Abstract: In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising lubricant base selected from the group consisting of solid lubricants, liquid lubricants, grease lubricants, emulsion lubricants, and dispersion lubricants, the improvement wherein the lubricant composition further comprises: an effective amount of water and surfactant. It is believed that mixing oil with water and surfactant provides a method for uniformly distributing the surface oxide at the meniscus for casting applications. Uniform distribution of the oxide at the meniscus reduces vertical fold formation that can lead to cracks in the aluminum ingot. In addition, the mixture promotes uniform heat transfer around the mold. Uniform heat transfer around the mold allows the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells. A process for continuous or semi-continuous casting of aluminum alloys via the use of this lubricant composition is also disclosed.

Abstract: In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising lubricant base selected from the group consisting of solid lubricants, liquid lubricants, grease lubricants, emulsion lubricants, and dispersion lubricants, the improvement wherein the lubricant composition further comprises: an effective amount of water and surfactant or water and a compound comprising phosphates, borates, fluorides, and silicates. It is believed that mixing oil with water and surfactant or one of these compounds provides a method for uniformly distributing the surface oxide at the meniscus for casting applications, thereby reducing vertical fold formation that lead to cracks in aluminum ingots. In addition, the mixture promotes uniform heat transfer around the mold allowing the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells.

Abstract: In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising a lubricant base, the improvement wherein the lubricant composition further comprises: an effective amount of water, surfactant, and a high viscosity organic material having a low vapor pressure. It is believed that this mixture provides a method for uniformly distributing the surface oxide at the meniscus for casting applications and increasing meniscus stability. Uniform distribution of the oxide and increased stability at the meniscus reduces vertical fold formation that can lead to cracks in the aluminum ingot. In addition, the mixture promotes uniform heat transfer around the mold. Uniform heat transfer around the mold allows the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells. A process for continuous or semi-continuous casting of aluminum alloys via the use of this lubricant composition is also disclosed.

Abstract: In a lubricant composition suitable for use in the manufacture of aluminum alloys comprising a lubricant base, the improvement wherein the lubricant composition further comprises: an effective amount of water, surfactant, and a high viscosity organic material having a low vapor pressure. It is believed that this mixture provides a method for uniformly distributing the surface oxide at the meniscus for casting applications and increasing meniscus stability. Uniform distribution of the oxide and increased stability at the meniscus reduces vertical fold formation that can lead to cracks in the aluminum ingot. In addition, the mixture promotes uniform heat transfer around the mold. Uniform heat transfer around the mold allows the solidifying aluminum alloy to stay in contact with the mold longer and form stronger ingot shells. A process for continuous or semi-continuous casting of aluminum alloys via the use of this lubricant composition is also disclosed.

Abstract: There is disclosed a metal sheet product, more particularly formed food container stock and/or industrial sheet product, which has been treated with a polymerizable lubricant composition having a vegetable oil portion which is less than about 60% monounsaturate in character, said composition comprising: (a) about 10-90 wt. % of a technical white mineral oil, preferably a polyalphaolefin, and/or white mineral oil, said component having an average molecular weight greater than about 480; and (b) about 10-90 wt. % of an edible vegetable oil selected from the group consisting of: safflower oil, canola oil, soybean oil, sunflower oil, corn oil, olive oil, pine nut oil, cottonseed oil and combinations thereof. Preferably, the latter component is a combination of about 8-20 wt. % safflower oil and about 25-50 wt. % canola oil.

Abstract: There is disclosed a metal sheet product, more particularly formed food container stock and/or industrial sheet product, which has been treated with a lubricant composition having a vegetable oil portion which is less than about 60% monounsaturate in character, said composition comprising: (a) about 10-90 wt. % of a technical white mineral oil, preferably a polyalphaolefin, and/or white mineral oil, said component having an average molecular weight greater than about 400; and (b) about 10-90 wt. % of an edible vegetable oil selected from the group consisting of: safflower oil, canola oil, sunflower oil, corn oil, olive oil, cottonseed oil and combinations thereof. Preferably, the latter additive is a combination of about 8-20 wt. % safflower oil and about 25-50 wt. % canola oil. When applied in total deposited weights of about 0.

