Abstract: An apparatus for producing hydrogen gas, wherein the apparatus includes a gasification unit or a reforming unit configured to form a first syngas and a first clean-up section is coupled to the gasification unit for acidic gas removal. The first clean-up section is configured to form a second syngas and includes at least one of a high temperature shift catalyst and a low temperature shift catalyst. The apparatus also includes a second clean-up section coupled to the first clean-up section for acidic gas removal.

Abstract: A porous membrane for separation of carbon dioxide from a fluid stream at a temperature higher than about 200° C. with selectivity higher than Knudsen diffusion selectivity. The porous membrane comprises a porous support layer comprising alumina, silica, zirconia or stabilized zirconia; a porous separation layer comprising alumina, silica, zirconia or stabilized zirconia, and a functional layer comprising a ceramic oxide contactable with the fluid stream to preferentially transport carbon dioxide. In particular, the functional layer may be MgO, CaO, SrO, BaO, La2O3, CeO2, ATiO3, AZrO3, AAl2O4, A1FeO3, A1MnO3, A1CoO3, A1NiO3, A2HfO3, A3CeO3, Li2ZrO3, Li2SiO3, Li2TiO3 or a mixture thereof; wherein A is Mg, Ca, Sr or Ba; A1 is La, Ca, Sr or Ba; A2 is Ca, Sr or Ba; and A3 is Sr or Ba.

Abstract: An apparatus for producing hydrogen gas, wherein the apparatus includes a reactor. The reactor includes a catalyst, a membrane in flow communication with the catalyst, and a heat exchanger integrated with the reactor.

Abstract: A power generation system and method includes a first gas turbine system comprising a first combustion chamber configured to combust a first fuel stream of primarily hydrogen that is substantially free of carbon-based fuels. The first gas turbine system also includes a first compressor configured to supply a first portion of compressed oxidant to the first combustion chamber and a first turbine configured to receive a first discharge from the first combustion chamber and generate a first exhaust and electrical energy. The power generation system further includes a second gas turbine system comprising a second combustion chamber configured to combust a second fuel stream to generate a second discharge. The first compressor of the first gas turbine system is configured to supply a second portion of compressed oxidant to the second combustion chamber.