Abstract: A method of manufacturing a lithium solid electrolyte, the method including: providing a composition including a lithium precursor, a lanthanum precursor, and a zirconium precursor; disposing the composition on a substrate having a temperature of 270° C. to 500° C. to form a film; and heat-treating the film at 300° C. to less than 750° C. for 1 hour to 100 hours to manufacture the lithium solid electrolyte.

Abstract: A lithium ion conductor includes a compound of Formula 1: Li7?a*??(b?4)*??xMa?La3Zr2??Mb?O12?x??XxN???Formula 1 wherein in Formula 1, Ma is a cationic element having a valence of a, Mb is a cationic element having a valence of b, and X is an anion having a valence of ?1, wherein, when Ma comprises H, 0???5, otherwise 0???0.75, and wherein 0???1.5, 0?x?1.5, (a*?+(b?4)?+x)>0, and 0<??6.

Abstract: A multi-phase electrolyte film includes a first phase comprising a metal oxide, wherein the metal oxide is amorphous, crystalline, or a glass; and a second phase comprising a lithium salt having a decomposition temperature in air of greater than 200° C. or a lithium halide. The first phase is dispersed in the second phase and has an average particle size of 5 to 200 nanometers. Methods for the manufacture of the electrolyte film are also disclosed.

Abstract: A multi-phase electrolyte film includes a first phase comprising a metal oxide, wherein the metal oxide is amorphous, crystalline, or a glass; and a second phase comprising a lithium salt having a decomposition temperature in air of greater than 200° C. or a lithium halide. The first phase is dispersed in the second phase and has an average particle size of 5 to 200 nanometers. Methods for the manufacture of the electrolyte film are also disclosed.

Abstract: Thin films of lithium-containing materials and methods for fabricating them are generally described. In some embodiments, the formation of a first vapor is induced from a first target and the formation of a second vapor is induced from a second target, resulting in the formation of a thin film. In some embodiments, at least a portion of the formation of the first vapor and the formation of the second vapor occurs under vacuum conditions. In some embodiments, the thin film has a relatively high ionic conductivity, mixed ionic/electronic conductivity, or other properties beneficial for applications such as active electrode materials or solid-state electrolytes.

Abstract: A method of manufacturing a lithium solid electrolyte, the method including: providing a composition including a lithium precursor, a lanthanum precursor, and a zirconium precursor; disposing the composition on a substrate having a temperature of 270° C. to 500° C. to form a film; and heat-treating the film at 300° C. to less than 750° C. for 1 hour to 100 hours to manufacture the lithium solid electrolyte.

Abstract: Resistive switching devices that contain lithium, including resistive switching devices containing a lithium titanate, and associated systems and methods are generally described. In some cases, the resistive switching device contains a lithium titanate-containing domain, a first electrode, and a second electrode. In some cases, the application of an electrical potential to the resistive switching device causes a change in resistance state of the lithium titanate-containing domain. The resistive switching devices described herein may be useful as memristors, and in applications that include Resistive-random access memory and neuromorphic computing.

Abstract: A component for a lithium battery including a first layer including a lithium garnet having a porosity of 0 percent to less than 25 percent, based on a total volume of the first layer; and a second layer on the first layer and having a porosity of 25 percent to 80 percent, based on a total volume of the second layer, wherein the second layer is on the first layer and the second layer has a composition that is different from a composition of the first layer.

Abstract: A method of manufacturing a lithium solid electrolyte, the method including: providing a composition including a lithium precursor, a lanthanum precursor, and a zirconium precursor; disposing the composition on a substrate having a temperature of 270° C. to 500° C. to form a film; and heat-treating the film at 300° C. to less than 750° C. for 1 hour to 100 hours to manufacture the lithium solid electrolyte.

Abstract: A component for a lithium battery including a first layer including a lithium garnet having a porosity of 0 percent to less than 25 percent, based on a total volume of the first layer; and a second layer on the first layer and having a porosity of 25 percent to 80 percent, based on a total volume of the second layer, wherein the second layer is on the first layer and the second layer has a composition that is different from a composition of the first layer.

Abstract: A lithium ion conductor includes a compound of Formula 1: Li7?a*??(b?4)*??xM?La3Zr2??Mb?O12?x??XxN???Formula 1 wherein in Formula 1, Ma is a cationic element having a valence of a, Mb is a cationic element having a valence of b, and X is an anion having a valence of ?1, wherein, when Ma comprises H, 0???5, otherwise 0?a?0.75, and wherein 0???1.5, 0?x?1.5, (a*?+(b-4)?+x)>0, and 0<??6.