Abstract: There is disclosed a metal sheet product, more particularly formed food container stock and/or industrial sheet product, which has been treated with an ester-free, lubricant composition that is suitable for direct food contact. This composition consists essentially of: (i) about 10-90 wt. % of a polyalphaolefin; (ii) about 10-90 wt. % of an oleic acid; (iii) about 0-60 wt. % of an isostearic acid; and preferably, about 10-35 wt. % isostearic acid. It should be noted that especially good smudge testing results were observed with the presence of oleic acid. In alternative embodiments, the lubricant composition further includes: (iv) up to about 5 wt. % of an antioxidant, preferably about 0.1-3 wt. % butylated hydroxytoluene; and (v) up to about 10 wt. % of a conductivity enhancer, such as about 2-7 wt. % lecithin. When applied in total deposited weights of about 0.

Abstract: Metal sheet product, more particularly food can stock and beer and beverage can tab, end and body stock, is treated with a lubricant made by blending a mixture consisting essentially of about 25-90 wt.% of: (i) an ester selected from the group consisting of: bis(2-ethylhexyl)sebacate (or DOS), butyl stearate, and an acetylated, partially hydrogenated soybean oil; and (ii) about 10-75 wt.% of a blend consisting essentially of: (a) about 35-65 wt.% of a polyalphaolefin; and (b) about 65-35 wt.% of a microcrystalline wax; with a balance of incidental additives and impurities. With said composition applied thereon, in preferred average thicknesses between about 3-110 mg/ft.sup.2 for can tab stock and between about 3-35 mg/ft.sup.2 for can end and body stock, the invention produces prelubricated can stock in a suitable condition for conversion without further lubrication.

Abstract: Apparatus for lubricating die and/or workpiece surfaces, the apparatus including a container adapted to capture a predetermined volume of lubricant. At least one nozzle is provided for spraying the volume of lubricant onto the die/workpiece surfaces when the volume is received from the container. A first valve is connected between the nozzle and container, and a reservoir of lubricant and a pump for circulating lubricant through the container and past the first valve at a relatively low pressure is provided, the circulation of lubricant occurring during a portion of a lubricating cycle when no lubricant is sprayed onto the die/workpiece surfaces. A second valve is located between the pump and container for interrupting the flow of lubricant past the first valve, and a blocking valve is located between the container and the reservoir for interrupting the flow of lubricant from the container.

Abstract: Metal sheet product, more particularly food or beverage can tab and end stock, is treated with a lubricant blend consisting essentially of about 25-90 wt % bis(2-ethylhexyl)sebacate or DOS; about 10-75 wt % petrolatum and a balance of incidental additives and impurities prior to coiling for transport and storage. With said composition applied hereon, in preferred average thicknesses between about 10-110 mg/ft.sup.2 for aluminum can tab stock and up to about 35 mg/ft.sup.2 for aluminum can end stock, the invention produces prelubricated can stock in a suitable condition for conversion into can tabs and/or can ends without further lubrication.

Abstract: Hydrocarbon lubricating oils with a tetrahydrocarbylammonium thiomolybdate having at least about 19 carbon atoms, such as dicocodimethylammonium thiomolybdate, solubilized in the oil are characterized by improved anti-friction properties.

Abstract: The presence of a minor amount of a tetrahydrocarbylammonium thiomolybdate containing at least about 15 carbon atoms, such as trioctylmethylammonium thiomolybdate, to a grease thickened with a substituted-urea composition substantially improves the extreme pressure properties of the grease.

Abstract: Novel quaternary ammonium thiomolybdates are prepared by contacting an aqueous solution of a thiomolybdate salt with a solution of a water-insoluble quaternary ammonium salt in a water-immiscible organic solvent. For example, mixing a solution of dicocodimethylammonium chloride in toluene with an aqueous solution of potassium thiomolybdate results in a toluene solution containing dicocodimethylammonium thiomolybdate. These quaternary ammonium thiomolybdates find use as additives in motor oils and greases to enhance their antifriction characteristics.

Abstract: Quaternary ammonium thiomolybdates are prepared in a two-phase reaction system by contacting an aqueous solution of a thiomolybdate salt with a solution of a quaternary ammonium salt in a water-immiscible organic solvent. For example, mixing a solution of dicocodimethylammonium chloride in toluene with an aqueous solution of potassium thiomolybdate results in a toluene solution containing dicocodimethylammonium thiomolybdate.