Abstract: A method of charging a battery is provided that alters the amount of energy stored within the battery based upon a temperature profile across time. Battery materials and components, like liquid electrolyte or electrodes for instance, can be damaged when a rechargeable cell is exposed to elevated temperatures for extended amounts of time, thereby reducing the overall amount of energy that may be stored within the cell. This method monitors stored energy capacity and temperature. When a fully-charged cell is held at a temperature that exceeds a predetermined temperature threshold for an extended amount of time, the method discharges the cell, thereby reducing the amount of energy stored within the cell. For example, when a single, lithium-ion cell is maintained at 4.2 V for over 10 hours, the method will discharge the cell by roughly 1% or 50 mV. The discharge may be either automatic, or at the prompt of a user.

Abstract: A multiple cell capacitor (200) includes at least first and second capacitor cells (260) and a cell balancing circuit (265) electrically coupled to the first and second capacitor cells (260). Packaging material (280) encloses the first and second capacitor cells (260) and the cell balancing circuit (265). The cell balancing circuit (265) can include, for each capacitor cell (260), a resistor (265) formed electrically in parallel with that capacitor cell (260).

Abstract: Structures (1, 21, 41, 71, 161) of electrochemical cells and electrochemical cell components employ a switch-like article (10, 26, 48, 63, 65, 68, 76, 166) comprised of an electrically conducting material that becomes nonconductive or semiconductive outside of a discrete voltage window. Said switch-like article serves as a reversible, self-regulating electrochemical switch at boundary voltages, thereby protecting the cell against over-charge and or over-discharge, and can be employed in a variety of configurations to provide self-regulating cell architectures. Cell assemblies that include said switch-like articles may themselves serve an auxiliary function as switches for other cells placed in series or parallel, and for external circuits.

Abstract: An electrochemical cell 10 includes first and second electrodes 12 and 14 with an electrolyte system 26 disposed therebetween. The electrolyte system includes at least a multilayered first polymeric region 28, having second layers 30 and 32, of a second polymer material. The second layers may absorb an electrolyte active species and to adhere the adjacent layer of electrode material to the electrolyte 26. The electrolyte system further includes a process for packaging and curing the electrolyte after it has been incorporated into a discrete battery device.

Abstract: A hybrid electrode for a high power, high energy, electrical storage device contains both a high-energy electrode material (42) and a high-rate electrode material (44). The two materials are deposited on a current collector (40), and the electrode is used to make an energy storage device that exhibits both the high-rate capability of a capacitor and the high energy capability of a battery. The two materials can be co-deposited on the current collector in a variety of ways, either in superimposed layers, adjacent layers, intermixed with each other or one material coating the other to form a mixture that is then deposited on the current collector.

Abstract: An electrochemical cell 10 includes first and second electrodes 12 and 14 with an electrolyte system 26 disposed therebetween. The electrolyte system includes at least a multilayered first polymeric region 28, having second layers 30 and 32, of a second polymer material. The second layers may absorb an electrolyte active species and to adhere the adjacent layer of electrode material to the electrolyte 26. The electrolyte system further includes a process for packaging and curing the electrolyte after it has been incorporated into a discrete battery device.

Abstract: A method for making high power electrochemical capacitors (20) provides for depositing an electrically conducting polymer (24) onto a metal substrate (22). The electrically conducting polymer is initially grown in the presence of a soft anion, i.e., an anion having a high degree of polarizability. Subsequently, the polymer is treated with a relatively hard anion which at least partially replaces the soft anion in the polymer. The result is an electrochemical charge storage device which has enhanced electrochemical properties.