Patents by Inventor Jeffrey Sakamoto
Jeffrey Sakamoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Publication number: 20250046865Abstract: A method is disclosed for suppressing propagation of a metal in a solid state electrolyte during cycling of an electrochemical device including the solid state electrolyte and an electrode comprising the metal. One method comprises forming the solid state electrolyte such that the solid state electrolyte has a structure comprising a plurality of grains of a metal-ion conductive material and a grain boundary phase located at some or all of grain boundaries between the grains, wherein the grain boundary phase suppresses propagation of the metal in the solid state electrolyte during cycling. Another method comprises forming the solid state electrolyte such that the solid state electrolyte is a single crystal.Type: ApplicationFiled: October 21, 2024Publication date: February 6, 2025Inventors: Jeffrey Sakamoto, Travis Thompson, Asma Sharafi, Nathan Taylor, Neil P. Dasgupta, Eric Kazyak
-
Patent number: 12194661Abstract: A method of and apparatus for sinter forging a precursor powder to form a film may reduce or eliminate the stress in the film and may facilitate processing of continuous length of films such as ceramic films for use in batteries. The precursor powder can be provided on a substrate and is simultaneously heated and pressed in a pressing direction parallel to a thickness of the film so as to sinter and densify the precursor powder to form the film in a sinter forging area. Notably, in a plane perpendicular to the pressing direction, there are no lateral constraints on the sinter forging area or the material received therein.Type: GrantFiled: February 1, 2021Date of Patent: January 14, 2025Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGANInventors: Jeffrey Sakamoto, Michael Wang, Nathan Taylor
-
Methods For Stabilizing A Garnet-Electron Pair Donor Hybrid Electrolyte For A Lithium-Sulfur Battery
Publication number: 20240372150Abstract: A hybrid electrolyte comprises: (i) a first electrolyte having a first surface and an opposed second surface, wherein the first electrolyte comprises a solid state electrolyte material comprising an oxide, wherein the first surface is an acid-treated surface; and (ii) a second electrolyte comprising a liquid electrolyte, wherein the liquid electrolyte comprises an alkali metal salt and a solvent selected from the group consisting of electron pair donor solvents, and solvent mixtures including at least one electron pair donor solvent and at least one glyme solvent. The oxide can be a doped or undoped LLZO electrolyte material, and the acid can be selected from H3PO4 and HCl.Type: ApplicationFiled: May 2, 2024Publication date: November 7, 2024Inventors: JEFFREY SAKAMOTO, MAX PALMER, ABHINANDAN SHYAMSUNDER, LINDA NAZAR -
Patent number: 12125967Abstract: A method is disclosed for suppressing propagation of a metal in a solid state electrolyte during cycling of an electrochemical device including the solid state electrolyte and an electrode comprising the metal. One method comprises forming the solid state electrolyte such that the solid state electrolyte has a structure comprising a plurality of grains of a metal-ion conductive material and a grain boundary phase located at some or all of grain boundaries between the grains, wherein the grain boundary phase suppresses propagation of the metal in the solid state electrolyte during cycling. Another method comprises forming the solid state electrolyte such that the solid state electrolyte is a single crystal.Type: GrantFiled: June 6, 2018Date of Patent: October 22, 2024Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGANInventors: Jeffrey Sakamoto, Travis Thompson, Asma Sharafi, Nathan Taylor, Neil P. Dasgupta, Eric Kazyak
-
Publication number: 20240313193Abstract: A lithium-ion battery includes an electrode with a plurality of channels formed at least partially through its thickness. Each channel has a diameter in a range from 5 ?m to 100 ?m and/or is spaced apart from another channel by a distance in a range from 10 ?m to 200 ?m as measured between centerlines of the channels. The electrode may be an anode and includes carbonaceous material such as graphite and/or additional electrochemically active lithium host materials. The battery can be charged at a C-rate greater than 2 C.Type: ApplicationFiled: May 22, 2024Publication date: September 19, 2024Inventors: Kuan-Hung Chen, Neil Dasgupta, Jeffrey Sakamoto, Min Ji Namkoong
