Abstract: Disclosed herein are methods and systems for identifying target analytes such as H2S and CO2 during downhole fluid analysis. The systems may include a fluid sampling tool comprising at least one probe to fluidly connect the fluid sampling tool to a formation in a wellbore, at least one passageway that passes through the at least one probe and into the fluid sampling tool, a sensor section comprising a measurement region in fluid communication with the at least one passageway, and a thin film deposited on the measurement region, wherein the thin film changes at least one of its physical properties upon exposure to the target analyte found in the at least one passageway. The methods may include disposing the fluid sampling tool into a wellbore, drawing a formation fluid from a sampling zone, and passing the fluid sample over the thin film deposited on a measurement region.

Abstract: A downhole fluid sampling system with hydraulic actuation can be used to collect one or more samples of formation fluid during a well operation. The sampling system can be within a downhole tool deployed in a wellbore of the well operation. Then sampling system then can collect a first sample from the flow of formation fluid from the wellbore using a first sampling chamber of a sampling unit in the sampling system. The sampling unit can define a set of sampling chambers including the first sampling chamber and a second sampling chamber. A piston of the sampling system that actuates on hydraulic fluid can advance the sampling unit by a predefined distance from a first position associated with the first sampling chamber to a second position associated with the second sampling chamber. Subsequently, the second sampling chamber can collect a second sample from the flow of formation fluid.

Abstract: Systems and methods for determining a level of contamination of a formation fluid by a drilling fluid are disclosed. The method includes defining a first curve of a range of values for a plurality of properties of the formation fluid in a multidimensional space, wherein each dimension is associated with one of the plurality of properties, defining a first point of the values of the plurality of properties for the drilling fluid in the multidimensional space, accessing measurements of the plurality of properties for a plurality of samples of a fluid being pumped out of a wellbore, defining a plurality of second points of the respective measured properties in the multidimensional space, and defining a vector from the first point through the plurality of second points to the first curve.

Abstract: Systems and methods of separating multiphase flows in a flowline of a downhole fluid sampling and analysis tool, measuring target ions in the water phase, and separating between formation water and injection water are described. The system to separate the multiphase flows includes a three-dimensional barrier permeable to water and repelling oil and/or drilling mud filtrate into at least one bypass channel within the flowline of the downhole fluid sampling and analysis tool. For instance, the system to measure the targeted ions includes the system to separate the multiphase flows and an optical sensor, wherein the three-dimensional barrier has an aperture inside the three-dimensional barrier to let a light from an optical sensor go through perpendicular to the flowline.

Abstract: Systems and methods are provided for facilitating continuous affinity-based separation of phases in multi-phase formation fluid in a downhole environment. A system can comprise a formation sampler that samples a formation to gather multi-phase formation fluid in a continuous flow through a wellbore during a testing pump out of the formation. The system can also comprise a phase separator comprising one or more affinity-based separators that continuously separates one or more phases of the multi-phase formation fluid through either or both diffusion or flow while downhole in the wellbore during the testing pump out.

Abstract: Systems and methods are provided for determining ion concentration of a fluid downhole using a polymer matrix packaged in a cartridge. An example method can include disposing a cartridge within a flow path of a sensor. The cartridge includes a bracket; a retainer formed of a porous material having pores sized to allow a fluid to flow therethrough; and a substrate comprising a polymer matrix embedded with an ion-indicator, the substrate configured to interact with the fluid and to modify an optical characteristic of the substrate according to an ion concentration of the fluid. The method further includes illuminating the substrate; detecting a change in an optical characteristic of the substrate, the change indicative of the ion concentration of the fluid; and determining the ion concentration of the fluid.

Abstract: A downhole tool to be positioned in a wellbore in a subsurface formation. The downhole tool comprises a first rod configured with a first cavity to obtain samples of formation fluid. The downhole tool comprises a translating member configured to shift the first rod from an open position to a closed position to obtain, via the first cavity, a first fluid sample of the formation fluid from a first location in the wellbore.

