Abstract: The present invention relates to a negative electrode active material for a secondary battery and a manufacturing method thereof. A negative electrode active material, according to one embodiment of the present invention, comprises silicon-based primary particles, and a particle size distribution of the silicon-based primary particles is D10?50 nm and D90?150 nm. The negative electrode active material suppresses or reduces tensile hoop stress generated in lithiated silicon particles during a charging of a battery to thus suppress a crack due to a volume expansion of the silicon particles and/or an irreversible reaction caused by the crack, such that the lifetime and capacity of the battery can be improved.

Abstract: Disease prediction using analyte measurements and machine learning is described. In one or more implementations, a combination of features of analyte measurements may be selected from a plurality of features of the analyte measurements based on a robustness metric and a performance metric of the combination, and a machine learning model may be trained to predict a health condition classification using the combination. The performance metric may be associated with an accuracy of predicting the health condition classification, and the robustness metric may be associated with an insensitivity to analyte sensor manufacturing variabilities on the accuracy. Once trained, the machine learning model predicts the health condition classification for a user based on analyte measurements of the user collected by a wearable analyte monitoring device. The combination of features may be extracted from the analyte measurements of the user and input into the machine learning model to predict the classification.

Abstract: Various embodiments generally relate to a method for forming a graphene barrier layer for a semiconductor device, and more particularly, to a method of forming a barrier thin film including a graphene layer capable of reducing the contact resistance of a metal interconnect. A method for forming a graphene barrier layer according to an embodiment includes: loading a substrate, which has a titanium-containing layer formed thereon, in a chamber of a substrate processing system, the chamber having a processing space formed therein; inducing nucleation on the titanium-containing layer by supplying a first reactant gas including a unsaturated hydrocarbon into the chamber; and forming a graphene layer on the titanium-containing layer by supplying a second reactant gas including a saturated hydrocarbon into the chamber.

Abstract: The present invention relates to a cathode active material for a secondary battery and a manufacturing method thereof. A cathode active material, according to one embodiment of the present invention, comprises silicon-based primary particles, and a particle size distribution of the silicon-based primary particles is D10?50 nm and D90?150 nm. The cathode active material suppresses or reduces tensile hoop stress generated in lithiated silicon particles during a charging of a battery to thus suppress a crack due to a volume expansion of the silicon particles and/or an irreversible reaction caused by the crack, such that the lifetime and capacity of the battery can be improved.

Abstract: The present invention relates to a method for preparing silicon-based active material particles for a secondary battery and silicon-based active material particles. The method for preparing silicon-based active material particles according to an embodiment of the present invention comprises the steps of: providing silicon powder; dispersing the silicon powder into an oxidant solvent to provide a mixture prior to grinding; fine-graining the silicon powder by applying mechanical compression and shear stress to the silicon powder in the mixture prior to grinding to produce silicon particles; producing a layer of chemical oxidation on the fine-grained silicon particles with the oxidant solvent while applying mechanical compression and shear stress to produce silicon-based active material particles; and drying the resulting product comprising the silicon-based active material particles to yield silicon-based active material particles.

Abstract: The present invention relates to a method for producing silicon-based active material particles for a secondary battery and silicon-based active material particles. A method for producing silicon-based active material particles for a secondary battery according to an embodiment of the present invention may comprise: a step of providing silicon powder; a step of providing a pre-pulverization mixture in which the silicon powder is dispersed in a solvent for dispersion comprising an antioxidant; a step of applying mechanical compression and shear stress to the silicon powder of the pre-pulverization mixture to refine the silicon powder, thereby forming silicon particles having an oxygen content controlled by the antioxidant; and a step of drying the resulting material comprising the silicon particles to obtain silicon-based active material particles.

Abstract: The present invention relates to a silicon-based anode active material and a method of fabricating the same. The silicon-based anode active material according to an embodiment of the present invention comprises: particles comprising silicon and oxygen combined with the silicon, wherein a carbon-based conductive layer is coated with on outermost surface of the particles; and phosphorus doped in the particles, wherein a content of the phosphorus with respect to a total weight of the particles and the phosphorus doped in the particles have a range of 0.01 wt % to 15 wt %, and a content of the oxygen has a range of 9.5 wt % to 25 wt %.

Abstract: The present invention relates to a silicon-based anode active material and a method for manufacturing the same. The silicon-based anode active material according to an embodiment of the present invention comprises: particles comprising silicon and oxygen combined with the silicon, and having a carbon-based conductive film coated on the outermost periphery thereof; and boron doped inside the particles, wherein with respect to the total weight of the particles and the doped boron, the boron is included in the amount of 0.01 weight % to 17 weight %, and the oxygen is included in the amount of 16 weight % to 29 weight %.

Abstract: Provided is an anode active material for a secondary battery and a method of fabricating the anode active material. A silicon-based active material composite according to an embodiment of the inventive concept includes silicon and silicon oxide obtained by oxidizing at least a part of the silicon, and an amount of oxygen with respect to a total weight of the silicon and the silicon oxide is restricted to 9 wt % to 20 wt %.

