Patents by Inventor Jean-Francois Thierry

Jean-Francois Thierry has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20230071006
    Abstract: The present invention relates to a process for producing a highly concentrated aqueous solution of a salt of a diamine and dicarboxylic acid by using a pre-salt aqueous solution having a high concentration of diacid/diamine salt and an excess of dicarboxylic acid; and adding additional diamine to obtain the final diacid/diamine solution. The final diacid/diamine salt solution obtained is suitable for the manufacture of a polyamide such as for example polyamide 66.
    Type: Application
    Filed: December 23, 2020
    Publication date: March 9, 2023
    Inventors: Thomas TERNISIEN, Jean-Francois THIERRY
  • Patent number: 10975199
    Abstract: The present invention relates to a process for the production of an aqueous solution of a salt of a diamine and a diacid for the manufacture of polyamide.
    Type: Grant
    Filed: September 15, 2017
    Date of Patent: April 13, 2021
    Assignee: PolyTeclmyl SAS
    Inventors: Jean-François Thierry, Thomas Ternisien
  • Publication number: 20200339753
    Abstract: The present invention relates to a polyamide ester obtainable by polymerizing a polyamide salt, a polyhydric alcohol containing at least three hydroxyl groups, a dicarboxylic acid, and a chain limiting agent, wherein the polyhydric alcohol and the dicarboxylic acid are used in such amounts that the molar ratio of the excess of carboxylic acid groups from the dicarboxylic acid used to the molar equivalent amount of hydroxyl groups from the polyhydric alcohol used is at least 0.1.
    Type: Application
    Filed: December 20, 2018
    Publication date: October 29, 2020
    Applicant: BASF SE
    Inventors: Christophe MOINEAU, Jean-Francois THIERRY
  • Publication number: 20200317866
    Abstract: The present invention relates to a novel process for the production of a copolyamide comprising a polymerization product of hexamethylene diamine, adipic acid and terephthalic acid. A process for the production of a copolyamide comprising less than 50 mol % of units of hexamethylene terephthalamide may include (a) introducing an aqueous solvent and the monomers adipic acid, terephthalic acid and hexamethylene diamine, or salts thereof, into an evaporator to obtain a mixture; (b) concentrating the mixture obtained in step (a) in the evaporator by evaporation of at least part of the solvent, to obtain a concentrated mixture; (c) transferring the concentrated mixture obtained in step (b) into an autoclave; (d) polymerizing the monomers in the autoclave at a pressure of at least 1.
    Type: Application
    Filed: December 21, 2018
    Publication date: October 8, 2020
    Applicant: PolyTechnyl SAS
    Inventors: Jean-François Thierry, Christophe Moineau, Rémi-Gaël Aubert
  • Publication number: 20200017637
    Abstract: The present invention relates to a process for the production of an aqueous solution of a salt of a diamine and a diacid for the manufacture of polyamide.
    Type: Application
    Filed: September 15, 2017
    Publication date: January 16, 2020
    Applicant: RHODIA OPERATIONS
    Inventors: Jean-François Thierry, Thomas Ternisien
  • Patent number: 9856375
    Abstract: The invention pertains to A polyannide composition [composition (C)] comprising: —from 20 to 95% wt of at least one polyamide [polyamide (A)]; —from 1 to 30% wt of at least one branched polyamide different from polyamide (A), said branched polyamide comprising recurring units derived from polycondensation of a mixture [mixture (B)] comprising: —at least one polyamine monomer comprising at least three amine functional groups selected from the group consisting of secondary amine group of formula —NH— and primary amine group of formula -MH2 [monomer (FN)], and—?-caprolactam (or derivates thereof); said branched polyamide possessing a concentration of amine end groups (AEG) and a concentration of carboxylic end groups (CEG) such that the difference AEG?CEG is of at least 100 meq/kg [polyamide (B)]; and—from 0.01 to 3.
    Type: Grant
    Filed: November 7, 2014
    Date of Patent: January 2, 2018
    Assignee: Rhodia Operations
    Inventors: Stéphane Jeol, Thierry Badel, Jean-François Thierry
  • Patent number: 9656409
    Abstract: The present invention relates to a method for preparing polyamide granules. This method comprises, in particular, steps of extruding the polymer, cooling and cutting the extruded material, and a step of cooling the granules. The method of the invention is simple and quick to implement.
