Abstract: An antimicrobial coating is disclosed that provides fast transport rates of biocides for better effectiveness to deactivate SARS-CoV-2 and other viruses or bacteria on common surfaces. Some variations provide an antimicrobial structure comprising: a solid structural phase comprising a solid structural material; a continuous transport phase that is interspersed within the solid structural phase, wherein the continuous transport phase comprises a solid transport material; and an antimicrobial agent contained within the continuous transport phase, wherein the solid structural phase and the continuous transport phase are separated by an average phase-separation length from about 100 nanometers to about 500 microns. The antimicrobial structure is capable of destroying at least 99.99% of bacteria and/or viruses in 10 minutes of contact. Many options are disclosed for suitable materials to form the solid structural phase, the continuous transport phase, and the antimicrobial agent.

Abstract: The disclosed technology provides a vitrimeric poly(diketoenamine) network comprising: a plurality of multifunctional triketone dimers; a plurality of multifunctional amine species containing primary or secondary amine groups, but no tertiary amine groups; and optionally, one or more amine-reactive groups. The disclosed technology also provides a method of making a vitrimeric polymer network, comprising: obtaining multifunctional triketone dimers; obtaining a multifunctional imine compound, with imine groups blocking amine groups; mixing the multifunctional triketone dimers with the multifunctional imine compound, thereby forming a polymer precursor mixture; applying the polymer precursor mixture onto a substrate; and allowing the multifunctional imine compound to undergo hydrolysis with water, unblocking the amine functional groups and generating a multifunctional amine compound. The multifunctional amine compound reacts with the multifunctional triketone dimers to form a vitrimeric polymer network.

Abstract: The disclosed technology provides a vitrimeric poly(diketoenamine) network comprising: a plurality of multifunctional triketone dimers; a plurality of multifunctional amine species containing primary or secondary amine groups, but no tertiary amine groups; and optionally, one or more amine-reactive groups. The disclosed technology also provides a method of making a vitrimeric polymer network, comprising: obtaining multifunctional triketone dimers; obtaining a multifunctional imine compound, with imine groups blocking amine groups; mixing the multifunctional triketone dimers with the multifunctional imine compound, thereby forming a polymer precursor mixture; applying the polymer precursor mixture onto a substrate; and allowing the multifunctional imine compound to undergo hydrolysis with water, unblocking the amine functional groups and generating a multifunctional amine compound. The multifunctional amine compound reacts with the multifunctional triketone dimers to form a vitrimeric polymer network.

Abstract: A method for producing a planar semiconductor surface includes forming a workpiece that has a carrier substrate, one or more insulating layers, a semiconductor layer, a first etch stop layer, and a second etch stop layer; forming a contact on the workpiece; biasing the workpiece to a second voltage through the contact; etching the second etch stop layer and part of the first etch stop layer with a photo-electrochemical etching and the second voltage that selectively removes the second etch stop layer faster than the first etch stop layer; biasing the workpiece to a first voltage through the contact; and etching the first etch stop layer and part of the semiconductor layer with the photo-electrochemical etching and the first voltage that selectively removes the first etch stop layer faster than the semiconductor layer to produce a semiconductor device with a planar surface on the semiconductor layer.

Abstract: Aspects of the present disclosure provide titanium-based coatings and methods for making titanium-based coatings on surfaces. In at least one aspect, a coating includes an oxygen content, a fluorine content, a titanium content, and a sodium content. In one or more additional aspects, a coating includes titanium dioxide and Na5Ti3F14. In one or more additional aspects, a method of making a titanium-based coating includes contacting a substrate with a composition that includes from about 0.01 M to about 0.8 M of a titanium fluoride, from about 0.01 M to about 2 M of a sodium salt, and from about 0.1 M to about 1.5 M of a fluorine scavenger.

Abstract: A deployable structure includes a hydride material to be converted into hydrogen gas; and a sheet material encapsulating the hydride material; wherein the sheet material is to be plastically deformed by the hydrogen gas to have an expanded structure. A method of manufacturing a deployable structure includes: forming a sheet material comprising an outer shell structure and a hollow interior; placing a hydride material capable of being converted into hydrogen gas into the hollow interior; sealing the outer shell structure; and converting and releasing the hydrogen gas to expand and plastically deform the sheet material.

