Patents by Inventor Jean-Francois Thierry
Jean-Francois Thierry has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20230071006Abstract: The present invention relates to a process for producing a highly concentrated aqueous solution of a salt of a diamine and dicarboxylic acid by using a pre-salt aqueous solution having a high concentration of diacid/diamine salt and an excess of dicarboxylic acid; and adding additional diamine to obtain the final diacid/diamine solution. The final diacid/diamine salt solution obtained is suitable for the manufacture of a polyamide such as for example polyamide 66.Type: ApplicationFiled: December 23, 2020Publication date: March 9, 2023Inventors: Thomas TERNISIEN, Jean-Francois THIERRY
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Patent number: 10975199Abstract: The present invention relates to a process for the production of an aqueous solution of a salt of a diamine and a diacid for the manufacture of polyamide.Type: GrantFiled: September 15, 2017Date of Patent: April 13, 2021Assignee: PolyTeclmyl SASInventors: Jean-François Thierry, Thomas Ternisien
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Publication number: 20200339753Abstract: The present invention relates to a polyamide ester obtainable by polymerizing a polyamide salt, a polyhydric alcohol containing at least three hydroxyl groups, a dicarboxylic acid, and a chain limiting agent, wherein the polyhydric alcohol and the dicarboxylic acid are used in such amounts that the molar ratio of the excess of carboxylic acid groups from the dicarboxylic acid used to the molar equivalent amount of hydroxyl groups from the polyhydric alcohol used is at least 0.1.Type: ApplicationFiled: December 20, 2018Publication date: October 29, 2020Applicant: BASF SEInventors: Christophe MOINEAU, Jean-Francois THIERRY
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Publication number: 20200317866Abstract: The present invention relates to a novel process for the production of a copolyamide comprising a polymerization product of hexamethylene diamine, adipic acid and terephthalic acid. A process for the production of a copolyamide comprising less than 50 mol % of units of hexamethylene terephthalamide may include (a) introducing an aqueous solvent and the monomers adipic acid, terephthalic acid and hexamethylene diamine, or salts thereof, into an evaporator to obtain a mixture; (b) concentrating the mixture obtained in step (a) in the evaporator by evaporation of at least part of the solvent, to obtain a concentrated mixture; (c) transferring the concentrated mixture obtained in step (b) into an autoclave; (d) polymerizing the monomers in the autoclave at a pressure of at least 1.Type: ApplicationFiled: December 21, 2018Publication date: October 8, 2020Applicant: PolyTechnyl SASInventors: Jean-François Thierry, Christophe Moineau, Rémi-Gaël Aubert
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Publication number: 20200017637Abstract: The present invention relates to a process for the production of an aqueous solution of a salt of a diamine and a diacid for the manufacture of polyamide.Type: ApplicationFiled: September 15, 2017Publication date: January 16, 2020Applicant: RHODIA OPERATIONSInventors: Jean-François Thierry, Thomas Ternisien
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Patent number: 9856375Abstract: The invention pertains to A polyannide composition [composition (C)] comprising: —from 20 to 95% wt of at least one polyamide [polyamide (A)]; —from 1 to 30% wt of at least one branched polyamide different from polyamide (A), said branched polyamide comprising recurring units derived from polycondensation of a mixture [mixture (B)] comprising: —at least one polyamine monomer comprising at least three amine functional groups selected from the group consisting of secondary amine group of formula —NH— and primary amine group of formula -MH2 [monomer (FN)], and—?-caprolactam (or derivates thereof); said branched polyamide possessing a concentration of amine end groups (AEG) and a concentration of carboxylic end groups (CEG) such that the difference AEG?CEG is of at least 100 meq/kg [polyamide (B)]; and—from 0.01 to 3.Type: GrantFiled: November 7, 2014Date of Patent: January 2, 2018Assignee: Rhodia OperationsInventors: Stéphane Jeol, Thierry Badel, Jean-François Thierry
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Patent number: 9656409Abstract: The present invention relates to a method for preparing polyamide granules. This method comprises, in particular, steps of extruding the polymer, cooling and cutting the extruded material, and a step of cooling the granules. The method of the invention is simple and quick to implement.Type: GrantFiled: October 24, 2012Date of Patent: May 23, 2017Assignee: Rhodia OperationsInventors: Jean-Francois Thierry, Phlippe Boulanger
