Abstract: This invention is directed to a molecular sieve composition or a catalyst containing molecular sieve which has a relatively high residual silica index, preferably at least about 1.5. The molecular sieve or catalyst can be made by contacting a template-containing molecular sieve with a silicon containing material having an average kinetic diameter that is larger than the average pore diameter of the sieve or catalyst, and heating to leave residual silica at the sieve or catalyst surface. The molecular sieve or catalyst is particularly effective in making an olefin product from an oxygenate feedstock.

Abstract: This invention is directed to a molecular sieve composition or a catalyst containing molecular sieve which has a relatively high residual silica index, preferably at least about 1.5. The molecular sieve or catalyst can be made by contacting a template-containing molecular sieve with a silicon containing material having an average kinetic diameter that is larger than the average pore diameter of the sieve or catalyst, and heating to leave residual silica at the sieve or catalyst surface. The molecular sieve or catalyst is particularly effective in making an olefin product from an oxygenate feedstock.

Abstract: This invention is directed to a molecular sieve composition or a catalyst containing molecular sieve which has a relatively high residual silica index, preferably at least about 1.5. The molecular sieve or catalyst can be made by contacting a template-containing molecular sieve with a silicon containing material having an average kinetic diameter that is larger than the average pore diameter of the sieve or catalyst, and heating to leave residual silica at the sieve or catalyst surface. The molecular sieve or catalyst is particularly effective in making an olefin product from an oxygenate feedstock.

Abstract: This invention is directed to a molecular sieve composition or a catalyst containing molecular sieve which has a relatively high residual silica index, preferably at least about 1.5. The molecular sieve or catalyst can be made by contacting a template-containing molecular sieve with a silicon containing material having an average kinetic diameter that is larger than the average pore diameter of the sieve or catalyst, and heating to leave residual silica at the sieve or catalyst surface. The molecular sieve or catalyst is particularly effective in making an olefin product from an oxygenate feedstock.

Abstract: An ion exchange method is provided for loading and uniformly distributing noble metals into a catalyst substrate comprising a zeolite to make a monofunctional, non-acidic reforming catalyst. The catalyst substrate is contacted with an aqueous loading solution comprising noble metal cations and non-noble metal cations. The loading solution is formulated such that the equivalents of non-noble metal cations remaining in the catalyst not ionically bonded to the zeolite when loading is complete is 1.2 to 6.0 times the equivalents of non-noble metal cations displaced from the zeolite when the noble metal cations ion exchange into the zeolite, and simultaneously the endpoint pH of the loading solution is between 10.0 and 11.5. The required 1.2 to 6.0 ratio is achieved when the ratio of moles of non-noble metal cations added to the loading solution to moles of noble metal added to the loading solution is between 1 and 10.

Abstract: A process for reforming naphtha-containing hydrocarbon feedstreams is disclosed wherein a naphtha stream containing at least about 25 wt % of C5 to C9 aliphatic and cycloaliphatic hydrocarbons is contacted with a modified reforming catalyst, e.g. ZSM-5, containing a dehydrogenation metal, e.g. zinc, which has been modified by contact with Group IIA alkaline earth metal, e.g. barium, or with an organosilicon compound in an amount sufficient to neutralize at least a portion of the surface acidic sites present on the catalyst. The resulting reformate contains a reduced content of C1 to C4 gas and a C8 aromatic fraction having an enhanced content of para-xyelene.

Abstract: A process for reforming naphtha-containing hydrocarbon feedstreams is disclosed wherein a naphtha stream containing at least about 5 wt % of C9+ aromatics, at least about 25 wt % C.sub.5 to C.sub.9 aliphatic hydrocarbons and greater than 50 wt. ppm sulfur is contacted under reforming conditions with a bifunctional reforming catalyst, e.g. H.sup.+ ZSM-5, containing a dehydrogenation metal, e.g. zinc. The resulting reformate contains a higher ratio of C.sub.6 to C.sub.9 aromatics to C.sub.5 -C.sub.9 aliphatic hydrocarbon which boil near the boiling point of C.sub.6 to C.sub.8 aromatics present in the reformate, thereby facilitating separation of these aromatics form the reformate.

Abstract: A process for isomerizing a nonequilibrium xylene feed mixture is disclosed. The isomerization is conducted in the presence of hydrogen and at pressures in excess of 75 psig over a ZSM-5 type catalyst containing about 0.1 to 5 wt % of at least one metal selected from the group consisting of zinc, copper, silver and gallium. In another embodiment, the catalyst may further contain an oxide of at least one element selected from silicon, germanium and tin. The process produces a product containing about or above equilibrium quantities of para-xylene with low xylene loss.

Abstract: The invention provides a crystalline type L zeolite reforming catalyst comprising cylindrically shaped crystals having a length of 0.6 microns or less and an average length: diameter ratio of less than about 0.5, the catalyst containing at least one Group VIII metal and from about 0.1 to 2 wt % halogen e.g., chlorine. Also provided is a method for activating or regenerating the catalyst wherein a fresh or de-coked catalyst is oxychlorinated, purged to remove excess chlorine and reduced. The catalysts are particularly useful for the reforming of C.sub.6 to C.sub.11 naphthas to produce reformates having a high content of C.sub.6 to C.sub.8 light aromatics and a reduced content of heavier C.sub.9 and C.sub.10 aromatics.

