Patents by Inventor Jean-Marc Marechal

Jean-Marc Marechal has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20210340297
    Abstract: A rubber composition is based on an elastomeric matrix comprising at least 50 phr of butadiene elastomer, at most 60 phr of filler comprising from 5 to 30 phr of carbon black which predominantly comprises a carbon black termed black G, and from 2 to 30 phr of inorganic filler. A finished or semi-finished rubber item and a tire are made from this composition.
    Type: Application
    Filed: June 13, 2019
    Publication date: November 4, 2021
    Inventors: KARIM EL-OTHMANI, JEAN-MARC MARECHAL
  • Patent number: 10562985
    Abstract: A modified diene elastomer is provided. The elastomer comprises: at least 70% by weight, with respect to the total weight of the modified diene elastomer, of a linear diene elastomer functionalized predominantly in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, the alkoxysilane group optionally bearing another functional group capable of interacting with a reinforcing filler, the alkoxysilane group bonded to the two branches of the diene elastomer via the silicon atom, the functionalized diene elastomer exhibiting a polydispersity index before fractionalization of less than or equal to 1.6; and more than 0 and up to 30% by weight, with respect to the total weight of the modified diene elastomer, of a star-branched diene elastomer exhibiting a polydispersity index before star-branching of less than or equal to 1.6, the Mooney viscosity of the modified diene elastomer varying from 30 to 80.
    Type: Grant
    Filed: July 1, 2016
    Date of Patent: February 18, 2020
    Assignee: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Marie-Hélène Dessendier, Charlotte Dire, Margarita Dorato, Jean Marc Marechal, Florent Vaultier
  • Patent number: 10233312
    Abstract: A modified diene elastomer comprises: at least 55% by weight of entity coupled by a functional group bearing a function of formula —SiOR, in which R is a hydrogen atom or an alkyl radical, and optionally bearing another function capable of interacting with a reinforcing filler, from 5% by weight to 30% by weight of star-branched entity having three elastomeric branches connected to one and the same silicon atom belonging to a functional group bearing or not bearing a function capable of interacting with a reinforcing filler, less than or equal to 15% by weight of entity functionalized at the chain end by a functional group bearing a function —Si(OR)2, in which R is a hydrogen atom or an alkyl radical, and optionally bearing another function capable of interacting with a reinforcing filler, and a content of less than or equal to 15% by weight of non-functional diene elastomer.
    Type: Grant
    Filed: July 31, 2014
    Date of Patent: March 19, 2019
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte Dire, Jean-Marc Marechal, Margarita Dorato, Mathieu Manceau, Nuno Pacheco
  • Patent number: 10189914
    Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by a silanol group, the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine functional group.
    Type: Grant
    Filed: August 4, 2014
    Date of Patent: January 29, 2019
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Charlotte Dire, Jean-Marc Marechal, Nicolas Seeboth
  • Patent number: 10093750
    Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolyzed to give silanol, bearing a tertiary amine functional group and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine functional group.
    Type: Grant
    Filed: August 4, 2014
    Date of Patent: October 9, 2018
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Charlotte Dire, Jean Marc Marechal, Nicolas Seeboth
  • Patent number: 10093751
    Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolyzed to give silanol, bearing an epoxide function and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine function.
    Type: Grant
    Filed: October 29, 2014
    Date of Patent: October 9, 2018
    Assignees: COMPAGNIE GENERALE DES ESTABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte Dire, Jean-Marc Marechal, Nicolas Seeboth
  • Publication number: 20180194866
    Abstract: A modified diene elastomer is provided. The elastomer comprises: at least 70% by weight, with respect to the total weight of the modified diene elastomer, of a linear diene elastomer functionalized predominantly in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, the alkoxysilane group optionally bearing another functional group capable of interacting with a reinforcing filler, the alkoxysilane group bonded to the two branches of the diene elastomer via the silicon atom, the functionalized diene elastomer exhibiting a polydispersity index before fractionalization of less than or equal to 1.6; and more than 0 and up to 30% by weight, with respect to the total weight of the modified diene elastomer, of a star-branched diene elastomer exhibiting a polydispersity index before star-branching of less than or equal to 1.6, the Mooney viscosity of the modified diene elastomer varying from 30 to 80.