-
Patent number: 12040477Abstract: A lithium-ion battery includes an electrode with a plurality of channels formed at least partially through its thickness. Each channel has a diameter in a range from 5 ?m to 100 ?m and/or is spaced apart from another channel by a distance in a range from 10 ?m to 200 ?m as measured between centerlines of the channels. The electrode may be an anode and includes carbonaceous material such as graphite and/or additional electrochemically active lithium host materials. The battery can be charged at a C-rate greater than 2 C.Type: GrantFiled: March 14, 2023Date of Patent: July 16, 2024Assignee: The Regents of the University of MichiganInventors: Kuan-Hung Chen, Neil Dasgupta, Jeffrey Sakamoto, Min Ji Namkoong
-
Patent number: 11973182Abstract: Disclosed are electrochemical devices, such as lithium ion battery electrodes, lithium ion conducting solid-state electrolytes, and solid-state lithium ion batteries including these electrodes and solid-state electrolytes. Also disclosed are methods for making such electrochemical devices.Type: GrantFiled: June 29, 2020Date of Patent: April 30, 2024Assignees: The Regents of the University of Michigan, Board of Trustees of Michigan State UniversityInventors: Jeffrey Sakamoto, Travis Thompson, Isabel N. Boona
-
Patent number: 11916187Abstract: Disclosed are electrochemical devices, such as lithium ion battery electrodes, lithium ion conducting solid-state electrolytes, and solid-state lithium ion batteries including these electrodes and solid-state electrolytes. Also disclosed are methods for making such electrochemical devices. Also disclosed are composite electrodes for solid state electrochemical devices. The composite electrodes include one or more separate phases within the electrode that provide electronic and ionic conduction pathways in the electrode active material phase.Type: GrantFiled: August 7, 2018Date of Patent: February 27, 2024Assignee: The Regents of the University of MichiganInventors: Jeffrey Sakamoto, Travis Thompson, Nathan Taylor
-
Publication number: 20230282804Abstract: A lithium-ion battery includes an electrode with a plurality of channels formed at least partially through its thickness. Each channel has a diameter in a range from 5 ?m to 100 ?m and/or is spaced apart from another channel by a distance in a range from 10 ?m to 200 ?m as measured between centerlines of the channels. The electrode may be an anode and includes carbonaceous material such as graphite and/or additional electrochemically active lithium host materials. The battery can be charged at a C-rate greater than 2 C.Type: ApplicationFiled: March 14, 2023Publication date: September 7, 2023Inventors: Kuan-Hung Chen, Neil Dasgupta, Jeffrey Sakamoto, Min Ji Namkoong
-
Patent number: 11626583Abstract: An anode for a lithium ion battery is disclosed includes a first major face, a second major face that, together with the first major face, defines a thickness of the anode, and at least one carbonaceous electrochemically active lithium host material distributed between the first and second major faces of the anode. The at least one carbonaceous electrochemically active lithium host material is selected from the group consisting of graphite, hard carbon, or a blend of graphite and hard carbon. The anode additionally defines a plurality of vertical channels extending at least partially through the thickness of the anode. A lithium-ion batter that includes the disclosed anode and a method of charging a lithium-ion battery that includes the disclosed anode are also disclosed.Type: GrantFiled: June 11, 2020Date of Patent: April 11, 2023Assignee: The Regents of the University of MichiganInventors: Kuan-Hung Chen, Neil Dasgupta, Jeffrey Sakamoto, Min Ji Namkoong
-
