Abstract: Gas-liquid separation comprising a) feeding a product stream comprising a mixture of liquid and gaseous hydrocarbon products and water vapour; b) collecting the first liquid at a liquid outlet of the first vapour-liquid separator; c) discharging the first gas stream from a gas outlet of the first vapour-liquid separator; d) feeding the first cooled mixture from the first cooler into a second vapour-liquid separator; e) collecting the second liquid at a liquid outlet of the second vapour-liquid separator; f) discharging the second gas stream from a gas outlet of the second vapour-liquid separator; g) feeding the second gas stream from the gas outlet of the second vapour-liquid separator through a second cooler; h) feeding the second cooled mixture from the second cooler into a third vapour-liquid separator; i) collecting the third liquid at a liquid outlet; and j) discharging the third gas stream from a gas outlet.

Abstract: The present disclosure relates generally to processes for initiating Fischer-Tropsch synthesis. In particular, the application concerns a process for the initiation of Fischer-Tropsch synthesis, the process comprising: (i) providing the reaction zone with a temperature of no more than 140° C.; then (ii) purging the reaction zone with a purge gas comprising N2 at a pressure in the range of 2 barg to 10 barg; then (iii) contacting the catalyst in the reaction zone with a gaseous reaction mixture comprising H2 and CO in a ratio of between 1:1 and 3:1 at a pressure of no more than 20 barg and at a temperature of no more than 140° C.; then (iv) heating the reaction zone to a temperature of at least 200° C.; and (v) pressurizing the reaction zone to a pressure in the range of 30 barg and 45 barg.

Abstract: The present disclosure relates generally to processes for activating Fischer-Tropsch synthesis catalysts. In particular, the application concerns a process for the activation of a Fischer-Tropsch synthesis catalyst, the process comprising: (i) contacting the catalyst with a first gaseous composition comprising at least 80% N2 at a pressure in the range of 2 barg to 20 barg at a temperature of no more than 150° C.; (ii) contacting the catalyst with a second gaseous composition comprising at least 80% H2 to form a H2/N2 gaseous composition with a H2:N2 molar ratio in the range of 0.2:1 to 2:1, resulting in a pressure in the range of 10 barg to 30 barg; (iii) increasing the temperature to a range of 220° C. to 260° C.; (iv) maintaining the catalyst at the conditions of step (iii) for a hold period in the range of 2 hr to 96 hr.

Abstract: A method is described for shutting down a Fischer-Tropsch reactor fed with a reactant gas mixture comprising a synthesis gas and a recycle gas recovered from the Fischer-Tropsch reactor in a synthesis loop, said Fischer-Tropsch reactor containing a Fischer-Tropsch catalyst cooled indirectly by a coolant under pressure, comprising the steps of: (a) depressurising the coolant to cool the reactant gas mixture to quench Fischer-Tropsch reactions taking place in the Fischer-Tropsch reactor, (b) stopping the synthesis gas feed to the Fischer-Tropsch reactor, and (c) maintaining circulation of the recycle gas through the Fischer-Tropsch reactor during steps (a) and (b) to remove heat from the Fischer-Tropsch reactor. The method safely facilitates a more rapid return to operating conditions than a full shut-down.

Abstract: A catalyst carrier for insertion into a reactor tube of a tubular reactor that comprises a container containing particles of catalyst. The container further contains a compacting element for reducing fluidisation of the particles of catalyst.

Abstract: A catalyst carrier for insertion into a reactor tube of a tubular reactor comprises a container for holding catalyst and a seal for sealing between the container and the reactor tube. The seal comprises at least a first seal layer and a second seal layer each comprising a plurality of deflectable tongues separated by notches. The second seal layer is rotationally offset relative to the first seal layer such that the notches of the second seal layer are aligned with the deflectable tongues of the first seal layer.

Abstract: A method of installing a thermocouple in a reactor tube of a tubular reactor, comprising lowering a weighted tow line through a stack of catalyst carriers and using a tow line to pull the thermocouple down the reactor tube through inner channels of the stack of catalyst carriers into a desired installation position.

Abstract: Process for converting synthesis gas to hydrocarbons in a slurry reactor in the presence of a Fischer-Tropsch catalyst comprising cobalt and zinc oxide. The process is carried out by a) activating the Fischer-Tropsch catalyst with a reducing gas consisting of hydrogen and an inert gas at a temperature between 330 and 400° C., and b) contacting the activated Fischer-Tropsch catalyst from step a) with synthesis gas in the slurry reactor in order to convert the synthesis gas into hydrocarbons.

Abstract: The present invention relates to a process for converting synthesis gas to hydrocarbons, in particular to hydrocarbons in the C5-C60 range particularly suitable for use as liquid motor fuels, in a slurry reactor in the presence of a Fischer-Tropsch catalyst comprising cobalt and zinc oxide wherein the Fischer-Tropsch catalyst is activated with a reducing gas consisting of hydrogen and an inert gas at 330 to 400° C. prior to contact with synthesis gas in the slurry reactor.

Abstract: A process for activating a cobalt-containing catalyst by contacting the catalyst with hydrogen in a reaction system suitable for use in a Fischer-Tropsch synthesis wherein a first gaseous stream comprising 0.25 to 5% by volume of hydrogen and 95 to 99.75% by volume of inert gas is continuously introduced into the reaction system and a second gaseous stream is continuously withdrawn from the reactor system wherein the activation procedure comprises the steps of: (A) heating the contents of the reactor system to a temperature which is in a range of 25 to 5° C. below a critical activation temperature; (B) thereafter increasing the temperature at a rate of up to 20° C. per hour to a first hold temperature which is in a range of from the critical activation temperature to a temperature which is at most 20° C. above the critical activation temperature; and (C) maintaining the contents of the reactor system approaches the hydrogen content of the first gaseous stream.

Abstract: A process for activating a cobalt-containing catalyst by contacting the catalyst with hydrogen in a reaction system suitable for use in a Fischer-Tropsch synthesis wherein a first gaseous stream comprising 0.25 to 5% by volume of hydrogen and 95 to 99.75% by volume of inert gas is continuously introduced into the reaction system and a second gaseous stream is continuously withdrawn from the reactor system wherein the activation procedure comprises the steps of: (A) heating the contents of the reactor system to a temperature which is in a range of 25 to 5° C. below a critical activation temperature; (B) thereafter increasing the temperature at a rate of up to 20° C. per hour to a first hold temperature which is in a range of from the critical activation temperature to a temperature which is at most 20° C. above the critical activation temperature; and (C) maintaining the contents of the reactor system approaches the hydrogen content of the first gaseous stream.