Abstract: A crystalline titanium and magnesium compound having an X-ray diffraction pattern having interplanar spacing (d-spacing) values at about 5.94, 3.10, 2.97, 2.10, 1.98, 1.82, and 1.74±0.1 angstroms may be used in protective coatings for metal or metal alloy substrates. The coatings exhibit excellent corrosion resistances and provide corrosion protection equal to or better than typical non-chromate coatings.

Abstract: This disclosure provides corrosion-resistant coatings that significantly improve corrosion resistance compared to the prior art. The corrosion protection system senses gradients in electrical potential, pH, and metal ion concentration, and then automatically halts corrosion. Some variations provide a gradient-responsive corrosion-resistant coating comprising: a first layer comprising a transition metal oxide and mobile cations; a second layer comprising a biphasic polymer, wherein the biphasic polymer contains ionic groups, wherein the biphasic polymer comprises a discrete phase and a continuous transport phase, wherein the continuous transport phase is capable of delivering oligomers in response to corrosion byproducts, and wherein the oligomers are ionically crosslinkable with metal cations from a base metal substrate.

Abstract: A hydride flow reactor includes a tank configured to receive a hydride fuel. The reactor also includes a tubular member coupled to the tank and configured to receive the hydride fuel from the tank. The reactor also includes a transporter positioned at least partially within the tubular member and configured to transport the hydride fuel through the tubular member. The reactor also includes a heater positioned at least partially around the tubular member and the transporter. The heater is configured to heat the hydride fuel in the tubular member to convert the hydride fuel into hydrogen gas and a reacted byproduct.

Abstract: A vehicle, and a balancing device and method of controlling a state of charge of a reference electrode in a battery. The balancing device includes a measurement circuit and a charging circuit. The measurement circuit is configured to obtain a measurement of a reference voltage of the reference electrode. The charging circuit is configured to adjust the reference voltage based on the measurement. The state of charge of the reference electrode is controlled based on the reference voltage.

Abstract: Some variations provide a multiphase polymer composition comprising a first polymer material and a second polymer material that are chemically distinct, wherein the first polymer material and the second polymer material are microphase-separated on a microphase-separation length scale from about 0.1 microns to about 500 microns, wherein the multiphase polymer composition comprises first solid functional particles selectively dispersed within the first polymer material, and wherein the first solid functional particles are chemically distinct from the first polymer material and the second polymer material. Some embodiments provide an anti-corrosion composition comprising first corrosion-inhibitor particles or precursors selectively dispersed within the first polymer material, wherein the multiphase polymer composition optionally further comprises second corrosion-inhibitor particles or precursors selectively dispersed within the second polymer material.

Abstract: A crystalline titanium and magnesium compound having an X-ray diffraction pattern having interplanar spacing (d-spacing) values at about 5.94, 3.10, 2.97, 2.10, 1.98, 1.82, and 1.74±0.1 angstroms may be used in protective coatings for metal or metal alloy substrates. The coatings exhibit excellent corrosion resistances and provide corrosion protection equal to or better than typical non-chromate coatings.

Abstract: Some variations provide a sensing system configured to measure the concentration of an antimicrobial agent in a polymer, comprising: a polymer containing (i) a discrete solid structural phase comprising a solid structural polymer and (ii) a continuous transport phase comprising a solid transport polymer and capable of containing the antimicrobial agent; and an antimicrobial-agent sensor that chemically senses the antimicrobial agent. The antimicrobial-agent sensor is disposed on a surface of, and in mass transport with, the polymer. The antimicrobial-agent sensor contains a responsive material disposed on or within a carrier material. The responsive material is chemically reactive with the antimicrobial agent and exhibits an observable and quantifiable property change upon chemically reacting with the antimicrobial agent. The observable and quantifiable property change may involve chromaticity, optical transparency, ionic conductivity, or electronic conductivity, for example.