Abstract: The present invention relates to a silicon anode active material capable of high capacity and high output, and a method for fabricating the same. A silicon anode active material according to an embodiment of the present invention includes a silicon core including silicon particles; and a double clamping layer having a silicon carbide layer on the silicon core and a silicon oxide layer between the silicon core and the silicon carbide layer.

Abstract: Provided is a negative active material and a lithium secondary battery including the negative active material. The negative active material for a secondary battery includes silicon particles, wherein circularities of the particles are determined by equation 1 below, and the circularities are 0.5 or greater and 0.9 or less, Circularity=2(pi×A)1/2/P??[Equation 1] where A denotes a projected area of the silicon particle that is two-dimensionally projected, and P denotes a circumferential length of the silicon particle that is two-dimensionally projected.

Abstract: The present invention relates to a method for preparing silicon-based active material particles for a secondary battery and silicon-based active material particles. The method for preparing silicon-based active material particles according to an embodiment of the present invention comprises the steps of: providing silicon powder; dispersing the silicon powder into an oxidant solvent to provide a mixture prior to grinding; fine-graining the silicon powder by applying mechanical compression and shear stress to the silicon powder in the mixture prior to grinding to produce silicon particles; producing a layer of chemical oxidation on the fine-grained silicon particles with the oxidant solvent while applying mechanical compression and shear stress to produce silicon-based active material particles; and drying the resulting product comprising the silicon-based active material particles to yield silicon-based active material particles.

Abstract: Provided is an anode active material for a secondary battery and a method of fabricating the anode active material. A silicon-based active material composite according to an embodiment of the inventive concept includes silicon and silicon oxide obtained by oxidizing at least a part of the silicon, and an amount of oxygen with respect to a total weight of the silicon and the silicon oxide is restricted to 9 wt % to 20 wt %.

Abstract: The present invention relates to a method for preparing silicon-based active material particles for a secondary battery and silicon-based active material particles. The method for preparing silicon-based active material particles according to an embodiment of the present invention comprises the steps of: providing silicon powder; dispersing the silicon powder into an oxidant solvent to provide a mixture prior to grinding; fine-graining the silicon powder by applying mechanical compression and shear stress to the silicon powder in the mixture prior to grinding to produce silicon particles; producing a layer of chemical oxidation on the fine-grained silicon particles with the oxidant solvent while applying mechanical compression and shear stress to produce silicon-based active material particles; and drying the resulting product comprising the silicon-based active material particles to yield silicon-based active material particles.

Abstract: Provided is an anode active material for a secondary battery and a method of fabricating the anode active material. A silicon-based active material composite according to an embodiment of the inventive concept includes silicon and silicon oxide obtained by oxidizing at least a part of the silicon, and an amount of oxygen with respect to a total weight of the silicon and the silicon oxide is restricted to 9 wt % to 20 wt %.

Abstract: The present invention relates to a cathode active material for a secondary battery and a manufacturing method thereof. A cathode active material, according to one embodiment of the present invention, comprises silicon-based primary particles, and a particle size distribution of the silicon-based primary particles is D10?50 nm and D90?150 nm. The cathode active material suppresses or reduces tensile hoop stress generated in lithiated silicon particles during a charging of a battery to thus suppress a crack due to a volume expansion of the silicon particles and/or an irreversible reaction caused by the crack, such that the lifetime and capacity of the battery can be improved.

Abstract: The present invention relates to a method for producing silicon-based active material particles for a secondary battery and silicon-based active material particles. A method for producing silicon-based active material particles for a secondary battery according to an embodiment of the present invention may comprise: a step of providing silicon powder; a step of providing a pre-pulverization mixture in which the silicon powder is dispersed in a solvent for dispersion comprising an antioxidant; a step of applying mechanical compression and shear stress to the silicon powder of the pre-pulverization mixture to refine the silicon powder, thereby forming silicon particles having an oxygen content controlled by the antioxidant; and a step of drying the resulting material comprising the silicon particles to obtain silicon-based active material particles.

Abstract: The present invention relates to a silicon-based anode active material and a method of fabricating the same. The silicon-based anode active material according to an embodiment of the present invention comprises: particles comprising silicon and oxygen combined with the silicon, wherein a carbon-based conductive layer is coated with on outermost surface of the particles; and phosphorus doped in the particles, wherein a content of the phosphorus with respect to a total weight of the particles and the phosphorus doped in the particles have a range of 0.01 wt % to 15 wt %, and a content of the oxygen has a range of 9.5 wt % to 25 wt %.

Abstract: The present invention relates to a silicon anode active material capable of high capacity and high output, and a method for fabricating the same. A silicon anode active material according to an embodiment of the present invention includes a silicon core including silicon particles; and a double clamping layer having a silicon carbide layer on the silicon core and a silicon oxide layer between the silicon core and the silicon carbide layer.

Abstract: The present invention relates to a silicon-based anode active material and a method for manufacturing the same. The silicon-based anode active material according to an embodiment of the present invention comprises: particles comprising silicon and oxygen combined with the silicon, and having a carbon-based conductive film coated on the outermost periphery thereof; and boron doped inside the particles, wherein with respect to the total weight of the particles and the doped boron, the boron is included in the amount of 0.01 weight % to 17 weight %, and the oxygen is included in the amount of 16 weight % to 29 weight %.