Abstract: Spinel insertion compounds Li.sub.1+x Mn.sub.2-x-y M.sub.y O.sub.4 wherein M is a transition metal, 0<x< about 0.33, 0.ltoreq.y<about 1, can have relatively low surface area at relatively large values of x when prepared with a novel two step heating method. Li.sub.1 Mn.sub.2-y M.sub.y O.sub.4 is first prepared between a critical temperature, T.sub.c, and about 900.degree. C. Then, a lithium salt is mixed therewith and reacted at a temperature between about 400.degree. C. and T.sub.c. These compounds are suitable for use as a cathode in a lithium battery. The use of LiCl as the lithium salt can provide improved cycle life results in such a battery.

Abstract: Carbonaceous insertion compounds and methods for preparation are described wherein the compounds comprise silicon and oxygen and are characterized by x-ray diffraction patterns that resemble that of amorphous silicon dioxide. The compounds can exhibit a large reversible capacity for lithium and can be prepared by simple pyrolysis of suitable polymer/s containing silicon, oxygen and carbon at an appropriate temperature. These insertion compounds may be suitable for use as high capacity anodes in lithium ion batteries.