Abstract: A vehicle, and a balancing device and method of controlling a state of charge of a reference electrode in a battery. The balancing device includes a measurement circuit and a charging circuit. The measurement circuit is configured to obtain a measurement of a reference voltage of the reference electrode. The charging circuit is configured to adjust the reference voltage based on the measurement. The state of charge of the reference electrode is controlled based on the reference voltage.

Abstract: A crystalline titanium and magnesium compound having an X-ray diffraction pattern having interplanar spacing (d-spacing) values at about 5.94, 3.10, 2.97, 2.10, 1.98, 1.82, and 1.74±0.1 angstroms may be used in protective coatings for metal or metal alloy substrates. The coatings exhibit excellent corrosion resistances and provide corrosion protection equal to or better than typical non-chromate coatings.

Abstract: Some variations provide a system for sensing a chemical active in a coating, the system comprising: a coating disposed on a substrate; a chemical active contained within the coating, wherein the chemical active is mobile within the coating, and wherein the chemical active is ionically and/or electrically conductive; a first electrode and a second electrode configured to measure AC impedance within the coating; and an electrical meter configured in electrical communication with the first and second electrodes to read a signal corresponding to the AC impedance. Some methods comprise: pressing electrodes against the coating; reading out an impedance value; and converting the impedance value to a concentration of the chemical active in the coating. Other methods comprise: adding a solvent to a coating surface; pressing electrodes against a surface region; reading out an impedance value; and converting the impedance value to a concentration of the chemical active in the coating.

Abstract: Antimicrobial coatings that are transparent and not easily stained are disclosed. Some variations provide a transparent antimicrobial structure comprising: a discrete solid structural phase comprising a solid structural polymer with a glass-transition temperature from 25° C. to 300° C.; a continuous transport phase interspersed within the discrete solid structural phase, wherein the continuous transport phase comprises a solid transport material; and an antimicrobial agent contained within the continuous transport phase, wherein the antimicrobial agent is dissolved in a fluid and/or in a solid solution with the continuous transport phase. The discrete solid structural phase and the continuous transport phase are separated by an average phase-separation length selected from 100 nanometers to 500 microns. This invention resolves the trade-off between antifouling and fluorinated material content. This invention also resolves the trade-off between transport of absorbed molecules and transparency.

Abstract: According to an embodiment of the present disclosure, a power management system (e.g., a power management for a fuel cell or a fuel cell system) includes a fuel cell to generate an electrical power output; a metastable hydrogen carrier to supply hydrogen to the fuel cell; a heater coupled with the metastable hydrogen carrier; and a controller coupled to the heater to control a rate of hydrogen release from the metastable hydrogen carrier. A method of operating a fuel cell system includes controlling an electrical power input to a heater utilizing a controller; heating a metastable hydrogen carrier to a temperature by the heater and to generate hydrogen to feed a fuel cell. The heater is coupled to the controller, and the controller controls the electrical power input to the heater according to a relationship between a rate of hydrogen release and the temperature and a composition of the metastable hydrogen carrier.

Abstract: A composition for hydrogen (H2) storage and generation including lithium aluminum hydride (LAIN is provided. The composition includes a mixture of LiAlH4 and a catalytic metal additive designed to tailor the kinetics of hydrogen release. The LiAlH4 and catalytic metal additive and are gently mixed together in order to physically disperse the LiAlH4 and catalyst powders without causing a detrimental chemical interaction. The hydrogen capacity of the composition is substantially not reduced or decreased (e.g., undergoes less than about 5% reduction) during the mixing process.

Abstract: Disclosed herein are surface-functionalized powders which alter the solidification of the melted powders. Some variations provide a powdered material comprising a plurality of particles fabricated from a first material, wherein each of the particles has a particle surface area that is continuously or intermittently surface-functionalized with nanoparticles and/or microparticles selected to control solidification of the powdered material from a liquid state to a solid state. Other variations provide a method of controlling solidification of a powdered material, comprising melting at least a portion of the powdered material to a liquid state, and semi-passively controlling solidification of the powdered material from the liquid state to a solid state. Several techniques for semi-passive control are described in detail.