Abstract: An example article according to the present disclosure includes, among other possible things, a metallic substrate, and a bond coat on the metallic substrate. The bond coat includes a matrix phase, gettering particles in the matrix phase, wherein the gettering particles are reactive with oxidants, and a dispersion of matrix modifier particles in the matrix phase. The example article also includes a diffusion barrier between the bond coat and the metallic substrate, wherein the diffusion barrier is configured to inhibit diffusion of components from the bond coat into the metallic substrate. An example composite material and method of applying a barrier to a substrate are also disclosed.

Abstract: A gas turbine engine component having a substrate; a thermal barrier coating on the substrate having a porous microstructure; and a reflective layer conforming to the porous microstructure of the thermal barrier coating, wherein the reflective layer comprises a conforming nanolaminate defined by alternating layers of platinum group metal materials selected from the group consisting of platinum group metal-based alloys, platinum group metal intermetallic compounds, mixtures of platinum group metal with metal oxides and combinations thereof. A capping layer can be added over the reflective layer. A supporting layer can be added between the reflective layer and the thermal barrier coating. A process is also disclosed.

Abstract: A thermal spray powder includes composite powder particles that each have a silicon carbide core and a multi-layered shell that surrounds the core. The shell includes at least one layer of silica and at least one layer of alumina. The powder is used to deposit a mullite-based topcoat on a ceramic matrix composite wall of an article.

Abstract: A method for protecting a coated substrate having a porous ceramic barrier coating includes applying a molten salt to the ceramic barrier coating. The salt is selected from the group consisting of one or more acetates and/or nitrates. The molten salt is infiltrated into porosity of the ceramic barrier coating. The infiltrated molten salt is solidified. The solidified salt is sintered.

Abstract: A method for coating a ceramic matrix composite substrate with an environmental barrier coating includes the steps of: treating a surface of a ceramic matrix composite substrate to adjust wettability of the surface; and applying an aqueous slurry-based environmental barrier coating to the surface. The treating step can be a plasma treatment to remove organic contaminants, and can also be a treatment to modify oxidative state of the surface. The treatment can produce a surface for treatment that is hydrophilic and has a contact angle with aqueous-slurry coating materials of less than 40 degrees.

Abstract: A method of applying a coating to a substrate includes forming a slurry by mixing elemental precursors of gettering particles, diffusive particles, matrix material, and a carrier fluid; applying the slurry to a substrate; and sintering the slurry to form a composite material. The sintering causes the elemental precursors to react with one another to form gettering particles. An article is also disclosed.

Abstract: An article includes a ceramic-based substrate and a barrier layer on the ceramic-based substrate. The barrier layer includes a matrix phase and gettering particles in the matrix phase. The gettering particles with an aspect ratio greater than one are aligned such that a maximum dimension of the gettering particles extends along an axis that is generally parallel to the substrate. The barrier layer includes a dispersion of diffusive particles in the matrix phase. A composite material and a method of applying a barrier layer to a substrate are also disclosed.

Abstract: A gas turbine engine component having a substrate; a thermal barrier coating on the substrate having a porous microstructure; and a reflective layer conforming to the porous microstructure of the thermal barrier coating, wherein the reflective layer comprises a conforming nanolaminate defined by alternating layers of platinum group metal materials selected from the group consisting of platinum group metal-based alloys, platinum group metal intermetallic compounds, mixtures of platinum group metal with metal oxides and combinations thereof. A capping layer can be added over the reflective layer. A supporting layer can be added between the reflective layer and the thermal barrier coating. A process is also disclosed.

Abstract: A component of an aero-propulsion apparatus, wherein the component includes a material and has a surface, and a thin film on the surface, wherein the thin film is configured to undergo a detectible change in properties when exposed to a temperature exceeding a threshold temperature. Methods are also disclosed.

Abstract: A coated article including an article having a surface; an oxidation resistant bond coat layer deposited on the surface, the oxidation resistant bond coat layer comprising a healing silica matrix and at least one oxygen scavenger forming a metal silicide network dispersed within the healing silica matrix; and a top coat layer disposed upon the oxidation resistant bond coat layer, whereby the oxidation resistant bond coat layer is operable to seal a crack in the top coat layer.

