Patents by Inventor Jeffrey W. Freeman

Jeffrey W. Freeman has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7718838
    Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
    Type: Grant
    Filed: December 12, 2006
    Date of Patent: May 18, 2010
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: William M. Woodard, Warren M. Ewert, Harvey D. Hensley, Mark E. Lashier, Glyndal D. Cowan, Jeffrey W. Freeman, Ralph V. Franklin, Ronald D. Knudsen, Richard L. Anderson, Lyle R. Kallenbach, Bruce E. Kreischer
  • Patent number: 7157612
    Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: January 2, 2007
    Assignee: Phillips Petroleum Company
    Inventors: Warren M. Ewert, William M. Woodard, Harvey D. Hensley, Mark E. Lashier, Glyndal D. Cowan, Jeffrey W. Freeman, Ralph V. Franklin, Ronald D. Knudsen, Richard L. Anderson, Lyle R. Kallenbach, Bruce E. Kreischer
  • Publication number: 20040228775
    Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
    Type: Application
    Filed: June 18, 2004
    Publication date: November 18, 2004
    Inventors: Warren M. Ewert, William M. Woodard, Harvey D. Hensley, Mark E. Lashier, Glyndal D. Cowan, Jeffrey W. Freeman, Ralph V. Franklin, Ronald D. Knudsen, Richard L. Anderson, Lyle R. Kallenbach, Bruce E. Kreischer
  • Publication number: 20020182124
    Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
    Type: Application
    Filed: October 14, 1997
    Publication date: December 5, 2002
    Inventors: WILLIAM M. WOODARD, WARREN M. EWERT, HARVEY D. HENSLEY, MARK E. LASHIER, BRUCE E. KREISCHER, GLYNDAL D. COWAN, JEFFREY W. FREEMAN, RALPH V. FRANKLIN, RONALD D. KNUDSEN, RICHARD L. ANDERSON, LYLE R. KALLENBACH
  • Patent number: 6455648
    Abstract: A process is provided which comprises preparing an olefin oligomerization or trimerization catalyst system and producing olefins in the presence of the olefin oligomerization or trimerization catalyst system and a solvent, wherein said catalyst system preparation comprises the steps of first contacting a chromium source and a pyrrole-containing compound to form a chromium/pyrrole mixture; second, contacting said chromium/pyrrole mixture with a metal alkyl to form a catalyst system; and then contacting said catalyst system with an alpha-olefin, preferably ethylene.
    Type: Grant
    Filed: December 29, 1999
    Date of Patent: September 24, 2002
    Assignee: Chevron Phillips Chemical Company LP
    Inventors: Jeffrey W. Freeman, Warren M. Ewert, Bruce E. Kreischer, Ronald D. Knudsen, Glyndal D. Cowan
  • Publication number: 20010053742
    Abstract: A process is provided to modify an olefin production catalyst system which comprises contacting an olefin production catalyst system with ethylene prior to use. A second embodiment of the invention comprises contacting an aluminum alkyl and a pyrrole-containing compound prior to contacting a chromium containing compound and prior to contacting an olefin. A process also is provided to trimerize and/or oligomerize olefins with the novel, modified olefin catalyst production systems. These modified olefin production catalyst systems can produce less solids, such as, for example, polymer, during a trimerization reaction.
    Type: Application
    Filed: December 18, 1998
    Publication date: December 20, 2001
    Inventors: RONALD D. KNUDSEN, JEFFREY W. FREEMAN
  • Patent number: 5986153
    Abstract: A process for substantially stabilizing the color of a fluid which comprises an olefin is disclosed. The process comprises contacting the fluid with a composition, which comprises aluminum, zirconium and a borate, under a condition effective to stabilize the color of the fluid.