Abstract: A coating system for coating an interior surface of a housing comprising: first and second closures engaging first and second ends, respectively, of the housing to provide an enclosed volume; first and second flow lines coupled to the first and second closures, respectively, the first flow line and/or the second flow line connected to an inert gas source; a reactant gas source(s) comprising a reactant gas and coupled to the first and/or second flow line; and a controller in electronic communication with the reactant gas and inert gas sources, and configured to control flow of inert gas into the enclosed volume, and counter current injection of reactant gas from the reactant gas source(s) into the enclosed volume whereby introduction of pulse(s) of the reactant gas into the enclosed volume are separated by introduction of inert gas into the enclosed volume, and coating layer(s) are deposited on the interior surface.

Abstract: A coating system for coating, with a surface coating process, an interior surface of a housing defining an interior volume, having: a first closure and a second closure to sealingly engage with the housing; one or more first flow lines and second flow lines fluidically coupled to the first and second closure, respectively; a pressurized cell comprising a pressurized gas comprising at least one reactant and at a pressure of greater than a pressure within the housing, wherein the pressurized cell is fluidically coupled to a pressurized cell line comprising one of the first flow lines or second flow lines; and a controller in electronic communication with the pressurized cell and configured to control injection of a pulse of the pressurized gas into a flow of inert gas in the pressurized cell line, whereby the pulse is introduced into the interior volume, coating the interior surface with a coating layer.

Abstract: Systems and techniques are provided for optimizing the performance of a target for a downhole neutron generator. An example method can include disposing a first source material and a first substrate in a vacuum chamber at an initial temperature, evaporating the first source material to be deposited onto a surface of the first substrate, monitoring a temperature of the first substrate during the evaporation of the first source material, and determining a thermal equilibrium process temperature at which the temperature of the first substrate is stabilized. The example method can further include disposing a second source material and a second substrate in the vacuum chamber at the thermal equilibrium process temperature, evaporating the second source material to be deposited onto a surface of the second substrate, and obtaining the second substrate deposited with the second source material for a target of a downhole neutron generator.

Abstract: A method and system for identifying scale. The method may include disposing a fluid sampling tool into a wellbore. The fluid sampling tool may comprise at least one probe configured to fluidly connect the fluid sampling tool to a formation in the wellbore and at least one passageway that passes through the at least one probe and into the fluid sampling tool. The method may further comprise drawing a formation fluid, as a fluid sample, through the at least one probe and through the at least one passageway, perturbing the formation fluid, and analyzing the fluid sample in the fluid sampling tool for one or more indications of scale.

Abstract: A device for monitoring deposition of a coating comprising a dielectric material during deposition of the coating. The device includes a parallel-plate capacitor having a first plate, and a second plate; a first lead electrically connected to the first plate; a second lead electrically connected to the second plate; and a power supply. The first plate and the second plate are parallel and separated by a spacing with a known spacing thickness. The first lead and the second lead can be electrically connected to positive and negative terminals of the power supply. The device is configured to register a capacitance when the first lead and the second lead are respectively connected to the positive and the negative terminals of the power supply and a dielectric material fills the spacing, and is configured to register no capacitance until the dielectric material fills the spacing.

Abstract: Wellbore equipment used in oil and gas operations can be negatively affected by corrosive fluids. Coatings can be applied to the equipment to help protect the equipment. A field test can be used at a wellsite to ensure the coating is effective. Due to the HSE risks of the corrosive fluids, a proxy fluid can be used instead. The proxy fluid can have similar chemical or physical properties and simulate the corrosive fluid that is anticipated to be present in the wellbore. The wellbore equipment that is coated can be sealed to create a containment area where an initial concentration of the proxy fluid is introduced into the containment area for a period of time. A final concentration of the proxy fluid can be measured after the period of time has elapsed. By calculating the percent change of the proxy fluid, the effectiveness of the coating can be determined.

