Abstract: The present invention is for a process for making a heteropoly acid compound catalyst for oxidation of unsaturated aldehydes, such as methacrolein, to unsaturated carboxylic acids, such as methacrylic acid, said catalyst containing oxides of molybdenum, phosphorus, and M?, wherein M? is cesium, potassium, rubidium, or sodium, and bismuth. The process is a synthesis of the catalyst with specific process conditions for addition of the bismuth compound as an aqueous slurry without nitric acid. A catalyst precursor is formed by removing the water and drying the solid particles. The heteropoly acid compound catalyst is formed by calcination of the catalyst precursor.

Abstract: A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron, cesium and certain other metals to molybdenum and, optionally, tungsten. For a catalyst of the formula: Mo12BiaWbFecCodNieSbfCsgMghZniPjOx wherein a is 0.1 to 1.5, b is 0 to 4, c is 0.2 to 5.0, d is 0 to 9, e is 0 to 9, f is 0 to 2.0, g is from 0.4 to 1.5, h is 0 to 1.5, i is 0 to 2.0, j is 0 to 0.5 and x is determined by the valences of the other components, c:g=3.3-5.0, c:a=2.0-6.0 and (3a+3c+2d+2e+g+2h+2i)/(2×12+2b)=0.95-1.10.

Abstract: A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron, cesium and certain other metals to molybdenum and, optionally, tungsten. For a catalyst of the formula: Mo12BiaWbFecCodNieSbfCsgMghZniPjOx wherein a is 0.1 to 1.5, b is 0 to 4, c is 0.2 to 5.0, d is 0 to 9, e is 0 to 9, f is 0 to 2.0, g is from 0.4 to 1.5, h is 0 to 1.5, i is 0 to 2.0, j is 0 to 0.5 and x is determined by the valences of the other components, c:g=3.3–5.0, c:a=2.0–6.0 and (3a+3c+2d+2e+g+2h+2i)/(2×12+2b)=0.95–1.10.

Abstract: The present invention is for a process for making a catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene, said catalyst containing oxides of molybdenum, bismuth, iron, cesium, tungsten, cobalt, nickel, antimony, magnesium and zinc. The process is a two-part synthesis of the catalyst with the water insoluble components in one part and the water soluble components in the other part. The water insoluble components are co-precipitated to form an intermediate catalyst precursor of a precipitated support incorporating oxides of the metal components. The intermediate catalyst precursor is filtered and washed to remove nitrates. The intermediate catalyst precursor is slurried with the remaining water soluble components. A final catalyst precursor is formed by removing the water and incorporating the water soluble components. This two-part process reduces the amount of nitrates in the final catalyst precursor.

Abstract: A catalyst for production of unsaturated aldehydes, such as methacrolein, by gas phase catalytic oxidation of olefins, such as isobutylene contains oxides of molybdenum, bismuth, iron, cesium and, optionally, other metals, such as tungsten, cobalt, nickel, antimony, magnesium, zinc and phosphorus. The catalyst has a certain relative amount ratio of cesium to bismuth, a certain relative amount ratio of iron to bismuth and a certain relative amount ratio of bismuth, iron and cesium to molybdenum.

Abstract: A simulator which may provide interferometer-based signatures of agent, stimulant, interferent and toxic chemicals for scenarios to test sensors, detectors and like systems. The simulator may assimilate data and information related to a calibrated background spectrum, and atmospheric and cloud models for simulating signatures and corresponding scenarios. Data and information may include, but not limited to, field data, atmospheric conditions, agent absorption coefficients, system performance requirements. Various modeling and computing tools may be incorporated in the simulation process.

Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.

Abstract: A process for preparing a low-dusting, free-flowing pigment which has not been subjected to any micronizing treatment comprising the steps of providing an inorganic pigment material; providing a source of water; forming a fine, well dispersed slurry of the pigment and water; milling the slurry; depositing a treating agent having the formula ROOCCHSO.sub.3 MCH.sub.2 COOR' wherein R and R' are monovalent alkyl radicals having from about 2 to about 20 carbon atoms, and M is a metallic monovalent cation on the slurried milled pigment; and drying the pigment material having a treating agent deposited thereon. The invention also provides the free-flowing pigments produced by this process.