    Type: Grant
    Filed: September 30, 1997
    Date of Patent: November 16, 1999
    Assignee: Phillips Petroleum Company
    Inventors: Lyle R. Kallenbach, Jeffrey W. Freeman
  • Patent number: 5919996
    Abstract: A process is provided to modify an olefin production catalyst system which comprises contacting an olefin production catalyst system with ethylene prior to use. A process also is provided to trimerize and/or oligomerize olefins with the novel, modified olefin catalyst production system. The modified olefin production catalyst system produces less solids, such as, for example, polymer.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: July 6, 1999
    Assignee: Phillips Petroleum Company
    Inventors: Jeffrey W. Freeman, John L. Buster, Ronald D. Knudsen
  • Patent number: 5856257
    Abstract: A process is provided to modify an olefin production catalyst system which comprises contacting an olefin production catalyst system with ethylene prior to use. A process also is provided to trimerize and/or oligomerize olefins with the novel, modified olefin catalyst production system. The modified olefin production catalyst system produces less solids, such as, for example, polymer.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: January 5, 1999
    Assignee: Phillips Petroleum Company
    Inventors: Jeffrey W. Freeman, John L. Buster, Ronald D. Knudsen
  • Patent number: 5814575
    Abstract: Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 29, 1998
    Assignee: Phillips Petroleum Company
    Inventors: William K. Reagen, Ted M. Pettijohn, Jeffrey W. Freeman
  • Patent number: 5786431
    Abstract: Novel chromium-containing compounds are prepared by forming a mixture of a chromium salt, a metal amide, and an ether. These novel chromium-containing, or chromium pyrrolide, compounds, with a metal alkyl and an unsaturated hydrocarbon, can be used as a cocatalyst system in the presence of an olefin polymerization catalyst system to produce a comonomer in-situ. The resultant polymer, although produced from predominately one monomer, has characteristics of a copolymer.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: July 28, 1998
    Assignee: Phillips Petroleum Company
    Inventors: William K. Reagen, Ted M. Pettijohn, Jeffrey W. Freeman, Elizabeth A. Benham
  • Patent number: 5763723
    Abstract: Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 9, 1998
    Assignee: Phillips Petroleum Company
    Inventors: William K. Reagen, Ted M. Pettijohn, Jeffrey W. Freeman
  • Patent number: 5689028
    Abstract: A process is provided to inhibit trimerization catalyst system activity which comprises the sequential steps of contacting a reactor effluent stream with alcohol; removing any desired olefin products; adding an aqueous base to the non-olefin portion; removing a precipitate; separating the aqueous and organic phases; and adding an acid to the aqueous phase.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: November 18, 1997
    Assignee: Phillips Petroleum Company
    Inventors: Mark E. Lashier, Jeffrey W. Freeman, Ronald D. Knudsen
  • Patent number: 5563312
    Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: October 8, 1996
    Assignee: Phillips Petroleum Company
    Inventors: Ronald D. Knudsen, Jeffrey W. Freeman, Mark E. Lashier
  • Patent number: 5543375
    Abstract: A process is provided to stabilize and/or reactivate an olefin production catalyst system which comprises contacting an olefin production catalyst system, either before or after use, with an aromatic compound.
    Type: Grant
    Filed: February 18, 1994
    Date of Patent: August 6, 1996
    Assignee: Phillips Petroleum Company
    Inventors: Mark E. Lashier, Jeffrey W. Freeman, Ronald D. Knudsen
  • Patent number: 5523507
    Abstract: Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
    Type: Grant
    Filed: July 29, 1994
    Date of Patent: June 4, 1996
    Assignee: Phillips Petroleum Company
    Inventors: William K. Reagen, Ted M. Pettijohn, Jeffrey W. Freeman
  • Patent number: 5451645
    Abstract: Novel chromium-containing compounds are prepared by forming a mixture of a chromium salt, a metal amide, and an ether. These novel chromium-containing, or chromium pyrrolide, compounds, with a metal alkyl and an unsaturated hydrocarbon, can be used as a cocatalyst system in the presence of an olefin polymerization catalyst system to produce a comonomer in-situ. The resultant polymer, although produced from predominately one monomer, has characteristics of a copolymer.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: September 19, 1995
    Assignee: Phillips Petroleum Company
    Inventors: William K. Reagen, Ted M. Pettijohn, Jeffrey W. Freeman, Elizabeth A. Benham
  • Patent number: 5376612
    Abstract: Novel chromium-containing compounds, such as, for example, chromium pyrrolides, are prepared by forming a mixture of a chromium salt, a metal amide, and an electron pair donor solvent, such as, for example, an ether. These novel chromium-containing, or chromium pyrrolide, compounds can be used either unsupported or supported on an inorganic oxide support, with a metal alkyl and an unsaturated hydrocarbon, to trimerize, oligomerize, and/or polymerize olefins.
    Type: Grant
    Filed: August 20, 1993
    Date of Patent: December 27, 1994
    Assignee: Phillips Petroleum Company
    Inventors: William K. Reagen, Ted M. Pettijohn, Jeffrey W. Freeman