Abstract: By considering ratio of emissions at one or more pairs of energies to threshold values, the invention provides for the determination of the dispersion format of a radioactive material within a matrix, wherein said radioactive material is potentially present in a dispersion format which is self-shielding against emissions arising from said radioactive. In particular the presence of lumpy material or the confirmation that lump material is absent may be provided. The following pairs of energies: 143.8 keV and 185.7 keV; 163.3 keV and 185.7 keV; 205.3 keV and 187.5 keV may be used.