-D7342, a less than 10 mg weight loss as determined by ASTM-D4170, or both.
    Type: Grant
    Filed: December 12, 2018
    Date of Patent: September 15, 2020
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Sarvesh K. Agrawal, James E. Spagnoli, Chengrong Wang
  • Patent number: 10676689
    Abstract: Grease compositions are provided that can have one or more unexpectedly beneficial low temperature properties even though the grease compositions are formed from lower value components that traditional low temperature greases. The unexpectedly beneficial low temperature properties can be achieved in part by grease compositions that include a naphthenic base stock having a viscosity index of roughly 120 or less and/or a pour point of ?20° C. or more while having a naphthenes content of 60 wt % or more. In some aspects, the naphthenic base stock can have an aromatics content of 20 wt % or less.
    Type: Grant
    Filed: December 11, 2018
    Date of Patent: June 9, 2020
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Sarvesh K. Agrawal, James E. Spagnoli, David A. Blain
  • Publication number: 20190382680
    Abstract: The present disclosure provides a lithium complex grease with high-temperature resistivity and a method of using the same. The lithium complex grease includes: a lithium complex thickener, a friction modifier, a polymer or copolymer, and at least one synthetic base oil with alkylated naphthalene. The lithium complex grease can be substantially free of polytetrafluoroethylene. Furthermore, the lithium complex grease provides a median failure rate via a ball bearing test (e.g., using the FE9 grease life test method of DIN 51 821) performed at 160° C. of no less than 100 hours.
    Type: Application
    Filed: December 26, 2018
    Publication date: December 19, 2019
    Inventors: John K. GRAHAM, Nabila BRABEZ, John ZACHARKOW, Raymond C. ENNIS, James E. SPAGNOLI
  • Publication number: 20190203149
    Abstract: The present disclosure provides a grease composition with improved water resistance and mechanical stability at high-temperatures, including: at least one base oil; a water insoluble thickener; and a low molecular weight thixotropic polyamide composition having molecular weight distribution characteristics meeting the requirement described by the relationship: ( A + D ) ( B + C ) ? 0.05 where A=the % mass of the polyamide composition with a molecular weight greater than 1700 AMU; B=the % mass of the polyamide composition with a molecular weight between 1100 AMU and 1300 AMU; C=the % mass of the polyamide composition with a molecular weight between 700 AMU and 1000 AMU; and D=the % mass of the polyamide composition with a molecular weight of 600 AMU or lower (determined by GPC). The grease composition of the present disclosure provides a less than 50 penetration point change as determined by ASTM-D7342, a less than 10 mg weight loss as determined by ASTM-D4170, or both.
    Type: Application
    Filed: December 12, 2018
    Publication date: July 4, 2019
    Inventors: Sarvesh K. AGRAWAL, James E. SPAGNOLI, Chengrong WANG
  • Publication number: 20190203150
    Abstract: Grease compositions are provided that can have one or more unexpectedly beneficial low temperature properties even though the grease compositions are formed from lower value components that traditional low temperature greases. The unexpectedly beneficial low temperature properties can be achieved in part by grease compositions that include a naphthenic base stock having a viscosity index of roughly 120 or less and/or a pour point of ?20° C. or more while having a naphthenes content of 60 wt % or more. In some aspects, the naphthenic base stock can have an aromatics content of 20 wt % or less.
    Type: Application
    Filed: December 11, 2018
    Publication date: July 4, 2019
    Inventors: Sarvesh K. AGRAWAL, James E. SPAGNOLI, David A. BLAIN
  • Publication number: 20190062669
    Abstract: The present disclosure provides a lithium complex grease with high-temperature resistivity and a method of making the same. The lithium complex grease includes: a lithium complex thickener, a friction modifier, a polymer or copolymer, and at least one synthetic base oil with alkylated naphthalene. The lithium complex grease can be substantially free of polytetrafluoroethylene. Furthermore, the lithium complex grease can have a median failure rate with via ball bearing test (e.g., using the FE9 grease life test method of DIN 51 821) performed at 160° C. of no less than 100 hours.
    Type: Application
    Filed: June 18, 2018
    Publication date: February 28, 2019
    Inventors: Nabila BRABEZ, John K. GRAHAM, James E. SPAGNOLI, Raymond C. ENNIS, John ZACHARKOW
  • Publication number: 20190016984
    Abstract: This disclosure relates to a continuous process for preparing a grease thickener product in which operating conditions of the continuous process can be varied to obtain desired grease product properties. The process includes: (a) introducing a C3 to C30 hydroxy fatty acid or a C3 to C30 hydroxy fatty acid ester, and a metal base into a reaction zone; (b) operating the reaction zone at a temperature between 100° C. and 240° C. to react the C3 to C30 hydroxy fatty acid or the C3 to C30 hydroxy fatty acid ester, and the metal base, to produce a grease thickener product; (c) introducing the grease thickener product of step (b) into a flash chamber zone; and (d) operating the flash chamber zone at a temperature sufficient to remove volatiles from the grease thickener product of step (b). The continuous process conditions afford a production throughput of grease thickener product of greater than 8,000 pounds per hour.
    Type: Application
    Filed: July 9, 2018
    Publication date: January 17, 2019
    Inventors: Craig J. EMETT, John K. GRAHAM, John ZACHARKOW, Nabila BRABEZ, James E. SPAGNOLI
  • Patent number: 7829512
    Abstract: A continuous process for preparing lithium complex greases improved by using a complexing agent of dimethyl glutarate, dimethyl adipate, glutaric acid, adipic acid, or mixtures thereof, and preferably also a specialized flash chamber to achieve a penetration split (60X-UW) of within ?20 mm/10 to 10 mm/10, a roll stability (D1831) of <30 mm/10, and a dropping point (D2265) of >240° C.
    Type: Grant
    Filed: October 1, 2004
    Date of Patent: November 9, 2010
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Spencer Troy Stober, Todd Timothy Nadasdi, John Phillips Doner, John Kenneth Graham, Norman Charles Sundstrom, Paul Richard Grives, Barbara Anne Carfolite, James Fredrick Van Auken, James E. Spagnoli