Publication number: 20210399331Abstract: A hybrid electrolyte for an electrochemical device comprises: (i) a first electrolyte comprising a solid state electrolyte material, such as lithium lanthanum zirconium tantalum oxide (LLZTO) or lithium lanthanum zirconium oxide (LLZO); and a second electrolyte comprising a liquid electrolyte or a gel electrolyte, the second electrolyte comprising a solvent and a salt in case of a liquid electrolyte and polymer, solvent and a salt in case of a gel electrolyte. The salt is selected from the group consisting of lithium (halosulfonyl)imides, lithium (haloalkanesulfonyl)imides, lithium (halosulfonyl haloalkanesulfonyl)imides, and mixtures thereof, wherein the second electrolyte contacts the first surface of the first electrolyte. An electrochemical device comprises the hybrid electrolyte; a cathode facing the first surface of the first electrolyte of the hybrid electrolyte; and an anode contacting the second surface of the first electrolyte of the hybrid electrolyte, wherein the anode comprises lithium metal.Type: ApplicationFiled: June 18, 2021Publication date: December 23, 2021Inventors: JEFFREY SAKAMOTO, ARUSHI GUPTA
-
Publication number: 20210346951Abstract: A method of and apparatus for sinter forging a precursor powder to form a film may reduce or eliminate the stress in the film and may facilitate processing of continuous length of films such as ceramic films for use in batteries. The precursor powder can be provided on a substrate and is simultaneously heated and pressed in a pressing direction parallel to a thickness of the film so as to sinter and densify the precursor powder to form the film in a sinter forging area. Notably, in a plane perpendicular to the pressing direction, there are no lateral constraints on the sinter forging area or the material received therein.Type: ApplicationFiled: February 1, 2021Publication date: November 11, 2021Inventors: JEFFREY SAKAMOTO, MICHAEL WANG, NATHAN TAYLOR
-
Publication number: 20210226193Abstract: The present disclosure relates to a method of electrodeposition using pulsed currents to improve the uniformity of electrodeposited materials at solid-solid interfaces. It has been demonstrated that films of electrodeposited metals can be robustly deposited at a solid-solid interface without damage to the solid-electrolyte. Furthermore, the effects of the pulse parameters, including current density, pulse width, and duty cycle have shown to have dramatic effects on the spatial distribution of the electrodeposited metal. This methodology can aid in the manufacturing of thin films and microscopic structures for application in advanced functional materials and electrochemical devices. In one embodiment, the method provides for anode-free manufacturing in which a battery is fabricated in the discharged state, with a bare current collector replacing the conventional anode, and a metal anode is then formed electrochemically on the first charge cycle by electroplating a metal contained within the cathode.Type: ApplicationFiled: January 21, 2021Publication date: July 22, 2021Inventors: JEFFREY SAKAMOTO, MICHAEL WANG
-
Patent number: 10938061Abstract: Disclosed are electrochemical devices, such as lithium battery electrodes, lithium ion conducting solid state electrolytes, and solid-state lithium metal batteries including these electrodes and solid state electrolytes. In one embodiment, a method for forming an electrochemical device is disclosed in which a precursor electrolyte is heated to remove at least a portion of a resistive surface region of the precursor electrolyte.Type: GrantFiled: April 2, 2018Date of Patent: March 2, 2021Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGANInventors: Jeffrey Sakamoto, Travis Thompson, Asma Sharafi
-
Patent number: 10903484Abstract: Disclosed are electrochemical devices and methods for making electrochemical devices such as metal infiltrated electrodes for solid state lithium ion and lithium metal batteries. In one method for forming an electrode, a metal is infiltrated into the pore space of the active material of the electrode providing improved electronic conductivity to the electrode. The electrode may also include a solid-state ion conducting material providing improved ion conductivity to the electrode. Before infiltration of the metal, a stabilization coating may be applied to the active material and/or the solid-state ion conducting material to the stabilize electrode interfaces by slowing, but not eliminating, the chemical reactions that occur at elevated temperatures during sintering of the active material and/or the solid-state ion conducting material forming the electrode.Type: GrantFiled: October 25, 2017Date of Patent: January 26, 2021Assignee: The Regents of the University of MichiganInventors: Jeffrey Sakamoto, Travis Thompson, Nathan Taylor
