Abstract: A thermal barrier layer (20) is formed by exposing an oxide ceramic material to a thermal regiment to create a surface heat affected zone effective to protect an underlying structural layer (18) of the material. The heat affected surface layer exhibits a lower strength and higher thermal conductivity than the underlying load-carrying material; however, it retains a sufficiently low thermal conductivity to function as an effective thermal barrier coating. Importantly, because the degraded material retains the same composition and thermal expansion characteristics as the underlying material, the thermal barrier layer remains integrally connected in graded fashion with the underlying material without an interface boundary there between.

Abstract: A hybrid structure (50) and method of manufacturing the same including a structural ceramic matrix composite (CMC) material (42) coated with a layer of ceramic insulating tiles (24). Individual ceramic tiles are attached to a surface (22) of a mold (20). The exterior surface (32) of the tiles may be subjected to a mechanical process such as machining with the mold in place to provide mechanical support for the tiles. A layer of CMC material is then applied to bond the tiles and the CMC material together into a hybrid structure. The mold may include a fugitive material portion (26) to facilitate removal of the mold when the hybrid structure has a complex shape. Tiles located in different regions of the structure may have different compositions and/or dimensions. The gaps between adjacent tiles may be filled from the outside before the CMC material is applied or from the inside after the mold is removed.

Abstract: A method of manufacturing a composite structure uses a layer of an insulating material (22) as a mold for forming a substrate of a ceramic matrix composite (CMC) material (24). The insulating material may be formed in the shape of a cylinder (10) with the CMC material wound on an outer surface (14) of the cylinder to form a gas turbine combustor liner (20). Alternatively, the insulating material may be formed in the shape of an airfoil section (32) with the CMC material formed on an inside surface (36) of the insulating material. The airfoil section may be formed of a plurality of halves (42, 44) to facilitate the lay-up of the CMC material onto an easily accessible surface, with the halves then joined together to form the complete composite airfoil. In another embodiment, a box structure (102) defining a hot gas flow passage (98) is manufactured by forming insulating material in the shape of opposed airfoil halves (104) joined at respective opposed ends by platform members (109).

Abstract: A method for making a material system includes the steps of: providing a chamber, placing hollow geometric shapes in the chamber, closing the chamber, evacuating air from the chamber, feeding a binder for the shapes into the evacuated chamber to impregnate the geometric shapes, drying the binder permeated geometric shapes, and heating the hollow shapes and binder to provide a unitary, sintered material system.

Abstract: An alumina comprising composition protective overlayer (20) for protecting a ceramic matrix composite material (12) from a high temperature, moisture-containing environment. Alumina may be used as a protective overlayer to protect an underlying mullite layer to temperatures in excess of 1,500° C. The coating may have porosity of greater than 15% for improved thermal shock protection. To prevent the ingress of oxygen to an underlying ceramic material, an oxide barrier layer may be optionally disposed between the alumina coating and the ceramic material. Such a protective overlayer may be used for an article having a ceramic oxide or non-oxide substrate.

Abstract: A method for making a thermal insulating material includes the steps of: providing a chamber, placing hollow geometric shapes in the chamber, closing the chamber, evacuating air from the chamber, feeding a slurry into an adjacent slurry chamber, pressurizing the slurry chamber and forcing the slurry in to the sphere chamber around the spheres against a fibrous material adjacent a side wall of the sphere chamber. The fibrous material allows capillary wicking of the liquid from the slurry around the spheres. Due to this pressure the spheres and slurry are semi dried into a green state. The material in its green state green is subsequently dried and fired to form the insulating material.

Abstract: A method of manufacturing a composite structure uses a layer of an insulating material (22) as a mold for forming a substrate of a ceramic matrix composite (CMC) material (24). The insulating material may be formed in the shape of a cylinder (10) with the CMC material wound on an outer surface (14) of the cylinder to form a gas turbine combustor liner (20). Alternatively, the insulating material may be formed in the shape of an airfoil section (32) with the CMC material formed on an inside surface (36) of the insulating material. The airfoil section may be formed of a plurality of halves (42, 44) to facilitate the lay-up of the CMC material onto an easily accessible surface, with the halves then joined together to form the complete composite airfoil. In another embodiment, a box structure (102) defining a hot gas flow passage (98) is manufactured by forming insulating material in the shape of opposed airfoil halves (104) joined at respective opposed ends by platform members (109).

