Patents by Inventor Jens Martin Paulsen

Jens Martin Paulsen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240132373
    Abstract: Positive electrode active material for solid-state batteries, comprising Li, M?, and oxygen, wherein M? comprises: Ni in a content x between 50.0 mol % and 75.0 mol %, Co in a content y between 0.0 mol % and 40.0 mol %, Mn in a content z between 0.0 mol % and 40.0 mol %, dopants in a content a between 0.0 mol % and 2.0 mol %, Zr in a content b between 0.1 mol % and 5.0 mol %, wherein x+y+z+a+b is 100.0 mol %, wherein Zr A = b ( x + y + z + b ) , wherein the positive electrode active material has a Zr content ZrB is expressed as molar fraction compared to the sum of molar fractions of Co, Mn, Ni, and Zr all as measured by XPS analysis, wherein ZrB/ZrA>50.0, the positive electrode active material comprising secondary particles having a plurality of primary particles said primary particles having an average diameter between 170 nm and 340 nm.
    Type: Application
    Filed: February 24, 2022
    Publication date: April 25, 2024
    Inventors: Jens Martin PAULSEN, Shinichi KUMAKURA, TaeHyeon YANG, HyeJeong YANG, JiHoon KANG, JinDoo OH, JooEun HYOUNG
  • Publication number: 20240132374
    Abstract: Positive electrode active material for solid-state batteries, comprising Li, M?, and oxygen, wherein M? comprises: Ni in a content x between 50.0 mol % and 85.0 mol %, Co in a content y between 0.0 mol % and 40.0 mol %, Mn in a content z between 0.0 mol % and 40.0 mol %, dopants in a content a between 0.0 mol % and 2.0 mol %, Zr in a content b between 0.1 mol % and 5.0 mol %, wherein x+y+z+a+b is 100.0 mol %, wherein Zr A = b ( x + y + z + b ) , wherein the positive electrode active material has a Zr content ZrB is expressed as molar fraction compared to the sum of molar fractions of Co, Mn, Ni, and Zr all as measured by XPS analysis, wherein ZrB/ZrA>50.0, the positive electrode active material comprising secondary particles having a plurality of primary particles said primary particles having an average diameter between 170 nm and 340 nm.
    Type: Application
    Filed: February 24, 2022
    Publication date: April 25, 2024
    Inventors: Jens Martin PAULSEN, Shinichi KUMAKURA, TaeHyeon YANG, HyeJeong YANG, JiHoon KANG, JinDoo OH, JooEun HYOUNG
  • Publication number: 20240038982
    Abstract: A positive electrode active material for batteries which comprises Li, M?, and oxygen, wherein M? comprises: Ni in a content a between 70.0 mol % and 95.0 mol %; Co in a content x between 0.0 mol % and 25.0 mol %; Mn in a content y between 0.0 mol % and 25.0 mol %, a dopant D in a content z between 0.0 mol % and 2.0 mol %, Al and B in a total content c between 0.1 mol % and 5.0 mol %, wherein the active material has an Al content AlA and a B content BA, wherein a, x, y, z, c, AlA and BA are measured by ICP, wherein AlA, and BA are expressed as molar fractions compared to the sum of a and x and y, wherein the positive electrode active material, when measured by XPS analysis, shows an average Al fraction AlB and an average B fraction BB, wherein the ratio AlB/AlA>1.0, wherein the ratio BB/BA>1.0, and wherein the positive electrode active material is a single-crystalline powder.