Abstract: A fluid sampling tool may include a fluid characterization device consisting of a densitometer, a viscometer, or a vibrating element, or a combination thereof and a polymer disposed in or around the fluid characterization device, wherein the polymer volume, density, or viscosity changes with an ionic stimulus. The fluid characterization device may be located within a bypass flow line of the sampling tool. A method of measuring pH and a method of monitoring at least two analytes at the same time using the fluid characterization devices are also discussed.

Abstract: Systems and methods of separating multiphase flows in a flowline of a downhole fluid sampling and analysis tool, measuring target ions in the water phase, and separating between formation water and injection water are described. The system to separate the multiphase flows includes a three-dimensional barrier permeable to water and repelling oil and/or drilling mud filtrate into at least one bypass channel within the flowline of the downhole fluid sampling and analysis tool. For instance, the system to measure the targeted ions includes the system to separate the multiphase flows and an optical sensor, wherein the three-dimensional barrier has an aperture inside the three-dimensional barrier to let a light from an optical sensor go through perpendicular to the flowline.

Abstract: A model is used to generate corrections to mitigate ideal condition artifacts in acoustic property values of an annular material in a cased wellbore. A mathematical model that generates acoustic property values at ideal conditions introduces artifacts into the acoustic property values. Acoustic measurements of an annular material are used to generate features that represent wellbore conditions and are not accounted for in the mathematical model that generates acoustic property values. A model will generate corrections for acoustic property values of an annular material with the features to yield a more accurate acoustic property profile for the annular material of a cased hole.

Abstract: Methods and systems for determining one or more ion components. The method may include disposing a fluid sampling tool into a wellbore wherein the fluid sampling tool includes at least one probe to fluidly connect the fluid sampling tool to a formation in the wellbore, and at least one passageway that passes through the at least one probe and into the fluid sampling tool. The method may further comprise drawing a formation fluid, as a fluid sample, through the at least one probe and through the at least one passageway, and analyzing the fluid sample in the fluid sampling tool for one or more ion components.

Abstract: A method and system for identifying scale. The method may include disposing a fluid sampling tool into a wellbore. The fluid sampling tool may comprise at least one probe configured to fluidly connect the fluid sampling tool to a formation in the wellbore and at least one passageway that passes through the at least one probe and into the fluid sampling tool. The method may further comprise drawing a formation fluid, as a fluid sample, through the at least one probe and through the at least one passageway, perturbing the formation fluid, and analyzing the fluid sample in the fluid sampling tool for one or more indications of scale.

Abstract: A coating system for coating, with a surface coating process, an interior surface of a housing defining an interior volume, having: a first closure and a second closure to sealingly engage with the housing; one or more first flow lines and second flow lines fluidically coupled to the first and second closure, respectively; a pressurized cell comprising a pressurized gas comprising at least one reactant and at a pressure of greater than a pressure within the housing, wherein the pressurized cell is fluidically coupled to a pressurized cell line comprising one of the first flow lines or second flow lines; and a controller in electronic communication with the pressurized cell and configured to control injection of a pulse of the pressurized gas into a flow of inert gas in the pressurized cell line, whereby the pulse is introduced into the interior volume, coating the interior surface with a coating layer.

Abstract: A coating system for coating an interior surface of a housing comprising: first and second closures engaging first and second ends, respectively, of the housing to provide an enclosed volume; first and second flow lines coupled to the first and second closures, respectively, the first flow line and/or the second flow line connected to an inert gas source; a reactant gas source(s) comprising a reactant gas and coupled to the first and/or second flow line; and a controller in electronic communication with the reactant gas and inert gas sources, and configured to control flow of inert gas into the enclosed volume, and counter current injection of reactant gas from the reactant gas source(s) into the enclosed volume whereby introduction of pulse(s) of the reactant gas into the enclosed volume are separated by introduction of inert gas into the enclosed volume, and coating layer(s) are deposited on the interior surface.