Abstract: A process for reforming a hydrocarbon fraction substantially free of dimethylbutanes. The hydrocarbon is separated into a fraction comprising the C.sub.5 - hydrocarbons and the dimethylbutanes, a light fraction excluding dimethyl butanes, and a heavy fraction. The light fraction is reformed in the presence of a monofunctional catalyst, and the heavy fraction is reformed in the presence of a bifunctional catalyst.

Abstract: The present invention is a process for regenerating deactivated catalyst or redispersing catalytic metal in a fresh catalyst comprising at least one Group VIII catalytic metal, zeolite, an inert binder. The process comprises coke burn, hydrogen reduction, catalyst conditioning, oxychlorination, low pressure stripping, and low pressure final hydrogen reduction.

Abstract: A process for producing zeolite aggregates involves providing a formable paste composed of zeolite, a binder composed of an organic/metal oxide containing aluminum, a peptizing agent and water; forming the paste into an aggregate, preferably by extruding into an extrudate; curing the aggregate; hydro-thermally calcining the aggregate; and washing the hydro-thermally calcined aggregate with a washing medium, preferably followed by rinsing with a rinsing medium to remove residual washing medium from the aggregate. The washed and rinsed aggregate may then be permitted to equilibrate or is subjected to a drying procedure. Preferably, the washed and rinsed aggregate is again subjected to curing/hydro-thermal calcining.

Abstract: The present invention discloses an alcohol coupling process in which a vaporized mixture of starting alcohols, preferably methanol and ethanol, is reacted with syngas in the presence of a large pore L zeolite, Y zeolite or large port mordenite, to form at least one alcohol coupling product having a greater number of carbon atoms than all of the starting alcohols. The large pore zeolite preferably has a substantial absence of strongly acidic catalytic sites and the reaction preferably produces the product alcohol in the substantial absence of C.sub.6+ oxygenates.

Abstract: A process for producing zeolite aggregates involves providing a formable paste composed of zeolite, a binder composed of an organic/metal oxide containing aluminum, a peptizing agent and water; forming the paste into an aggregate, preferably by extruding into an extrudate; curing the aggregate; hydro-thermally calcining the aggregate; and washing the hydro-thermally calcined aggregate with a washing medium, preferably followed by rinsing with a rinsing medium to remove residual washing medium from the aggregate. The washed and rinsed aggregate may then be permitted to equilibrate or is subjected to a drying procedure. Preferably, the washed and rinsed aggregate is again subjected to curing/hydro-thermal calcining.

Abstract: Zeolites washed with aqueous solutions or water to exhibit pH in the range of 9.4 to 10.0 and preferably 9.6 to 10.0 which can be converted to reforming catalysts with enhanced activity, selectivity and activity maintenance. Also processes for washing the zeolite to the target pH range and processes for using catalysts made with the washed zeolite to reform naphtha feeds.

Abstract: Zeolites washed with aqueous solutions or water or exhibit pH in the range of 9.4 to 10.0 and preferably 9.6 to 10.0 which can be converted to reforming catalysts with enhanced activity, selectivity and activity maintenance. Also processes for washing the zeolite to the target pH range and processes for using catalysts made with the washed zeolite to reform naphtha feeds.

Abstract: A class of bound catalysts which exhibit superior activity maintenance in dehydrocyclization reactions are defined as a type L zeolite having exchangeable cations of which at least 75% are selected from Group IA and calcium and barium cations and containing well dispersed particles of at least one Group VIII noble metal where at least 90% of the noble metal thereof is dispersed in the form of particles having a diameter less than 7 .ANG.. The catalysts may also be identified as type L zeolites loaded with at least one Group VIII noble metal which have a terminal cracking index (as a measure of production of pentanes versus butanes from hexane) of at least 1.5.

Abstract: A class of bound catalysts which exhibit superior activity maintenance in dehydrocyclization reactions are defined as a type L zeolite having exchangeable cations of which at least 75% are selected from Group IA and calcium and barium cations and containing well dispersed particles of at least one Group VIII noble metal where at least 90% of the noble metal thereof is dispersed in the form of particles having a diameter less than 7 .ANG.. The catalysts may also be identified as type L zeolites loaded with at least one Group VIII noble metal which have a terminal cracking index (as a measure of production of pentanes versus butanes from hexane) of at least 1.5.

Abstract: A process is provided for loading and uniformly distributing platinum onto a Zeolite-L. The Zeolite-L is contacted with an aqueous solution containing a platinum salt and a non-platinum metal salt, wherein the non-platinum metal salt is present in solution in an amount which is critical to preventing the formation of acid sites as well as avoiding an excess of metal ions in the form of a salt which could block the pores of the Zeolite-L. The Zeolite-L is then aged to allow the platinum to migrate and uniformly distribute throughout the Zeolite.

Abstract: A process for the preparation of bromoalkyl esters and vicinal glycol esters which comprises thermally decomposing at temperatures of from 100.degree. C. to 200.degree. C. a bis(2-bromoalkyl)tellurium dicarboxylate compound of the formula ##STR1## wherein at least one R is hydrogen or R is a methyl group and R' is hydrogen or an alkyl group having 1 to 3 carbon atoms in the presence of an aliphatic monocarboxylic acid selected from formic, acetic, propionic or butyric acid employed as solvent and to facilitate solvolysis in the reaction to give in addition to the bromoalkyl ester, the vicinal glycol ester. An inert acetonitrile solvent may be employed alone to give predominately the bromoalkyl ester or an admixture with the acid may be employed. Oxygen is preferably employed with the carboxylic acid solvent to provide an increase in the mole ratio of vicinal glycol ester to the bromoalkyl ester produced.