    Type: Application
    Filed: December 14, 2021
    Publication date: February 1, 2024
    Inventors: JiHye KIM, Jens Martin PAULSEN
  • Publication number: 20240030408
    Abstract: A positive electrode active material for solid state rechargeable batteries, whereby the positive electrode active material is a powder which comprises Li, NI, and 0, wherein M? consists of Co in a content x superior or equal to 2.0 mol % and inferior or equal to 35.0 mol %, Mn in a content y superior or equal to 0 mol % and inferior or equal to 35.0 mol %, A in a content m superior or equal to 0 mol % and inferior or equal to 5 mol %, whereby A comprises at least one element of the group consisting of: Al, Ba, B, Mg, Nb, Sr, Ti, W, S, Ca, Cr, Zn, V, Y, Si, and Zr, Ni in a content of 100-x-y-m mol %, a first compound which comprises Li2WO4 and a second compound which comprises WO3, whereby the powder is a single-crystalline powder, whereby the positive electrode active material comprises Li in a molar ratio of Li/(Co+Mn+Ni+A) of at least 0.9 and at most 1.1, whereby the positive electrode active material has a tap density which is at least 1.0 gr/cm3 and at most 3.0 g/cm3.
    Type: Application
    Filed: December 17, 2021
    Publication date: January 25, 2024
    Inventors: Jens Martin PAULSEN, Shinichi KUMAKURA, Liang ZHU, JiHye KIM, JiHoon KANG, HyeJeong YANG, YuRi LEE
  • Publication number: 20240030423
    Abstract: A positive electrode active material for lithium-ion liquid electrolyte rechargeable batteries, whereby the positive electrode active material is a powder which comprises Li, M?, and O, wherein M? consists of Co in a content x superior or equal to 2.0 mol % and inferior or equal to 35.0 mol %, Mn in a content y superior or equal to 0 mol % and inferior or equal to 35.0 mol %, A in a content m superior or equal to 0 mol % and inferior or equal to 5 mol %, whereby A comprises at least one element of the group consisting of: Al, Ba, B, Mg, Nb, Sr, Ti, W, S, Ca, Cr, Zn, V, Y, Si, and Zr, Ni in a content of 100-x-y-m mol %, a first compound which comprises Li2WO4 and a second compound which comprises WO3, whereby the powder is a single-crystalline powder, whereby the positive electrode active material comprises Li in a molar ratio of Li/(Co+Mn+Ni+A) of at least 0.9 and at most 1.1.
    Type: Application
    Filed: December 17, 2021
    Publication date: January 25, 2024
    Inventors: Jens Martin PAULSEN, Shinichi KUMAKURA, Liang ZHU, JiHye KIM, JiHoon KANG, HyeJeong YANG, YuRi LEE
  • Publication number: 20240025762
    Abstract: A positive electrode active material for batteries which comprises Li, M?, and oxygen, wherein M? comprises: Ni in a content a between 60.0 mol % and 75.0 mol %; Co in a content x between 0.0 mol % and 20.0 mol %; Mn in a content y between 0.0 mol % and 35.0 mol %, a dopant D in a content z between 0.0 mol % and 2.0 mol %, Al, B and W in a total content c between 0.1 mol % and 5.0 mol %, wherein the active material has an Al content AlA, a B content BA, and a W content WA, wherein a, x, y, z, c, AlA, BA and WA are measured by ICP, wherein AlA, BA and WA, wherein the positive electrode active material, when measured by XPS analysis, shows an average Al fraction AlB, an average B fraction BB and an average W fraction WB, wherein AlB/AlA, BB/BA, and WB/WA are all larger than 1.0, and wherein the positive electrode active material is a single crystalline powder.
    Type: Application
    Filed: December 14, 2021
    Publication date: January 25, 2024
    Inventors: JiHye KIM, Jens Martin PAULSEN, JeongYim SHIN, Maxime BLANGERO
  • Publication number: 20240014381
    Abstract: The present invention provides a positive electrode active material for lithium-ion secondary batteries, comprising: (i) a first lithium transition metal oxide, comprising single-crystalline particles having a median particle size D50A of between 3 ?m and 15 ?m, as determined by laser particle size analysis, and (ii) a second lithium transition metal oxide, comprising single-crystalline particles having a median particle size D50B of between 0.5 ?m and 3 ?m, as determined by laser particle size analysis, wherein a weight fraction ?B of said second lithium transition metal oxide with respect to the total weight of said positive electrode active material is between 5 wt. % and 40 wt. %.
