Abstract: A novel approach to sample deposition in furnace atomization is disclosed which obviates the need for skilled application of microvolumes by syringe. By means of the apparatus and method disclosed, the analyte in aerosol form is deposited under controlled conditions on the internal surface areas of graphite furnaces. Precision approaching that of flame atomization systems is achieved and at the same time, concentrational sensitivity may be increased simply by extending the deposition time. The amount of analyte deposited in the furnace is restricted only by the sample volume available and the matrix concentration. A single standard can be used to construct a calibration curve by simply varying the aerosol deposition time.

Abstract: Apparatus for directly controlling the power delivered to an electrically heated furnace atomizer for use in atomic spectroscopy and thus for controlling the temperature of the furnace by utilizing dimensional changes produced in the furnace due to thermal expansion and contraction to produce electrical signals that are used by means of a feedback control to control the electrical input to the furnace.