Abstract: A flexible isocyanate-based polymeric foam which has: (i) low resiliency; (ii) a Tg less than or equal to about 0° C.; and (iii) a change in tan &dgr; less than or equal to about 35% from a median value measured over a temperature range of from about −20° to about +60° C. The foam may be produced using a formulation comprising selected plasticizers as set in the disclosure. The subject foam is less temperature sensitive than currently known low resilience, flexible polyurethane foams. Thus, the present foam finds many applications such as for use in the interior of a vehicle where energy dissipation of the foam is important over a relatively wide temperature range—e.g., −20° to +60° C.

Abstract: In one of its aspects, the present invention relates to a foamed isocyanate-based polymer derived from a reaction mixture comprising toluene diisocyanate, wherein the foam has a compression force deformation of at least about 50 kPa at 30% deflection when measured pursuant to ASTM 3574 and a density of less than about 45 kg/m3. In another of its aspects, the present invention relates to a process for producing a foamed isocyanate-based polymer comprising the steps of: contacting an isocyanate comprising toluene diisocyanate, an active hydrogen-containing compound, a dendritic macromolecule and a blowing agent to form a reaction mixture; and expanding the reaction mixture to produce the foamed isocyanate-based polymer; wherein at least a 15% by weight of the dendritic macromolecule may be mixed with a polyether polyol having an OH number less than about 40 mg KOH/g to form a stable liquid at 23° C.

Abstract: In one of its aspects, the invention relates to a foamed isocyanate-based polymer having a compression force deformation of greater than about 130 kPa at 10% deflection when measured pursuant to ASTM 1621 and a flexural displacement at yield of greater than about 5 mm when measured pursuant to ASTM D790-00. The present foamed polymer has a novel combination of hardness/stiffness and a flexibility.

Abstract: In one of its aspects, the present invention relates to foamed isocyanate-based polymer derived from a reaction mixture comprising an isocyanate, an active hydrogen-containing compound, a dendritic macromolecule and a blowing agent; wherein at least a 15% by weight of the dendritic macromolecule may be mixed with a polyether polyol having an OH number less than about 40 mg KOH/g to form a stable liquid at 23° C. The dendritic macromolecule confers advantageous load building characteristics to the foamed isocyanate-based polymer and may be used to partially or fully displace the use of conventional copolymer polyols used. A process for production of a foam isocyanate-based polymer and a process for conferring loading building properties to a foamed isocyanate-based polymer are also described.

Abstract: A one-part moisture curable polyurethane adhesive composition comprises a blend of polyurethane prepolymers and one or more additives which unexpectedly improve the sag resistance and mechanical properties of the formulation. The final adhesive composition retains good stability in the absence of moisture for an extended period between manufacture and application of the adhesive, and has a relatively rapid and consistent cure rate in the presence of atmospheric moisture. The final cured composition exhibits good mechanical properties and generally is unaffected by ambient application and cure conditions.