Abstract: Disclosed herein is a composition comprising a co-continuous interpenetrating network of an organic polymer and a electroactive moiety; where the organic polymer is operative to depolymerize at a temperature of 50 to 500° C. and to repolymerize on a surface in the presence of the electroactive moiety; and where the electroactive moiety is an organic semiconductor that does not react with a repolymerized polymer. Disclosed herein too is a method comprising co-evaporating a polymeric precursor and an electroactive moiety onto a substrate; condensing the polymeric precursor and an electroactive moiety on the substrate; and polymerizing the polymeric precursor to form a co-continuous interpenetrating network of an organic polymer and an electroactive moiety; where the electroactive moiety is defined as a chemical functional group which is capable of transporting an electrical charge.