    Type: Application
    Filed: July 1, 2016
    Publication date: July 12, 2018
    Applicant: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Marie-Hélène DESSENDIER, Charlotte DIRE, Margarita DORATO, Jean Marc MARECHAL, Florent VAULTIER
  • Publication number: 20180194867
    Abstract: A system for the continuous synthesis of a modified diene elastomer is provided. The system comprises a device for modifying a living diene elastomer resulting from an anionic polymerization step, modelled on one of the following models: 1. a tubular reactor with axial dispersion, 2. a tubular reactor with axial dispersion, in series with at least one continuous stirred reactor, presumed to be perfectly stirred, 3. at least one tubular reactor with axial dispersion, in series with a continuous stirred reactor, presumed to be perfectly stirred, 4. several tubular reactors with axial dispersion, in series with several continuous stirred reactors, presumed to be perfectly stirred, 5. at least two continuous stirred reactors, presumed to be perfectly stirred, in series.
    Type: Application
    Filed: January 22, 2018
    Publication date: July 12, 2018
    Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Charlotte DIRE, Jean-Marc MARECHAL, Margarita DORATO, Mathieu MANCEAU, Nuno PACHECO
  • Patent number: 9908949
    Abstract: A continuous method for synthesizing a diene elastomer includes modifying the diene elastomer in a functionalizing device by: a kinetic model according to which the ratio of the rate constants is greater than 1, and a flow represented by a residence time distribution in the functionalizing device that is expressed according to equations 1 or 3: (i) in a functionalizing device having at least one tubular continuous reactor or having at least one cascade of at least two stirred reactors, E 1 ? ( t ) = 1 2 ? ( P ?? 1 ? t ) 1 2 ? e - P ? ( ? 1 - t ) 2 4 ? ? 1 ? t Eq ? ? 1 (ii) in a functionalizing device that is a combination of the device (i) and of a device having at least one continuous stirred reactor, having a residence time distribution characterized by the following equation: E 2 ? ( t ) = e ( - t ? 2 ) ? 2 Eq ? ? 2 the device (ii) having a residence time distribution characterized by the
    Type: Grant
    Filed: July 11, 2014
    Date of Patent: March 6, 2018
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Charlotte Dire, Jean-Marc Marechal, Margarita Dorato, Mathieu Manceau, Nuno Pacheco
  • Patent number: 9856330
    Abstract: The present invention relates to a modified diene elastomer predominantly comprising a species coupled via a group bearing a function comprising a silicon atom predominantly hydrolyzed into silanol and a tertiary amine function, linked to the diene elastomer via the silicon atom, and to the process for synthesizing the modified diene elastomer. This elastomer has the particular feature of not undergoing any change in Mooney viscosity during its storage.
    Type: Grant
    Filed: July 11, 2014
    Date of Patent: January 2, 2018
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE
    Inventors: Charlotte Dire, Jean-Marc Marechal, Margarita Dorato
  • Patent number: 9670291
    Abstract: The present invention relates to a specific functionalized diene elastomer. This functionalized elastomer exhibits a reduced cold flow without, however, damaging the properties of a reinforced rubber composition in which it is present, in particular the processing properties and the hysteresis properties. This functionalized diene elastomer carries, at the chain end, a silanol functional group or a polysiloxane block having a silanol end and is partially coupled by or star-branched by tin.
    Type: Grant
    Filed: October 7, 2010
    Date of Patent: June 6, 2017
    Assignees: Compagnie Generale des Etablissements Michelin, Michelin Recherche et Technique S.A.
    Inventors: Jean-Marc Marechal, Stéphanie De Landtsheer, Jean-Michel Favrot
  • Patent number: 9624359
    Abstract: The invention relates to a functionalized diene elastomer composed: a) of a diene elastomer functionalized, at the chain end or in the middle of the chain, by a tin functional group, exhibiting a monomodal distribution of molecular weights before functionalization and a polydispersity index before functionalization of less than or equal to 1.3, b) of a diene elastomer star-branched with a tin compound, exhibiting a monomodal distribution of molecular weights before star-branching and a polydispersity index before star-branching of less than or equal to 1.3, and c) of a content of less than 15% by weight, with respect to the total weight of the functionalized diene elastomer, of a non-tin-functional diene elastomer, the said diene elastomers a), b) and c) being, before optional functionalization or optional star-branching, the same in nature.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: April 18, 2017
    Assignees: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Mathilde Abad, Margarita Dorato, Jean-Michel Favrot, Nathalie Simon, Jean Marc Marechal, Stéphanie De Landtsheer
  • Publication number: 20160319045
    Abstract: A modified diene elastomer, a process of preparing the elastomer is provided. The modified diene elastomer comprises: (i) from 40 to 80% by weight of the entity functionalized at the chain end by an alkylalkoxysilane group, optionally partially or completely hydrolysed to give silanol, bearing a primary, secondary or tertiary amine function, and bonded to the elastomer via the silicon atom, (ii) from 5 to 45% by weight of the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, bearing a primary, secondary or tertiary amine function, and the silicon atom of which bonds the two pieces of the chain, (iii) from 3 to 30% by weight of the three-branch star-branched entity containing a silane functional group, bearing a primary, secondary or tertiary amine function, and the silicon atom of which bonds the three branches of the chain.