-
Publication number: 20200395600Abstract: An anode for a lithium ion battery is disclosed includes a first major face, a second major face that, together with the first major face, defines a thickness of the anode, and at least one carbonaceous electrochemically active lithium host material distributed between the first and second major faces of the anode. The at least one carbonaceous electrochemically active lithium host material is selected from the group consisting of graphite, hard carbon, or a blend of graphite and hard carbon. The anode additionally defines a plurality of vertical channels extending at least partially through the thickness of the anode. A lithium-ion batter that includes the disclosed anode and a method of charging a lithium-ion battery that includes the disclosed anode are also disclosed.Type: ApplicationFiled: June 11, 2020Publication date: December 17, 2020Inventors: Kuan-Hung Chen, Neil Dasgupta, Jeffrey Sakamoto, Min Ji Namkoong
-
Patent number: 10854930Abstract: The present disclosure relates to a method for forming solid-state electrolytes, electrodes, current collectors, and/or conductive additives used in solid-state batteries. In one version, the method includes depositing a stabilization coating on a powdered electrolyte material, or a powdered electrode material, or a powdered conductive additive material and forming a slurry comprising the coated material. The slurry is then cast on a surface to form a layer, and the layer is sintered to form a solid state electrolyte, or an electrode, or an electrode having the conductive additive.Type: GrantFiled: October 9, 2017Date of Patent: December 1, 2020Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGANInventors: Jeffrey Sakamoto, Travis Thompson, Nathan Taylor
-
Patent number: 10847805Abstract: An article for forming an electrochemical device is disclosed. The article comprises a metallic current collector clad with an ion conducting solid-electrolyte material such that intimate contact between the current collector and the ion conducting solid-electrolyte material is made. A lithium metal anode can be formed in situ between the current collector clad and the ion conducting solid-electrolyte material from lithium ions contained within a cathode material that is placed in contact with the ion conducting solid-electrolyte material. A bipolar electrochemical cell can be constructed from the article.Type: GrantFiled: January 9, 2019Date of Patent: November 24, 2020Assignee: THE REGENTS OF THE UNIVERSITY OF MICHIGANInventors: Jeffrey Sakamoto, Travis Thompson, Nathan Taylor
-
Patent number: 10840543Abstract: Disclosed are electrochemical devices, such as lithium battery electrodes, lithium ion conducting solid-state electrolytes, and solid-state lithium metal batteries including these electrodes and solid-state electrolytes. In one disclosed method, a solid state electrolyte material including a precursor layer having a first electronic conductivity is provided; and the precursor layer on the solid state electrolyte material is reduced to an interfacial layer having a second electronic conductivity greater than the first electronic conductivity.Type: GrantFiled: April 2, 2018Date of Patent: November 17, 2020Assignee: The Regents of the University of MichiganInventors: Jeffrey Sakamoto, Travis Thompson, Nathan Taylor
-
Patent number: 10818965Abstract: Disclosed is a ceramic material having a formula of LiwAxM2Re3-yOz, wherein w is 5-7.5; wherein A is selected from B, Al, Ga, In, Zn, Cd, Y, Sc, Mg, Ca, Sr, Ba, and any combination thereof; wherein x is 0-2; wherein M is selected from Zr, Hf, Nb, Ta, Mo, W, Sn, Ge, Si, Sb, Se, Te, and any combination thereof; wherein Re is selected from lanthanide elements, actinide elements, and any combination thereof; wherein y is 0.01-0.75; wherein z is 10.875-13.125; and wherein the material has a garnet-type or garnet-like crystal structure. The ceramic garnet based material is ionically conducting and can be used as a solid state electrolyte for an electrochemical device such as a battery or supercapacitor.Type: GrantFiled: July 11, 2017Date of Patent: October 27, 2020Assignee: The Regents of the University of MichiganInventors: Jeffrey Sakamoto, Travis Thompson