Patents by Inventor James John McAlpin
James John McAlpin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7026040Abstract: This invention relates generally to films made from crystalline polypropylene polymers. Specifically, this invention relates to films comprising crystalline polypropylene polymer compositions containing both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.Type: GrantFiled: August 31, 2004Date of Patent: April 11, 2006Assignee: Exxon Mobil Chemical Patents Inc.Inventors: Aspy Keki Mehta, Michael Chia-Chao Chen, Chon-Yie Lin, James John Mcalpin, Anthony Nicholas Speca, Kelly Tormaschy
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Patent number: 6806316Abstract: This invention relates generally to crystalline polypropylene polymers and methods for their production. Specifically, this invention relates to crystalline polypropylene polymer compositions comprising both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.Type: GrantFiled: November 25, 2002Date of Patent: October 19, 2004Assignee: ExxonMobil Chemical Patents Inc.Inventors: Aspy Keki Mehta, Michael Chia-Chao Chen, Chon-Yie Lin, James John McAlpin, Anthony Nicholas Speca, Kelly Tormaschy
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Publication number: 20030153689Abstract: This invention relates generally to crystalline polypropylene polymers and methods for their production. Specifically, this invention relates to crystalline polypropylene polymer compositions comprising both propylene homopolymers and propylene copolymers. The compositions are prepared using metallocene catalyst systems comprising at least two metallocenes in a polymerization process that involves the sequential or parallel polymerization of propylene homopolymers and copolymers using propylene with a small amount of comonomer, preferably ethylene. The resulting polymers are excellent for use in the production of biaxially oriented films. Films prepared with these propylene polymers have a significantly broader processability range and can be evenly stretched at lower temperature compared to films prepared from traditional polypropylene polymers.Type: ApplicationFiled: November 25, 2002Publication date: August 14, 2003Inventors: Aspy Keki Mehta, Michael Chia-Chao Chen, Chon-Yie Lin, James John McAlpin, Anthony Nicholas Speca, Kelly Tormaschy
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Patent number: 6326442Abstract: The present invention provides a method for substantially continuously polymerizing olefins comprising: introducing into a first reaction zone a fresh olefin polymerization catalyst; contacting said fresh olefin polymerization catalyst in said first reaction zone with a first vent mixture at a first feed rate and under conditions sufficient to form and avoid melting a polyolefin, wherein first vent mixture comprises unreacted olefins and a diluent vented from a second reaction zone; withdrawing a vent product of unreacted olefins and diluent from said first reaction zone; withdrawing from said first reaction zone a first product mixture comprising said catalyst and said polyolefin; passing said first product mixture to said second reaction zone; contacting said first product mixture in said second reaction zone with a second vent mixture at a second feed rate and under conditions sufficient to form and avoid melting said polyolefin, wherein said second vent mixture comprises a material selected from the groupType: GrantFiled: May 15, 2000Date of Patent: December 4, 2001Assignee: Exxon Mobil Chemical, Inc.Inventors: Russell John Koveal, James John McAlpin, Jeffrey Lawrence Brinen
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Publication number: 20010000258Abstract: A molded or extruded article made from a propylene, &agr;-olefin copolymer, where the &agr;-olefin has 5 or more carbon atoms (higher alpha-olefins (HAO)), where the copolymer is made with a metallocene catalyst system, provides substantially higher cold flow resistance and resiliency than when the propylene copolymer contains an &agr;-olefin of 4 or less carbon atoms. Other properties such as ultimate tensile strength and impact strength are substantially higher as well. Such polymers can be used to advantage in extruded profiles and molded parts either alone or in a thermoplastic olefin (TPO). Parts made from the propylene HAO copolymers or compounds made from them show improved creep resistance than propylene ethylene copolymers.Type: ApplicationFiled: December 8, 2000Publication date: April 12, 2001Applicant: Exxon Chemical Patents Inc.Inventors: James John McAlpin, Aspy Keki Mehta, Jean Philippe Autran
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Patent number: 6066701Abstract: The present invention provides a method for substantially continuously polymerizing olefins comprising: introducing into a first reaction zone a fresh olefin polymerization catalyst; contacting said fresh olefin polymerization catalyst in said first reaction zone with a first vent mixture at a first feed rate and under conditions sufficient to form and avoid melting a polyolefin, wherein first vent mixture comprises unreacted olefins and a diluent vented from a second reaction zone; withdrawing a vent product of unreacted olefins and diluent from said first reaction zone; withdrawing from said first reaction zone a first product mixture comprising said catalyst and said polyolefin; passing said first product mixture to said second reaction zone; contacting said first product mixture in said second reaction zone with a second vent mixture at a second feed rate and under conditions sufficient to form and avoid melting said polyolefin, wherein said second vent mixture comprises a material selected from the groupType: GrantFiled: October 29, 1997Date of Patent: May 23, 2000Assignee: Exxon Chemical Patents Inc.Inventors: Russell John Koveal, James John McAlpin, Jeffrey Lawrence Brinen