Abstract: A process for producing a conductive, fluorine-doped titanium dioxide product which is doped throughout, said process comprising the steps of: (a) reacting the precursors in a system to form fluorine-doped TiO.sub.2, said precursors consisting essentially of a titanium alkoxide and a fluorine source; (b) reducing the fluorine-doped titanium dioxide product at a temperature sufficient to form said conductive, fluorine-doped titanium dioxide product; and (c) recovering the reduced product.

Abstract: Improved methods and polymer compositions are provided whereby ultraviolet radiation degradation of substrates formed of the compositions is attenuated.In accordance with the invention, ultraviolet scattering and absorbing particles having a particle size in the range of from about 0.001 micrometer to about 0.20 micrometer in diameter are dispersed in at least a surface layer of a polymer substrate.

Abstract: Improved methods and polymer compositions are provided whereby ultraviolet radiation degradation of substrates formed of the compositions is attenuated. In accordance with the invention, ultraviolet scattering and absorbing particles having a particle size in the range of from about 0.001 micrometer to about 0.20 micrometer in diameter are dispersed in at least a surface layer of a polymer substrate.

Abstract: Synthetic friction force algorithms provide simulated static friction forces as well as dynamic friction forces. On either side of a hand-control element reference position a small static friction zone is established. As long as the hand-control element is within this static friction zone, the reference position remains constant and the control element drive motor generates a centering force proportional to the distance of the hand-control element from the reference position; a force urging the hand-control element toward the reference position. When the relative position of the hand-control element reaches or exceeds an edge of the static friction zone, it enters the dynamic friction zone. The motor applies a constant dynamic friction force, urging the hand-control element toward the reference position and the reference position is translated so that the edge of the static friction zone is translated to the current hand-control element position.

Abstract: Improved methods and polymer compositions are provided whereby ultraviolet radiation degradation of substrates formed of the compositions is attenuated. In accordance with the invention, ultraviolet scattering and absorbing particles having a particle size in the range of from about 0.001 micrometer to about 0.20 micrometer in diameter are dispersed in at least a surface layer of a polymer substrate.

Abstract: A control system for an active hand controller, for example, uses a control stick connected to and controlled by a motor. Electronics are provided to control the motor to eliminate oscillations due to motor torque and high gain due to breakout at the control stick when the control stick is at about its null position. Both hardware as well as software implementations can provide position dependent dampening to the control sticks such that when the control stick is located about a null position, a higher rate of dampening is provided than when the control stick is located outside the null position, when a lower rate of dampening is provided. The system provides a stable active hand controller control stick without degraded force and feel characteristics of the system.

Abstract: An inventive process for forming a conductive, particulate, fluorine-doped, zinc oxide product which is doped throughout. The process comprises the step of reacting vapor phase reactants in a vapor phase oxidation system and at a temperature sufficient to form the conductive, particulate, fluorine-doped, zinc oxide product. The vapor phase reactants used in the inventive process comprise: elemental zinc vapor; at least one fluorine source; and at least one water source.

Abstract: Ultraviolet light stable polymeric resin compositions comprising an ultraviolet light degradable polymeric resin component and an effective ultraviolet light absorbing amount of a particulate metal titanate component.

Abstract: Ultraviolet light stable polymeric resin compositions comprising an ultraviolet light degradable polymeric resin component and an effective ultraviolet light absorbing amount of a particulate metal titanate component.

Abstract: Chemically inert pigmentary zinc oxide compositions, useful in producing UV light stable polymeric resin compositions are prepared by wet treatment of chemically reactive zinc oxide base pigments utilizing a process wherein chemically inert organic or inorganic coatings are deposited thereon.