Publication number: 20180097220
Abstract: The present invention relates to a method for manufacturing a material of olivine crystallographic structure of formula (I) AaZzMmSiO4 in which A is chosen from Li, Na, K and mixtures thereof, Z is chosen from Be, Mg, Ca, Sr, Ba, and mixtures thereof, M is chosen from Fe, Ni, Co, Mn, Cr, and mixtures thereof, a, z and m are the stoichiometric coefficients, respectively, of A, Z and M, and satisfy the following conditions: z>0, m>0, a>0, a+z+m?2, and 2?(4?a?2z)/m<4, said method comprising at least the steps consisting in i. having a material of olivine crystallographic structure of formula (II) ZzMmSiO4, obtained by oxidation of a material of olivine crystallographic structure of formula (III) Zz?MmSiO4, in which Z, M, z and m are as defined above and the stoichiometric index z? is such that z?>z, and ii. electrochemically reducing said material of formula (II) in the presence of a source electrode made of element A under conditions that are suitable for forming the material of formula (I).
Type:
Application
Filed:
September 12, 2017
Publication date:
April 5, 2018
Applicant:
Commissariat A L'Energie Atomique et aux Energies Alternatives
Inventors:
Guillaume LEFEVRE, Jean-Baptiste DUCROS, Sebastien MARTINET
Publication number: 20180076456
Abstract: The present invention relates to a product constituted totally or partly by a material of olivine crystallographic structure of formula: AaZzMmSiO4 in which A is chosen from lithium (Li), sodium (Na), potassium (K) and mixtures thereof, Z is chosen from beryllium (Be), magnesium (Mg), calcium (Ca), strontium (Sr), barium (Ba), and mixtures thereof, M is chosen from iron (Fe), nickel (Ni), cobalt (Co), manganese (Mn), chromium (Cr), and mixtures thereof, a, z and m are the stoichiometric coefficients, respectively, of A, Z and M, and satisfy the following conditions: z>0, m>0, a>0, a+z+m?2, and 2?(4?a?2z)/m<4.
Type:
Application
Filed:
September 12, 2017
Publication date:
March 15, 2018
Applicant:
Commissariat A L'Energie Atomique et aux Energies Alternatives
Inventors:
Guillaume Lefevre, Jean-Baptiste Ducros, Sebastien Martinet