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Patent number: 6010588Abstract: Novel fibers have been made of reactor grade isotactic poly-alpha-olefin wherein polypropylene is produced by single-site catalysis and has a melt flow rate of greater than zero to about 5,000, MWD in the range of about 1.0 to about 3.5.Type: GrantFiled: February 7, 1995Date of Patent: January 4, 2000Assignee: Exxon Chemical Patents Inc.Inventors: Glenn Allan Stahl, James John McAlpin
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Patent number: 5795946Abstract: Film is provided wherein, at least one layer comprises polymer, a molecular majority of which is derived from propylene, having water vapor transmission rate of less than or equal to about (-7.4428 g.times..mu.m/m.sup.2 .times.day.times.% polymer crystallinity) (% polymer crystallinity)+627.32 g.times..mu.m/m.sup.2 .times.day, or (-0.0189 g.times.mil/100 in.sup.2 .times.day.times.% polymer crystallinity) (% polymer crystallity)+1.593 g.times.mil/100 in.sup.2 .times.day.Type: GrantFiled: August 8, 1997Date of Patent: August 18, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Pawan Kumar Agarwal, Aspy Keki Mehta, Wai Yan Chow, James John McAlpin
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Patent number: 5763080Abstract: Propylene homopolymers and copolymers formed by metallocene catalyst system exhibit generally lower melting behavior than previous propylene polymers. This lower melting behavior will be of use in the fabrication and use of fibers and fabrics that depend upon either lower melting behavior in general or upon a melting point differential between two fabrics or fibers to achieve bonding. Such fibers are, for instance, chenille or tufted cord, core and sheath. Fabrics such as spunbonded and meltblown, when combined in SM or SMS fabrics will show bonding at lower temperatures with fewer pinholes. Such fabrics may also be bonded by adhesives such as hot melt, water based and extruded polyolefins. Combinations of Ziegler-Natta catalyzed and metallocene catalyzed polymers are contemplated.Type: GrantFiled: December 12, 1996Date of Patent: June 9, 1998Assignee: Exxon Chemical Co.Inventors: Glenn Allan Stahl, James John McAlpin
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Patent number: 5747592Abstract: A thermoplastic polymer composition incorporating at least about 50 wt % polypropylene, at least about 20 wt % of an elastomer such as EP rubber and at least about 4 wt % plastomer. The plastomer is preferably a single site catalyzed ethylene based copolymer having a density less than about 0.915. By adjusting the amount of the plastomer in the composition, considerable control is secured over post-mold shrinkage of components produced through injection molding operations utilizing the composition. The composition can be prepared as a reactor blend or a melt blend. The composition is particularly useful in producing large components such as bumpers and exterior trim fascia for automobiles.Type: GrantFiled: December 16, 1994Date of Patent: May 5, 1998Assignee: Exxon Chemical Patents, Inc.Inventors: Terrence Huff, James John McAlpin
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Patent number: 5736465Abstract: Novel fibers have been made from reactor grade isotactic poly-alpha-olefin wherein polypropylene is produced by single-site catalysis and has a melt flow rate of greater than zero to about 5,000, MWD in the range of about 1.0 to about 3.5.Type: GrantFiled: May 11, 1995Date of Patent: April 7, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Glenn Allan Stahl, James John McAlpin
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Patent number: 5726103Abstract: Propylene homopolymers and copolymers formed by metallocene catalyst system exhibit generally lower melting behavior than previous propylene polymers. This lower melting behavior will be of use in the fabrication and use of fibers and fabrics that depend upon either lower melting behavior in general or upon a melting point differential between two fabrics or fibers to achieve bonding. Such fibers are, for instance, chenille or tufted cord, core and sheath. Fabrics such as spunbonded and meltblown, when combined in SM or SMS fabrics will show bonding at lower temperatures with fewer pinholes. Such fabrics may also be bonded by adhesives such as hot melt, water based and extruded polyolefins. Combinations of Ziegler-Natta catalyzed and metallocene catalyzed polymers are contemplated.Type: GrantFiled: December 12, 1996Date of Patent: March 10, 1998Assignee: Exxon Chemical Co.Inventors: Glenn Allan Stahl, James John McAlpin
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Patent number: 5723217Abstract: Novel fibers have been made from reactor grade isotactic poly-alpha-olefin wherein polypropylene is produced by single-site catalysis and has a melt flow rate of greater than zero to about 5,000, MWD in the range of about 1.0 to about 3.5.Type: GrantFiled: May 11, 1995Date of Patent: March 3, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Glenn Allan Stahl, James John McAlpin