Patents by Inventor Jan Bock
Jan Bock has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4694058Abstract: Novel water soluble copolymers of acrylamide, oil soluble higher alkylacrylamide and alkali metal acrylate have been found to provide efficient viscosification of water or brine. The process for synthesizing them relies on the complete solubilization of the water insoluble monomer into an aqueous solution of the water soluble monomer(s) by means of a suitable water soluble surfactant. A redox initiator system is used in conjunction with high monomer concentration and a low reaction temperature. The surfactant chosen and its concentration is one that produces a clear, uniform, homogeneous mixture in the presence of the monomers and gives a product which remains a clear uniform, homogeneous mixture with no phase separation as the reaction proceeds toward completion. The molecular weight of the resulting polymer after isolation from the surfactant is sufficiently high that it gives an intrinsic viscosity greater than about 12 dl/g.Type: GrantFiled: May 27, 1986Date of Patent: September 15, 1987Assignee: Exxon Research and Engineering CompanyInventors: Donald B. Siano, Jan Bock
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Patent number: 4684473Abstract: A lubricating oil composition having improved friction reducing properties and the method of reducing friction in internal combustion engines by lubricating said engines with said lubricating oil which contains an effective friction reducing amount of an additive which is the reaction product of dimer carboxylic acid and a polyhydric alcohol having at least 2 hydroxyl groups in combination with an oil soluble alkanol or an oil soluble alkyl phosphate.Type: GrantFiled: March 31, 1986Date of Patent: August 4, 1987Assignee: Exxon Research and Engineering CompanyInventors: Jan Bock, Darrell W. Brownawell, Antonio Gutierrez, Max L. Robbins, Harold Shaub, Peter L. Steyn
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Patent number: 4673716Abstract: Novel water soluble copolymers of acrylamide, oil soluble higher alkylacrylamide and alkali metal acrylate have been found to provide efficient viscosification of water or brine. The process for synthesizing them relies on the complete solubilization of the water insoluble monomer into an aqueous solution of the water soluble monomer(s) by means of a suitable water soluble surfactant. A redox initiator system is used in conjunction with high monomer concentration and a low reaction temperature. The surfactant chosen and its concentration is one that produces a clear, uniform, homogeneous mixture in the presence of the monomers and gives a product which remains a clear uniform, homogeneous mixture with no phase separation as the reaction proceeds toward completion. The molecular weight of the resulting polymer after isolation from the surfactant is sufficiently high that it gives an intrinsic viscosity greater than about 12 dl/g.Type: GrantFiled: November 25, 1985Date of Patent: June 16, 1987Assignee: Exxon Research and Engineering CompanyInventors: Donald B. Siano, Jan Bock
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Patent number: 4663408Abstract: The present invention relates to improved viscosification agents for an aqueous or brine solutions. Typically, the viscosification agents are tetrapolymers of N-vinyl pyrrolidone/acrylamide/salt of acrylic acid/N-alkyl acrylamide wherein said tetrapolymers have the formula: ##STR1## wherein w is about 1 to about 80 mole percent, more preferably about 5 to about 75 mole percent, and most preferably about 10 to about 70 mole percent; x is about 10 to about 90 mole percent, more preferably about 20 to about 80 mole percent, and most preferably about 30 to about 70 mole percent; and y is about 0.1 to about 10.0 mole percent, more preferably about 0.15 to about 5.0 mole percent; and most preferably about 0.2 to about 3.0 mole percent; z is about 1.0 to about 30.0 mole percent, more preferably about 2.0 to about 25.0 mole percent, and most preferably about 5.0 to about 20.Type: GrantFiled: December 30, 1985Date of Patent: May 5, 1987Assignee: Exxon Research and Engineering CompanyInventors: Donald N. Schulz, Enock Berluche, John J. Maurer, Jan Bock
