Abstract: Various embodiments relate to a method for producing a metal-organic framework (MOF) having a desired redox conductivity and including redox-active linkers, having ?-alkyl-ferrocene groups, via de novo solvothermal synthesis. Various embodiments relate to a metal-organic framework (MOF) linker comprising an ?-alkyl-ferrocene group. Various embodiments relate to a metal-organic framework (MOF), having a first plurality of redox-active linkers, each having an ?-alkyl-ferrocene group. The MOF according to various embodiments, may further have one or more redox-inactive linkers. Various embodiments relate to materials, apparatuses, and components that include the MOF according to various embodiments. For example, various embodiments relate to thin-films, bulk powders, or electrodes.

Abstract: Various embodiments relate to a method for producing a metal-organic framework (MOF) having a desired redox conductivity and including redox-active linkers, having ?-alkyl-ferrocene groups, via de novo solvothermal synthesis. Various embodiments relate to a metal-organic framework (MOF) linker comprising an ?-alkyl-ferrocene group. Various embodiments relate to a metal-organic framework (MOF), having a first plurality of redox-active linkers, each having an ?-alkyl-ferrocene group. The MOF according to various embodiments, may further have one or more redox-inactive linkers. Various embodiments relate to materials, apparatuses, and components that include the MOF according to various embodiments. For example, various embodiments relate to thin-films, bulk powders, or electrodes.

Abstract: Various embodiments relate to a method for producing a metal-organic framework (MOF) having a desired redox conductivity and including redox-active linkers, having ?-alkyl-ferrocene groups, via de novo solvothermal synthesis. Various embodiments relate to a metal-organic framework (MOF) linker comprising an ?-alkyl-ferrocene group. Various embodiments relate to a metal-organic framework (MOF), having a first plurality of redox-active linkers, each having an ?-alkyl-ferrocene group. The MOF according to various embodiments, may further have one or more redox-inactive linkers. Various embodiments relate to materials, apparatuses, and components that include the MOF according to various embodiments. For example, various embodiments relate to thin-films, bulk powders, or electrodes.

Abstract: Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00l crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO4 displayed room temperature conductivity up to 0.26 mS cm?1 and stability up to 10.0 V (vs. Li+/Li0). This outcome portends use of COFs as solid-state electrolytes in batteries.

Abstract: Disclosed herein are metal-organic frameworks and methods of making and use thereof.

Abstract: Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO4 displayed room temperature conductivity up to 0.26 mS cm?1 and stability up to 10.0 V (vs. Li+/Li0). This outcome portends use of COFs as solid-state electrolytes in batteries.

Abstract: Various embodiments relate to a method for producing a metal-organic framework (MOF) having a desired redox conductivity and including redox-active linkers, having w-alkyl-ferrocene groups, via de novo solvothermal synthesis. Various embodiments relate to a metal-organic framework (MOF) linker comprising an w-alkyl-ferrocene group. Various embodiments relate to a metal-organic framework (MOF), having a first plurality of redox-active linkers, each having an ?-alkyl-ferrocene group. The MOF according to various embodiments, may further have one or more redox-inactive linkers. Various embodiments relate to materials, apparatuses, and components that include the MOF according to various embodiments. For example, various embodiments relate to thin-films, bulk powders, or electrodes.

Abstract: Disclosed herein are metal-organic frameworks and methods of making and use thereof.

Abstract: Covalent organic frameworks (COFs) usually crystallize as insoluble powders and their processing for suitable devices has been thought to be limited. Here, it is demonstrated that COFs can be mechanically pressed into shaped objects having anisotropic ordering with preferred orientation between the hk0 and 00/ crystallographic planes. Pellets prepared from bulk COF powders impregnated with LiClO4 displayed room temperature conductivity up to 0.26 mS cm?1 and stability up to 10.0 V (vs. Li+/Li0). This outcome portends use of COFs as solid-state electrolytes in batteries.

Abstract: A dosing system for delivering a dosing fluid includes a dosing manifold having a front panel and a rear panel with a plurality of channels and a plurality of inlet and outlet ports in fluid communication with corresponding channels. The front panel holds a plurality of flow control devices in fluid communication with corresponding channels to control the flow of the dosing fluid in the channels. A dosing pump is in fluid communication with the dosing manifold and is configured to pump the dosing fluid through the dosing manifold.

Abstract: A dosing system for delivering a dosing fluid includes a dosing manifold having a front panel and a rear panel with a plurality of channels and a plurality of inlet and outlet ports in fluid communication with corresponding channels. The front panel holds a plurality of flow control devices in fluid communication with corresponding channels to control the flow of the dosing fluid in the channels. A dosing pump is in fluid communication with the dosing manifold and is configured to pump the dosing fluid through the dosing manifold.

Abstract: Regulatory regions from maize .alpha.-tubulin genes are disclosed. In particular, 5' regulatory regions comprising an upstream regulatory ensemble (URE) from maize .alpha.-tubulin 1 and 3 genes is useful in tissue specific expression of heterologous genes in transformed plants. The maize .alpha.-tubulin URE comprises regulatory elements which when operably linked to a promoter and heterologous gene, confer regulated expression in roots, pollen and meristematic tissues. Expression constructs which confer tissue specific expression are also provided.