Abstract: A hybrid structure (50) and method of manufacturing the same including a structural ceramic matrix composite (CMC) material (42) coated with a layer of ceramic insulating tiles (24). Individual ceramic tiles are attached to a surface (22) of a mold (20). The exterior surface (32) of the tiles may be subjected to a mechanical process such as machining with the mold in place to provide mechanical support for the tiles. A layer of CMC material is then applied to bond the tiles and the CMC material together into a hybrid structure. The mold may include a fugitive material portion (26) to facilitate removal of the mold when the hybrid structure has a complex shape. Tiles located in different regions of the structure may have different compositions and/or dimensions. The gaps between adjacent tiles may be filled from the outside before the CMC material is applied or from the inside after the mold is removed.

Abstract: A hybrid vane (50) for a gas turbine engine having a ceramic matrix composite (CMC) airfoil member (52) bonded to a substantially solid core member (54). The airfoil member and core member are cooled by a cooling fluid (58) passing through cooling passages (56) formed in the core member. The airfoil member is cooled by conductive heat transfer through the bond ((70) between the core member and the airfoil member and by convective heat transfer at the surface directly exposed to the cooling fluid. A layer of insulation (72) bonded to the external surface of the airfoil member provides both the desired outer aerodynamic contour and reduces the amount of cooling fluid required to maintain the structural integrity of the airfoil member. Each member of the hybrid vane is formulated to have a coefficient of thermal expansion and elastic modulus that will minimize thermal stress during fabrication and during turbine engine operation.

Abstract: An alumina comprising composition protective overlayer (20) for protecting a ceramic matrix composite material (12) from a high temperature, moisture-containing environment. Alumina may be used as a protective overlayer to protect an underlying mullite layer to temperatures in excess of 1,500° C. The coating may have porosity of greater than 15% for improved thermal shock protection. To prevent the ingress of oxygen to an underlying ceramic material, an oxide barrier layer may be optionally disposed between the alumina coating and the ceramic material. Such a protective overlayer may be used for an article having a ceramic oxide or non-oxide substrate.

Abstract: A hybrid vane (50) for a gas turbine engine having a ceramic matrix composite (CMC) airfoil member (52) bonded to a substantially solid core member (54). The airfoil member and core member are cooled by a cooling fluid (58) passing through cooling passages (56) formed in the core member. The airfoil member is cooled by conductive heat transfer through the bond ((70) between the core member and the airfoil member and by convective heat transfer at the surface directly exposed to the cooling fluid. A layer of insulation (72) bonded to the external surface of the airfoil member provides both the desired outer aerodynamic contour and reduces the amount of cooling fluid required to maintain the structural integrity of the airfoil member. Each member of the hybrid vane is formulated to have a coefficient of thermal expansion and elastic modulus that will minimize thermal stress during fabrication and during turbine engine operation.

Abstract: A method for making a thermal insulating material includes the steps of: providing a chamber, placing hollow geometric shapes in the chamber, closing the chamber, evacuating air from the chamber, feeding a slurry into an adjacent slurry chamber, pressurizing the slurry chamber and forcing the slurry in to the sphere chamber around the spheres against a fibrous material adjacent a side wall of the sphere chamber. The fibrous material allows capillary wicking of the liquid from the slurry around the spheres. Due to this pressure the spheres and slurry are semi dried into a green state. The material in its green state green is subsequently dried and fired to form the insulating material.

Abstract: A ceramic composition for insulating components, made of ceramic matrix composites, of gas turbines is provided. The composition comprises a plurality of hollow oxide-based spheres of various dimensions, a phosphate binder, and at least one oxide filler powder, whereby the phosphate binder partially fills gaps between the spheres and the filler powders. The spheres are situated in the phosphate binder and the filler powders such that each sphere is in contact with at least one other sphere and the arrangement of spheres is such that the composition is dimensionally stable and chemically stable at a temperature of approximately 1600° C. A stationary vane of a gas turbine comprising the composition of the present invention bonded to the outer surface of the vane is provided. A combustor comprising the composition bonded to the inner surface of the combustor is provided. A transition duct comprising the insulating coating bonded to the inner surface of the transition is provided.

Abstract: An oxide ceramic composite suitable for fabricating components of combustion turbines and similar high temperature environments. The composite is fabricated by dispersing metal particles in a fiber preform and infiltrating the fiber preform with sol-gel matrix precursor material. Alternatively, the metal particles are mixed into the sol-gel matrix precursor material and the preform is infiltrated with the mixture. Later in the fabrication process, the metal particles oxidize and become oxidized metal when the sol-gel matrix precursor material is sintered. The oxidized metal has more volume and mass than the metal particles. As a result, the oxidized metal contributes to increasing the density of the composite so that it is suitable for use in combustion turbines and similar high temperature environments.