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Patent number: 4650848Abstract: A water soluble terpolymer having the structure: ##STR1## wherein x is selected from the group consisting of ##STR2## wherein x is about 1 to about 95 mole percent; y is about 0.1 to about 5.0 mole percent; R.sub.1 is methyl or hydrogen; z is about 1 to about 30 mole percent; R.sub.2 is an alkyl group of 1-5 carbon atoms; R.sub.3 is an alkyl group of 3 to 4 carbon atoms; R.sub.4 is an alkyl group of 1-5 carbon atoms; and R.sub.5 is an alkyl group of 4-20.Type: GrantFiled: December 30, 1985Date of Patent: March 17, 1987Assignee: Exxon Research & Engineering CompanyInventors: Donald N. Schulz, Ilan Duvdevani, Jan Bock, Enock Berluche
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Patent number: 4612332Abstract: Surfactant-free stable aqueous foams may be produced by water soluble copolymers of acrylamide and N-alkylacrylamide with chain lengths greater than or equal to 6 carbons. Additionally, these polymers may contain an anionic monomer, such as a monovalent salt of acrylic acid. These copolymers and terpolymers are added to water or brine at a concentration of 0.005 to 2 parts per 100 of solvent. When the resulting solutions are subjected to intensive mixing with the addition of air or other gases, such as nitrogen or carbon dioxide, high quality, persistent foams are formed. These foams are formed at relatively low polymer concentrations without added surfactants. They have good high temperature stability and excellent salt tolerance.Type: GrantFiled: December 12, 1985Date of Patent: September 16, 1986Assignee: Exxon Research and Engineering Co.Inventors: Jan Bock, Hartley H. Downs, Donald B. Siano, Salvatore J. Pace
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Patent number: 4599250Abstract: A method for treating particulate solids such as coal to reduce the cohesive strength of such solids when frozen which consists of spraying said solids with a hydrocarbon liquid solution of a balanced blend of surfactants which blend will form a single phase microemulsion at 20.degree. C. when added to water at the salinity of the water on said solids at a water to hydrocarbon ratio in the range between 99:1 and 85:15, said blend represented by the monoethanol amine salt of dodecyl o-xylene sulfonic acid and a dinonylphenol reacted with 9 moles of ethylene oxide, onto the wetted surface of said solids to form a single phase microemulsion which is optimally designed to undergo a lipophilic shift upon contacting the surface of said particles whereby an in-situ water-in-oil coarse emulsion is formed on the surfaces of said particles.Type: GrantFiled: November 19, 1982Date of Patent: July 8, 1986Assignee: Exxon Research & Engineering Co.Inventors: Virgil H. Cargle, Max L. Robbins, Jan Bock
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Patent number: 4585810Abstract: The present invention relates to drag reduction agents for water which are diblock polymers of t-butylstyrene/metal styrene sulfonate and triblock polymers of t-butylstyrene/metal styrene sulfonate/t-butylstyrene.Type: GrantFiled: July 2, 1984Date of Patent: April 29, 1986Assignee: Exxon Research and Engineering Co.Inventors: Jan Bock, Ralph M. Kowalik, Paul L. Valint
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Patent number: 4579926Abstract: The present invention relates to a process for the formation of water soluble copolymers of acrylamide and alkyl poly(etheroxy)acrylate which are finished by a dialysis process and are excellent viscosification agents. Wherein the process includes the free radical copolymerization of acrylamide monomer and alkyl poly(etheroxy)acrylate monomer in an aqueous medium under nitrogen conditions in the presence of free radical initiator at a sufficient temperature and for a sufficient time to effect copolymerization.Type: GrantFiled: April 9, 1984Date of Patent: April 1, 1986Assignee: Exxon Research and Engineering Co.Inventors: John J. Maurer, Donald N. Schulz, Jan Bock
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Patent number: 4548735Abstract: The present invention relates to oil solubilization agents for solubilizing oil into an aqueous solution in which the oil solubilization agents are diblock polymers of t-butylstyrene/metal styrene sulfonate and triblock polymers of t-butylstyrene/metal styrene sulfonate/t-butylstyrene.Type: GrantFiled: December 29, 1982Date of Patent: October 22, 1985Assignee: Exxon Research and Engineering Co.Inventors: Jan Bock, Paul L. Valint, Jr.