Abstract: A lithium ion conductor includes a compound of Formula 1: Li7-a*?-(b-4)*?-xMa?La3Zr2-?Mb?O12-x-?XxN???Formula 1 wherein in Formula 1, Ma is a cationic element having a valence of a, Mb is a cationic element having a valence of b, and X is an anion having a valence of ?1, wherein, when Ma comprises H, 0???5, otherwise 0???0.75, and wherein 0???1.5, 0?x?1.5, (a*?+(b?4)?+x)>0, and 0<??6.

Abstract: A multi-phase electrolyte film includes a first phase comprising a metal oxide, wherein the metal oxide is amorphous, crystalline, or a glass; and a second phase comprising a lithium salt having a decomposition temperature in air of greater than 200° C. or a lithium halide. The first phase is dispersed in the second phase and has an average particle size of 5 to 200 nanometers. Methods for the manufacture of the electrolyte film are also disclosed.

Abstract: A method of manufacturing a solid-state electrolyte including: providing a solvent; dissolving a precursor compound including lithium, a precursor compound including lanthanum, and a precursor compound including zirconium in the solvent to provide a precursor composition, wherein a content of lithium in the precursor composition is greater than a stoichiometric amount; spraying the precursor composition onto a heated substrate to form a film; and heat-treating the film at 300° C. to 800° C. to manufacture the solid state electrolyte, wherein the solid-state electrolyte includes Li(7-x)Alx/3La3Zr2O12 wherein 0?x?1, and wherein the solid state electrolyte is in a form a film having a thickness of 5 nanometers to 1000 micrometers.

Abstract: A method of manufacturing a solid-state electrolyte, the method including: providing a substrate; providing a precursor composition including a compound including a compound including lithium, a compound including lanthanum, and a compound including zirconium, and a solvent; disposing the precursor composition on the substrate to provide a coated substrate; treating the coated substrate at a temperature between ?40° C. and 25° C. to form a precursor film on the substrate; and heat-treating the precursor film at a temperature of 500° C. to 1000° C. to manufacture the solid-state electrolyte, wherein the solid-state electrolyte includes Li(7-x)Alx/3La3Zr2O12 wherein 0?x?1, and wherein the solid-state electrolyte in the form of a film having a thickness of 5 nanometers to 1000 micrometers.

Abstract: A method of manufacturing a solid-state electrolyte including: providing a solvent; dissolving a precursor compound including lithium, a precursor compound including lanthanum, and a precursor compound including zirconium in the solvent to provide a precursor composition, wherein a content of lithium in the precursor composition is greater than a stoichiometric amount; spraying the precursor composition onto a heated substrate to form a film; and heat-treating the film at 300° C. to 800° C. to manufacture the solid state electrolyte, wherein the solid-state electrolyte includes Li(7-x)Alx/3La3Zr2O12 wherein 0?x?1, and wherein the solid state electrolyte is in a form a film having a thickness of 5 nanometers to 1000 micrometers.

Abstract: Thin films of lithium-containing materials and methods for fabricating them are generally described. In some embodiments, the formation of a first vapor is induced from a first target and the formation of a second vapor is induced from a second target, resulting in the formation of a thin film. In some embodiments, at least a portion of the formation of the first vapor and the formation of the second vapor occurs under vacuum conditions. In some embodiments, the thin film has a relatively high ionic conductivity, mixed ionic/electronic conductivity, or other properties beneficial for applications such as active electrode materials or solid-state electrolytes.

Abstract: Lithium-containing thin films and methods for fabricating them are generally described. In some embodiments, the formation of a first vapor is induced from a first target and the formation of a second vapor is induced from a second target, resulting in the formation of a thin film. In some embodiments, at least a portion of the formation of the first vapor and the formation of the second vapor occurs under vacuum conditions. In some embodiments, the thin film has a relatively high ionic conductivity.

Abstract: A method of manufacturing a lithium solid electrolyte, the method including: providing a composition including a lithium precursor, a lanthanum precursor, and a zirconium precursor; disposing the composition on a substrate having a temperature of 270° C. to 500° C. to form a film; and heat-treating the film at 300° C. to less than 750° C. for 1 hour to 100 hours to manufacture the lithium solid electrolyte.

Abstract: Resistive switching devices that contain lithium, including resistive switching devices containing a lithium titanate, and associated systems and methods are generally described. In some cases, the resistive switching device contains a lithium titanate-containing domain, a first electrode, and a second electrode. In some cases, the application of an electrical potential to the resistive switching device causes a change in resistance state of the lithium titanate-containing domain. The resistive switching devices described herein may be useful as memristors, and in applications that include Resistive-random access memory and neuromorphic computing.