Abstract: An article includes a substrate, a barrier layer disposed on the substrate, and an oxide-based ceramic material topcoat disposed on the barrier layer. The topcoat includes at least one crack. The article also includes a filler layer disposed on the topcoat and in the at least one crack. A method of applying a coating to an article and an article are also disclosed.

Abstract: An article includes a substrate and a barrier layer on the substrate. The barrier layer includes a matrix, diffusive particles dispersed in the matrix, and gettering particles dispersed in the matrix. The gettering particles include at least one alloyed metal silicide. A composite material and a method of fabricating an article are also disclosed.

Abstract: An article according to an exemplary embodiment of this disclosure includes a substrate and a bond coat disposed on the substrate. The bond coat includes a matrix. The matrix includes regions of ?-cristobalite. The article also includes a plurality of gettering particles disposed in the matrix, a plurality of diffusive particles disposed in the matrix, and an additive operable to stabilize the regions of ?-cristobalite at ambient temperatures dispersed in the matrix. An article and a method of coating an article are also disclosed.

Abstract: An environmental barrier coating includes a barrier layer which includes a matrix, diffusive particles, and gettering particles; and a calcium-magnesia alumina-silicate (CMAS)-resistant component. The CMAS-resistant component includes hafnium silicate and a rare earth hafnate. An article and a method of fabricating an article are also disclosed.

Abstract: An environmental barrier coating includes a barrier layer which includes a matrix, diffusive particles, and gettering particles; and a calcium-magnesia alumina-silicate (CMAS)-resistant component. The CMAS-resistant component includes hafnium silicate and a rare earth hafnate. An article and a method of fabricating an article are also disclosed.

Abstract: A method for coating a substrate includes spraying a combination of powders. The combination of powders includes: Hf0.5Si0.5O2; Zr0.5Si0.5O2; and, optionally, at least one of HfO2 and ZrO2. A molar ratio of said Hf0.5Si0.5O2 and HfO2 combined to said Zr0.5Si0.5O2 and ZrO2 combined is from 2:1 to 4:1. A molar ratio of said Hf0.5Si0.5O2 to said HfO2 is at least 1:3.

Abstract: An article includes a substrate and a bond coat disposed on the substrate. The bond coat includes a matrix, a plurality of gettering particles disposed in the matrix, a plurality of diffusive particles disposed in the matrix, a radiation-absorbing component disposed in the matrix, wherein the radiation-absorbing component is concentrated at an outer surface of the bond coat. An article and a method of protecting an article are also disclosed.

Abstract: A barrier layer for an article according to an exemplary embodiment of this disclosure, among other possible things includes a bond coat comprising a matrix, diffusive particles disposed in the matrix, and gettering particles disposed in the matrix. The composition of the gettering particles is a reaction product of the chemical reaction of Equation 1 defined by Equation 2: Si w ? O x ? C y ? N z + ? ? O 2 = w ? Si ? O 2 + y ? CO + z 2 ? N 2 Equation ? 1 ? = 2 ? w + y - x 2 Equation ? 2 A barrier layer is also disclosed.

Abstract: A method of making spherical gettering particles for an environmental barrier coating according to an exemplary embodiment of this disclosure, among other possible things includes spraying liquid preceramic polymer into a chamber via a nozzle to form liquid droplets, curing the liquid droplets to form spherical particles in the chamber, and converting the spherical particles to spherical ceramic gettering particles in a fluidized bed. A method of making spherical gettering particles for an environmental barrier coating and an article are also disclosed.

Abstract: A method for coating a substrate includes spraying a combination of powders. The combination of powders includes: Hf0.5Si0.5O2; Zr0.5Si0.5O2; and, optionally, at least one of HfO2 and ZrO2. A molar ratio of said Hf0.5Si0.5O2 and HfO2 combined to said Zr0.5Si0.5O2 and ZrO2 combined is from 2:1 to 4:1. A molar ratio of said Hf0.5Si0.5O2 to said HfO2 is at least 1:3.