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Patent number: 4546784Abstract: The present invention relates to improved drag reduction agents which are water soluble copolymers of acrylamide and alkyl poly(etheroxy)acrylate.Type: GrantFiled: June 29, 1984Date of Patent: October 15, 1985Assignee: Exxon Research and Enginering Co.Inventors: Donald N. Schulz, Ralph M. Kowalik, Jan Bock, John J. Maurer
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Patent number: 4528348Abstract: The copolymerization of water soluble monomers with water insoluble monomers can be effected by using a solution of a water soluble surfactant to solubilize the water insoluble monomer. The aqueous medium containing the surfactant and water insoluble monomer is therefore a homogeneous, isotropic, transparent dispersion, into which the water soluble monomer can be dissolved and, after addition of a suitable free radical initiator, can be copolymerized to give a reaction mixture which does not phase separate, or contain substantial amounts of particulates of insoluble monomer. The copolymers which may be isolated from the reaction mixture are good viscosifiers of water and brine.Type: GrantFiled: August 29, 1983Date of Patent: July 9, 1985Assignee: Exxon Research & Engineering CompanyInventors: S. Richard Turner, Donald B. Siano, Jan Bock
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Patent number: 4521580Abstract: The copolymerization of water soluble monomers with water insoluble monomers can be effected by dissolving the water insoluble monomer into a homogeneous mixture of oil, surfactant, and cosurfactant and then diluting this with water containing the water soluble monomer to yield a predominently aqueous, homogeneous, transparent dispersion of microemulsion droplets. The polymerization is initiated with water soluble free radical initiators to give copolymers that are free of visible particulates and such that the reaction product remains homogenous. The components are chosen to yield copolymers that are water soluble and which viscosify at low concentrations.Type: GrantFiled: August 29, 1983Date of Patent: June 4, 1985Assignee: Exxon Research & Engineering Co.Inventors: S. Richard Turner, Donald B. Siano, Jan Bock
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Patent number: 4520182Abstract: Water soluble acrylamide/alkylacrylamide copolymers which are efficient viscosifiers of water or brine are described. They are made by processes which finely disperse the water insoluble alkylacrylamide into a water-external microemulsion or a micellar surfactant solution.Type: GrantFiled: August 29, 1983Date of Patent: May 28, 1985Assignee: Exxon Research & Engineering Co.Inventors: S. Richard Turner, Donald B. Siano, Jan Bock
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Patent number: 4492785Abstract: The present invention relates to viscosification agents for water which are diblock polymers of t-butylstyrene/metal styrene sulfonate and triblock polymers of t-butylstyrene/metal styrene sulfonate/t-butylstyrene.Type: GrantFiled: December 29, 1982Date of Patent: January 8, 1985Assignee: Exxon Research and Engineering Co.Inventors: Paul L. Valint, Jr., Jan Bock
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Patent number: 4463151Abstract: The present invention relates to a process for the formation of water soluble copolymers of acrylamide and alkyl poly(etheroxy)acrylate which are excellent viscosification agents, wherein the process includes the free radical copolymerization of acrylamide monomer and alkyl poly(etheroxy)acrylate monomer in an aqueous medium under nitrogen conditions in the presence of free radical initiator at a sufficient temperature and for a sufficient time to effect copolymerization.Type: GrantFiled: December 29, 1982Date of Patent: July 31, 1984Assignee: Exxon Research and Engineering Co.Inventors: Donald N. Schulz, John J. Maurer, Jan Bock
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Patent number: 4463152Abstract: The present invention relates to a composition of water soluble copolymers of acrylamide and alkyl poly(etheroxy)acrylate which are excellent viscosification agents.Type: GrantFiled: December 29, 1982Date of Patent: July 31, 1984Assignee: Exxon Research and Engineering Co.Inventors: Donald N. Schulz, John J. Maurer, Jan Bock
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Patent number: 4461696Abstract: Disclosed is a process for converting organic material of oil-shale to predominantly liquids. The oil-shale is first heated to a temperature from about 360.degree. C. to 475.degree. C. in an inert atmosphere. The resulting liquids and gases are collected and the residue is extracted with a microemulsion capable of extracting organic material from the heat treated oil-shale.Type: GrantFiled: April 25, 1983Date of Patent: July 24, 1984Assignee: Exxon Research and Engineering Co.Inventors: Jan Bock, Patrick P. McCall, Max L. Robbins, Michael Siskin
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Patent number: 4458757Abstract: Disclosed is a process for converting organic material of oil-shale to predominantly liquids. The oil-shale is first heated to a temperature from about 360.degree. C. to 475.degree. C. in an anionic atmosphere. The resulting liquids and gases are collected and the residue is extracted with a microemulsion capable of extracting organic material from the heat treated oil-shale.Type: GrantFiled: April 25, 1983Date of Patent: July 10, 1984Assignee: Exxon Research and Engineering Co.Inventors: Jan Bock, Patrick P. McCall, Max L. Robbins, Michael Siskin
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Patent number: 4316828Abstract: An improved process for the manufacture of extended gel free sulfonated elastomeric products includes the formation of a homogeneous mixture of fillers and oils with the acid form of the sulfonated polymer prior to the neutralization of the acid form of the sulfonated polymer with a basic material thereby resulting in a composition having improved physical properties.Type: GrantFiled: June 12, 1979Date of Patent: February 23, 1982Assignee: Exxon Research & Engineering Co.Inventors: Henry S. Makowski, Robert D. Lundberg, Jan Bock