    Type: Grant
    Filed: October 24, 2012
    Date of Patent: May 23, 2017
    Assignee: Rhodia Operations
    Inventors: Jean-Francois Thierry, Phlippe Boulanger
  • Publication number: 20160289448
    Abstract: The invention pertains to A polyannide composition [composition (C)] comprising: —from 20 to 95% wt of at least one polyamide [polyamide (A)]; —from 1 to 30% wt of at least one branched polyamide different from polyamide (A), said branched polyamide comprising recurring units derived from polycondensation of a mixture [mixture (B)] comprising: —at least one polyamine monomer comprising at least three amine functional groups selected from the group consisting of secondary amine group of formula —NH— and primary amine group of formula -MH2 [monomer (FN)], and —?-caprolactam (or derivates thereof); said branched polyamide possessing a concentration of amine end groups (AEG) and a concentration of carboxylic end groups (CEG) such that the difference AEG?CEG is of at least 100 meq/kg [polyamide (B)]; and —from 0.01 to 3.
    Type: Application
    Filed: November 7, 2014
    Publication date: October 6, 2016
    Applicant: RHODIA OPERATIONS
    Inventors: Stéphane JEOL, Thierry BADEL, Jean-François THIERRY
  • Publication number: 20150197602
    Abstract: Modified polyamides are prepared by polymerization of diacid and diamine monomers in the presence of a multifunctional compound having either at least three acid functions or at least three basic functions and, optionally, a monofunctional compound having either an acid function or a basic function. These polyamides can be formulated into molding compositions which can be converted into useful shaped articles.
    Type: Application
    Filed: January 26, 2015
    Publication date: July 16, 2015
    Inventors: Lise TROUILLET-FONTI, Marco AMICI, Jean-Francois THIERRY
  • Patent number: 9062204
    Abstract: A process is described for producing a polyamide from at least one diacid and from at least one diamine. The process can include introducing a lactam and/or an amino acid after a step of concentrating an aqueous solution of a salt of diacid and diamine.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: June 23, 2015
    Assignee: RHODIA OPERATIONS
    Inventors: Audrey Di Martino, Thierry Charbonneaux, Jean-François Thierry
  • Publication number: 20140327171
    Abstract: The present invention relates to a method for preparing polyamide granules. This method comprises, in particular, steps of extruding the polymer, cooling and cutting the extruded material, and a step of cooling the granules. The method of the invention is simple and quick to implement.
    Type: Application
    Filed: October 24, 2012
    Publication date: November 6, 2014
    Applicant: RHODIA OPERATIONS
    Inventors: Jean-Francois Thierry, Phlippe Boulanger
  • Patent number: 8802810
    Abstract: A method for manufacturing a solution of a diacid and diamine salt for manufacturing polyamide is described. A method for manufacturing an aqueous solution of diacid and diamine salts produced by mixing at least two diacids and at least one diamine, with a weight concentration of salt between 40% and 70%, including, in a first step, preparing an aqueous solution of diacid(s) and diamine(s) with a diacid/diamine mole ratio of less than 1 using one diacid and one diamine, and in a second step, adjusting the mole ratio of diacids/diamine(s) to a value of between 0.9 and 1.1, and fixing the weight concentration of salt by adding another diacid and, optionally, additional water and/or diamine is also described.
    Type: Grant
    Filed: March 25, 2010
    Date of Patent: August 12, 2014
    Assignee: Rhodia Operations
    Inventors: Sébastien Lomel, Jean-Francois Thierry, Véronique Bossennec
  • Patent number: 8772439
    Abstract: Solutions of a salt of a diamine and of a diacid, more particularly concentrated solutions of hexamethylene diammonium adipate salt (“nylon salt”), useful starting materials for the production of polyamides, more specifically of PA66, are prepared by mixing a diacid and a diamine, at a salt concentration by weight of from 50% to 80%, in a first stage, to provide aqueous solutions of diacid and diamine having a diacid/diamine molar ratio of greater than 1.1 and, in a second stage, adjusting the diacid/diamine molar ratio, by adding diamine, to a value of from 0.9 to 1.1, preferably from 0.99 to 1.01, and in fixing the salt concentration by weight by, optionally, adding water thereto.
