Abstract: This invention relates to phosphoroamidothioate and phosphoroamidodithioate compounds, to compositions thereof which are useful as pesticides, for example, as athropodicides (that is, insecticides and acaricides), nematocides, and fungicides, and to a method of controlling pests, such as insects, acarids, nematodes, and fungi. The compounds of the invention are effective against soil insects, especially the corn rootworm, when applied by soil application techniques and are also effective when applied to agricultural plants and other plants by foliar application techniques.

Abstract: This invention relates to phosphoroamidothioate and phosphorcamidodithioate compounds, to compositions thereof which are useful as pesticides. For example, as arthropodicides (that is, insecticides and acaricides), nematocides, and fungicides, and to a method of controlling pests, such as insects, acarids, nematodes, and fungi. The compounds of the invention are effective against soil insects, especially the corn rootworm, when applied by soil application techniques and are also effective when applied to agricultural plants and other plants by foliar application techniques.

Abstract: There are disclosed N-sulfonyl phosphorodiamido(di)thioates having pesticidal activity, especially miticidal activity against mites possessing resistance to organophosphorous compounds, when applied to pests or to loci to be freed from the pests by foliar or systematic application techniques.

Abstract: There are disclosed N-acyl and N-thioacyl phosphorodiamido(di)thioates having pesticidal activity when applied to pests or to loci to be freed from the pests by foliar or systemic application techniques.

Abstract: There are disclosed N-sulfonyl N'-oxalate phosphorodiamido(di)thioates having pesticidal activity, especially miticidal activity against mites possessing resistance to organo-phosphorous compounds, when applied to pests or to loci to be freed from the pests by foliar or systemic application techniques.

Abstract: Disclosed are compounds of the formula: ##STR1## wherein R.sup.1 isa hydrogen atom;an unsubstituted or substituted alkyl group;an alkynyl group;an alkenyl group;an alkyldienyl;a cycloalkyl group;an alkoxycarbonyl group;an unsubstituted or substituted phenyl group;an unsubstituted or substituted phenylalkyl group;R.sup.2 is an unsubstituted alkyl group;R.sup.3 is a hydrogen atom, an alkyl group, or an alkenyl group;R.sup.4 is a hydrogen atom, an alkyl group or additionally when R.sup.3 and R.sup.5 are not taken together to form a heterocycle, an alkenyl group;R.sup.5 isa hydrogen atom;an unsubstituted or substituted alkyl group;an alkynyl group;an alkenyl group;a cycloalkyl group;an unsubstituted or substituted phenyl group;an unsubstituted or substituted phenyl (C.sub.1 -C.sub.5) alkyl group, orR.sup.3 and R.sup.5 can be taken together to form a heterocyclic ring of the formula ##STR2## wherein Z is a --CH.sub.2 CH.sub.2 -- group, a --CH.sub.2 CH.sub.2 CH.sub.2 -- group, or a --CH.sub.2 CH.sub.2 CH.sub.2 CH.

Abstract: This invention relates to novel phosphoramidothioates of the formula: ##STR1## wherein A is optionally substituted (C.sub.6 -C.sub.10) aryl;R is hydrogen or (C.sub.1 -C.sub.6) alkyl;R.sup.1 is(a) optionally substituted (C.sub.1 -C.sub.6) alkyl,(b) (C.sub.3 -C.sub.8) cycloalkyl,(c) optionally substituted (C.sub.3 -C.sub.6) alkenyl,(d) (C.sub.3 -C.sub.6) alkynyl, or(e) optionally substituted (C.sub.7 -C.sub.11) aralkyl;R.sup.2 is(a) (C.sub.1 -C.sub.6) alkylthio,(b) (C.sub.6 -C.sub.10) aryloxy, or(c) NZ'Z"; whereinZ' is hydrogen or (C.sub.1 -C.sub.6) alkyl; andZ" is hydrogen, (C.sub.1 -C.sub.6) alkyl, (C.sub.3 -C.sub.6) alkenyl, di(C.sub.1 -C.sub.3) alkylamino, 2-ethylthioethyl, 2-methoxyethyl or (C.sub.1 -C.sub.4) alkoxycarbonylalkyl (C.sub.1 -C.sub.4);R.sup.3 is unsubstituted (C.sub.1 -C.sub.6) alkyl; andX is oxygen or sulfur;to compositions containing them and to methods of using them to control certain harmful pests.

Abstract: This invention relates to novel phosphoramidates of the formula: ##STR1## wherein A is an optionally substituted (C.sub.6 -C.sub.10) aryl group;R is a hydrogen atom, a (C.sub.1 -C.sub.6) alkyl group, a di(C.sub.1 -C.sub.4) alkylamino group, a (C.sub.4 -C.sub.6) cycloamino group, a (C.sub.1 -C.sub.6) alkoxy group, a (C.sub.1 -C.sub.6) alkylthio group or a cyano group;R.sup.1 is (a) an optionally substituted (C.sub.1 -C.sub.6) alkyl group;(b) an optionally substituted (C.sub.3 -C.sub.8) cycloalkyl group;(c) an optionally substituted (C.sub.3 -C.sub.6) alkenyl group;(d) an optionally substituted (C.sub.5 -C.sub.8) cycloalkenyl group;(e) a (C.sub.3 -C.sub.6) alkynyl group; or(f) an optionally substituted aralkyl group of up to 11 carbon atoms;R.sup.2 is a (C.sub.1 -C.sub.6) alkyl group;R.sup.3 is a (C.sub.1 -C.sub.6) alkyl group; andX is an oxygen or sulfur atom;To compositions containing them and to methods of using them to control certain harmful pests.

Abstract: This invention relates to novel phosphoramido(di)thioates of the formula: ##STR1## wherein A isA. a halogen atom,B. a cyano group,C. a (C.sub.1 -C.sub.6) alkoxy group,D. a (C.sub.1 -C.sub.6) alkylthio group,E. a (C.sub.1 -C.sub.6) alkylcarbonyloxy group,F. a phenoxy group, orG. a phenylthio group;R.sup.1 isA. a (C.sub.1 -C.sub.12) alkyl group,B. a (C.sub.3 -C.sub.8) cycloalkyl group,C. an optionally substituted aralkyl group of up to 11 carbon atoms, orD. an optionally substituted (C.sub.6 -C.sub.10) aryl group;R.sup.2 is a hydrogen atom or a (C.sub.1 -C.sub.4) alkyl group when A is a halogen atom, and a hydrogen atom when A is other than a halogen atom;R.sup.3 is a (C.sub.1 -C.sub.6) alkyl group;R.sup.4 is a (C.sub.1 -C.sub.6) alkyl group;R.sup.5 and R.sup.6 are independently hydrogen atoms or (C.sub.1 -C.sub.4) alkyl groups; andY is an oxygen or sulfur atom;To compositions containing them, to processes for preparing them, and to methods of utilizing them as arthropodicides.