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Publication number: 20160289448Abstract: The invention pertains to A polyannide composition [composition (C)] comprising: —from 20 to 95% wt of at least one polyamide [polyamide (A)]; —from 1 to 30% wt of at least one branched polyamide different from polyamide (A), said branched polyamide comprising recurring units derived from polycondensation of a mixture [mixture (B)] comprising: —at least one polyamine monomer comprising at least three amine functional groups selected from the group consisting of secondary amine group of formula —NH— and primary amine group of formula -MH2 [monomer (FN)], and —?-caprolactam (or derivates thereof); said branched polyamide possessing a concentration of amine end groups (AEG) and a concentration of carboxylic end groups (CEG) such that the difference AEG?CEG is of at least 100 meq/kg [polyamide (B)]; and —from 0.01 to 3.Type: ApplicationFiled: November 7, 2014Publication date: October 6, 2016Applicant: RHODIA OPERATIONSInventors: Stéphane JEOL, Thierry BADEL, Jean-François THIERRY
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Publication number: 20150197602Abstract: Modified polyamides are prepared by polymerization of diacid and diamine monomers in the presence of a multifunctional compound having either at least three acid functions or at least three basic functions and, optionally, a monofunctional compound having either an acid function or a basic function. These polyamides can be formulated into molding compositions which can be converted into useful shaped articles.Type: ApplicationFiled: January 26, 2015Publication date: July 16, 2015Inventors: Lise TROUILLET-FONTI, Marco AMICI, Jean-Francois THIERRY
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Patent number: 9062204Abstract: A process is described for producing a polyamide from at least one diacid and from at least one diamine. The process can include introducing a lactam and/or an amino acid after a step of concentrating an aqueous solution of a salt of diacid and diamine.Type: GrantFiled: April 21, 2011Date of Patent: June 23, 2015Assignee: RHODIA OPERATIONSInventors: Audrey Di Martino, Thierry Charbonneaux, Jean-François Thierry
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Publication number: 20140327171Abstract: The present invention relates to a method for preparing polyamide granules. This method comprises, in particular, steps of extruding the polymer, cooling and cutting the extruded material, and a step of cooling the granules. The method of the invention is simple and quick to implement.Type: ApplicationFiled: October 24, 2012Publication date: November 6, 2014Applicant: RHODIA OPERATIONSInventors: Jean-Francois Thierry, Phlippe Boulanger
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Patent number: 8802810Abstract: A method for manufacturing a solution of a diacid and diamine salt for manufacturing polyamide is described. A method for manufacturing an aqueous solution of diacid and diamine salts produced by mixing at least two diacids and at least one diamine, with a weight concentration of salt between 40% and 70%, including, in a first step, preparing an aqueous solution of diacid(s) and diamine(s) with a diacid/diamine mole ratio of less than 1 using one diacid and one diamine, and in a second step, adjusting the mole ratio of diacids/diamine(s) to a value of between 0.9 and 1.1, and fixing the weight concentration of salt by adding another diacid and, optionally, additional water and/or diamine is also described.Type: GrantFiled: March 25, 2010Date of Patent: August 12, 2014Assignee: Rhodia OperationsInventors: Sébastien Lomel, Jean-Francois Thierry, Véronique Bossennec
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Patent number: 8772439Abstract: Solutions of a salt of a diamine and of a diacid, more particularly concentrated solutions of hexamethylene diammonium adipate salt (“nylon salt”), useful starting materials for the production of polyamides, more specifically of PA66, are prepared by mixing a diacid and a diamine, at a salt concentration by weight of from 50% to 80%, in a first stage, to provide aqueous solutions of diacid and diamine having a diacid/diamine molar ratio of greater than 1.1 and, in a second stage, adjusting the diacid/diamine molar ratio, by adding diamine, to a value of from 0.9 to 1.1, preferably from 0.99 to 1.01, and in fixing the salt concentration by weight by, optionally, adding water thereto.Type: GrantFiled: May 22, 2008Date of Patent: July 8, 2014Assignee: Rhodia OperationsInventor: Jean-François Thierry