    Type: Application
    Filed: December 18, 2014
    Publication date: November 3, 2016
    Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte DIRE, Jean-Marc MARECHAL, Margarita DORATO
  • Publication number: 20160280806
    Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, bearing an epoxide function and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine function.
    Type: Application
    Filed: October 29, 2014
    Publication date: September 29, 2016
    Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte DIRE, Jean-Marc MARECHAL, Nicolas SEEBOTH
  • Publication number: 20160237219
    Abstract: The invention relates to a triblock diene elastomer, the central block of which is a polyether block having a number-average molecular weight ranging from 150 to 5000 g/mol and is connected via a silicon atom to each of the lateral blocks, and the chain ends of which are functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine function.
    Type: Application
    Filed: September 24, 2014
    Publication date: August 18, 2016
    Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte DIRE, Jean Marc MARECHAL, Nicolas SEEBOTH
  • Publication number: 20160176993
    Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by a silanol group, the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine functional group.
    Type: Application
    Filed: August 4, 2014
    Publication date: June 23, 2016
    Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte DIRE, Jean-Marc MARECHAL, Nicolas SEEBOTH
  • Publication number: 20160176992
    Abstract: The invention relates to a modified diene elastomer comprising predominantly the entity functionalized in the middle of the chain by an alkoxysilane group, optionally partially or completely hydrolysed to give silanol, bearing a tertiary amine functional group and the silicon atom of which bonds the two pieces of the chain, the chain ends of the modified diene elastomer being functionalized to at least 70 mol %, with respect to the number of moles of chain end, by an amine functional group.
    Type: Application
    Filed: August 4, 2014
    Publication date: June 23, 2016
    Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte DIRE, Jean-Marc MARECHAL, Nicolas SEEBOTH
  • Publication number: 20160160015
    Abstract: A modified diene elastomer comprises: at least 55% by weight of entity coupled by a functional group bearing a function of formula —SiOR, in which R is a hydrogen atom or an alkyl radical, and optionally bearing another function capable of interacting with a reinforcing filler, from 5% by weight to 30% by weight of star-branched entity having three elastomeric branches connected to one and the same silicon atom belonging to a functional group bearing or not bearing a function capable of interacting with a reinforcing filler, less than or equal to 15% by weight of entity functionalized at the chain end by a functional group bearing a function —Si(OR)2, in which R is a hydrogen atom or an alkyl radical, and optionally bearing another function capable of interacting with a reinforcing filler, and a content of less than or equal to 15% by weight of non-functional diene elastomer.
    Type: Application
    Filed: July 31, 2014
    Publication date: June 9, 2016
    Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE, S.A.
    Inventors: Charlotte DIRE, Jean-Marc MARECHAL, Margarita DORATO, Mathieu MANCEAU, Nuno PACHECO
  • Patent number: 9109109
    Abstract: The invention relates to a functionalized diene elastomer composed a) of a specific block copolymer functionalized, at the chain end or in the middle of the chain, by a tin functional group, b) of a specific block copolymer star-branched by tin and c) of a content of less than 15% by weight, with respect to the total weight of the functionalized diene elastomer, of a specific non-tin-functional block copolymer.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: August 18, 2015
    Assignees: COMPAGNIE GENERALE DES ESTABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Mathilde Abad, Margarita Dorato, Jean-Michel Favrot, Nathalie Simon, Jean Marc Marechal, Stéphanie De Landtsheer
  • Patent number: 8927643
    Abstract: The invention relates to a block diene elastomer corresponding to the following formula: where: n and m are each an integer of greater than or equal to 0, such that n+m?1 and n+m?20, each A block is composed of a polybutadiene, each B block is composed of a diene elastomer, the molar content of units resulting from conjugated dienes of which is greater than 15%, the B blocks being identical to one another, X is an organic or inorganic group which can comprise a functional group which interacts with a reinforcing filler, the number-average molecular weight Mn1 of each A block varies from 2 500 to 20 000 g/mol, the number-average molecular weight Mn2 of each B block varies from 80 000 to 350 000 g/mol, and the content of 1,2- linkages in each A block is between 1 and 20%.
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: January 6, 2015
    Assignees: Compagnie General des Etablissements, Michelin Recherche et Technique S.A.
    Inventors: Jean-Michel Favrot, Nathalie Simon, Jean Marc Marechal