    Type: Grant
    Filed: May 22, 2008
    Date of Patent: July 8, 2014
    Assignee: Rhodia Operations
    Inventor: Jean-François Thierry
  • Patent number: 8759475
    Abstract: Polyamides, e.g., polyhexamethylene adipamide, are continuously produced via the following stages: Stage 1: into and through a reactor, polycondensing a liquid stream which contain the polyamide monomer(s) at a pressure P1 greater than atmospheric pressure, the stream of material at the outlet of the reactor including a vapor phase which contains steam and a liquid phase which at least contains the product of polycondensation; Stage 2: feeding the outlet stream of material into a chamber, evacuating at least a portion of the vapor phase therefrom and recovering at least the liquid phase which at least contains the product of polycondensation, the pressure P2 in the chamber being regulated at a set value such that it is greater than atmospheric pressure and the residence time of said liquid phase in the chamber being less than 5 minutes; and Stage 3: pressure reducing at least the liquid phase which at least contains the stream of polycondensation product recovered during Stage 2.
    Type: Grant
    Filed: March 25, 2008
    Date of Patent: June 24, 2014
    Assignee: Rhodia Operations
    Inventors: Jean-Francois Thierry, Sébastien Lomel, Vincent Mollet, Matthieu Helft, Cédric Fillon
  • Patent number: 8735530
    Abstract: A method for making polyamide is described. More particularly, a method for making a polyamide from at least one diacid and one diamine, that includes a step of concentrating an aqueous solution of diacid and diamine salt up to a salt weight concentration higher than 85%, and a polymerization step up to a desired polymerization degree is described.
    Type: Grant
    Filed: March 9, 2010
    Date of Patent: May 27, 2014
    Assignee: Rhodia Operations
    Inventors: Virginie Thieblemont, Jean-Francois Thierry
  • Publication number: 20130184413
    Abstract: The present invention relates to a process for the manufacture of polyamide. The invention relates more particularly to a process for the manufacture of polyamide from at least one diacid and from at least one diamine, comprising the introduction of lactam and/or of amino acid after a stage of concentration of an aqueous solution of salt of diacid and diamine.
    Type: Application
    Filed: April 21, 2011
    Publication date: July 18, 2013
    Applicant: RHODIA OPERATIONS
    Inventors: Audrey Di Martino, Thierry Charbonneaux, Jean-François Thierry
  • Publication number: 20120046439
    Abstract: A method for manufacturing a solution of a diacid and diamine salt for manufacturing polyamide is described. A method for manufacturing an aqueous solution of diacid and diamine salts produced by mixing at least two diacids and at least one diamine, with a weight concentration of salt between 40% and 70%, including, in a first step, preparing an aqueous solution of diacid(s) and diamine(s) with a diacid/diamine mole ratio of less than 1 using one diacid and one diamine, and in a second step, adjusting the mole ratio of diacids/diamine(s) to a value of between 0.9 and 1.1, and fixing the weight concentration of salt by adding another diacid and, optionally, additional water and/or diamine is also described.
    Type: Application
    Filed: March 25, 2010
    Publication date: February 23, 2012
    Applicant: Rhodia Operations
    Inventors: Sébastien Lomel, Jean-François Thierry, Véronique Bossennec
  • Publication number: 20120046438
    Abstract: A method for making polyamide is described. More particularly, a method for making a polyamide from at least one diacid and one diamine, that includes a step of concentrating an aqueous solution of diacid and diamine salt up to a salt weight concentration higher than 85%, and a polymerization step up to a desired polymerization degree is described.
    Type: Application
    Filed: March 9, 2010
    Publication date: February 23, 2012
    Applicant: Rhodia Operations
    Inventors: Virginie Thieblemont, Jean-Francois Thierry
  • Publication number: 20110275760
    Abstract: Novel modified polyamides are prepared by polymerization of diacid and diamine monomers in the presence of certain multifunctional and, optionally, monofunctional compounds; such novel polyamides are formulated into molding compositions which can be converted into useful shaped articles.
    Type: Application
    Filed: September 29, 2008
    Publication date: November 10, 2011
    Inventors: Lise Trouillet-Fonti, Marco Amici, Jean-Francois Thierry
  • Publication number: 20100168375
    Abstract: Solutions of a salt of a diamine and of a diacid, more particularly concentrated solutions of hexamethylene diammonium adipate salt (“nylon salt”), useful starting materials for the production of polyamides, more specifically of PA66, are prepared by mixing a diacid and a diamine, at a salt concentration by weight of from 50% to 80%, in a first stage, to provide aqueous solutions of diacid and diamine having a diacid/diamine molar ratio of greater than 1.1 and, in a second stage, adjusting the diacid/diamine molar ratio, by adding diamine, to a value of from 0.9 to 1.1, preferably from 0.99 to 1.01, and in fixing the salt concentration by weight by, optionally, adding water thereto.
    Type: Application
    Filed: May 22, 2008
    Publication date: July 1, 2010
    Inventor: Jean-Francois Thierry