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Patent number: 8759475Abstract: Polyamides, e.g., polyhexamethylene adipamide, are continuously produced via the following stages: Stage 1: into and through a reactor, polycondensing a liquid stream which contain the polyamide monomer(s) at a pressure P1 greater than atmospheric pressure, the stream of material at the outlet of the reactor including a vapor phase which contains steam and a liquid phase which at least contains the product of polycondensation; Stage 2: feeding the outlet stream of material into a chamber, evacuating at least a portion of the vapor phase therefrom and recovering at least the liquid phase which at least contains the product of polycondensation, the pressure P2 in the chamber being regulated at a set value such that it is greater than atmospheric pressure and the residence time of said liquid phase in the chamber being less than 5 minutes; and Stage 3: pressure reducing at least the liquid phase which at least contains the stream of polycondensation product recovered during Stage 2.Type: GrantFiled: March 25, 2008Date of Patent: June 24, 2014Assignee: Rhodia OperationsInventors: Jean-Francois Thierry, Sébastien Lomel, Vincent Mollet, Matthieu Helft, Cédric Fillon
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Patent number: 8735530Abstract: A method for making polyamide is described. More particularly, a method for making a polyamide from at least one diacid and one diamine, that includes a step of concentrating an aqueous solution of diacid and diamine salt up to a salt weight concentration higher than 85%, and a polymerization step up to a desired polymerization degree is described.Type: GrantFiled: March 9, 2010Date of Patent: May 27, 2014Assignee: Rhodia OperationsInventors: Virginie Thieblemont, Jean-Francois Thierry
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Publication number: 20130184413Abstract: The present invention relates to a process for the manufacture of polyamide. The invention relates more particularly to a process for the manufacture of polyamide from at least one diacid and from at least one diamine, comprising the introduction of lactam and/or of amino acid after a stage of concentration of an aqueous solution of salt of diacid and diamine.Type: ApplicationFiled: April 21, 2011Publication date: July 18, 2013Applicant: RHODIA OPERATIONSInventors: Audrey Di Martino, Thierry Charbonneaux, Jean-François Thierry
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Publication number: 20120046439Abstract: A method for manufacturing a solution of a diacid and diamine salt for manufacturing polyamide is described. A method for manufacturing an aqueous solution of diacid and diamine salts produced by mixing at least two diacids and at least one diamine, with a weight concentration of salt between 40% and 70%, including, in a first step, preparing an aqueous solution of diacid(s) and diamine(s) with a diacid/diamine mole ratio of less than 1 using one diacid and one diamine, and in a second step, adjusting the mole ratio of diacids/diamine(s) to a value of between 0.9 and 1.1, and fixing the weight concentration of salt by adding another diacid and, optionally, additional water and/or diamine is also described.Type: ApplicationFiled: March 25, 2010Publication date: February 23, 2012Applicant: Rhodia OperationsInventors: Sébastien Lomel, Jean-François Thierry, Véronique Bossennec
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Publication number: 20120046438Abstract: A method for making polyamide is described. More particularly, a method for making a polyamide from at least one diacid and one diamine, that includes a step of concentrating an aqueous solution of diacid and diamine salt up to a salt weight concentration higher than 85%, and a polymerization step up to a desired polymerization degree is described.Type: ApplicationFiled: March 9, 2010Publication date: February 23, 2012Applicant: Rhodia OperationsInventors: Virginie Thieblemont, Jean-Francois Thierry
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Publication number: 20110275760Abstract: Novel modified polyamides are prepared by polymerization of diacid and diamine monomers in the presence of certain multifunctional and, optionally, monofunctional compounds; such novel polyamides are formulated into molding compositions which can be converted into useful shaped articles.Type: ApplicationFiled: September 29, 2008Publication date: November 10, 2011Inventors: Lise Trouillet-Fonti, Marco Amici, Jean-Francois Thierry
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Publication number: 20100168375Abstract: Solutions of a salt of a diamine and of a diacid, more particularly concentrated solutions of hexamethylene diammonium adipate salt (“nylon salt”), useful starting materials for the production of polyamides, more specifically of PA66, are prepared by mixing a diacid and a diamine, at a salt concentration by weight of from 50% to 80%, in a first stage, to provide aqueous solutions of diacid and diamine having a diacid/diamine molar ratio of greater than 1.1 and, in a second stage, adjusting the diacid/diamine molar ratio, by adding diamine, to a value of from 0.9 to 1.1, preferably from 0.99 to 1.01, and in fixing the salt concentration by weight by, optionally, adding water thereto.Type: ApplicationFiled: May 22, 2008Publication date: July 1, 2010Inventor: Jean-Francois Thierry