    Type: Application
    Filed: November 26, 2021
    Publication date: January 11, 2024
    Inventors: Shinichi KUMAKURA, TaeHyeon YANG, Jens Martin PAULSEN
  • Publication number: 20230411615
    Abstract: The present invention provides a positive electrode active oxide material for rechargeable batteries, comprising lithium, nickel, and at least one metal selected from the group comprising manganese and cobalt, whereby said positive electrode active material has a single-crystalline morphology and said surface layer further comprises aluminum and fluorine, wherein the atomic ratio of Al to a total amount of Ni, Mn, and/or Co of 1.0 to 7.0, and wherein said surface layer has an atomic ratio of F to a total amount of Ni, Mn, and/or Co of 0.5 to 6.0, as determined by XPS analysis.
    Type: Application
    Filed: November 3, 2021
    Publication date: December 21, 2023
    Inventors: Shinichi KUMAKURA, JiHoon KANG, TaeHyeon YANG, Jens Martin PAULSEN
  • Patent number: 11804599
    Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni0.5Mn0.5)yCox)1?kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.
    Type: Grant
    Filed: May 18, 2022
    Date of Patent: October 31, 2023
    Assignees: Umicore, Umicore Korea Ltd.
    Inventors: Areum Park, Jihye Kim, Song-Yi Han, Jens Martin Paulsen, Kyung-Tae Lee, Randy De Palma
  • Publication number: 20230054397
    Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1-a((Niz(Ni0.5Mn0.5)yCox)1-kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.
    Type: Application
    Filed: May 18, 2022
    Publication date: February 23, 2023
    Inventors: Areum PARK, JiHye KIM, Song-Yi HAN, Jens Martin PAULSEN, Kyung-Tae LEE, Randy De Palma
  • Patent number: 11367872
    Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni0.5Mn0.5)yCox)1?kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.
    Type: Grant
    Filed: September 6, 2019
    Date of Patent: June 21, 2022
    Assignees: UMICORE, UMICORE KOREA, LTD.
    Inventors: Areum Park, JiHye Kim, Song-Yi Han, Jens Martin Paulsen, Kyung-Tae Lee, Randy De Palma
  • Patent number: 11114662
    Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni1/2 Mn1/2)yCox)1?k Ak)1+aO2, wherein x+y+z=1, 0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.03?a?0.35, wherein the precursor has a crystalline size L expressed in nm, with 15?L?36. Also a method is described for manufacturing a positive electrode material having a general formula Li1+a?M?1?a?O2, with M?=(Niz(Ni1/2 Mn1/2)yCOx)1?k Ak, wherein x+y+z=1.0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.01?a??0.10, by sintering the lithium deficient precursor powder mixed with either one of LiOH, LiOH.H2O, in an oxidizing atmosphere at a temperature between 800 and 1000° C., for a time between 6 and 36 hrs.
    Type: Grant
    Filed: February 14, 2018
    Date of Patent: September 7, 2021
    Assignees: Umicore, Umicore Korea Ltd.
    Inventors: Areum Park, JiHye Kim, Song-Yi Han, Jens Martin Paulsen, Kyung-Tae Lee, Randy De Palma
  • Publication number: 20200168896
    Abstract: A positive electrode composition for a rechargeable battery, the composition comprising a first and a second powderous lithium metal oxide, the first lithium metal oxide comprising either one or more of Ni, Mn and Co, the second lithium metal oxide powder having either: the formula LixWM?yOz, M? being a metal having a valence state of +2 or +3, with 0<y?1, 3?x?4, 5?z?6, whereby x=(2*z)?[y*(valence state of M?)]?(valence state of W).
    Type: Application
    Filed: May 23, 2017
    Publication date: May 28, 2020
    Inventors: Shinichi KUMAKURA, Liang ZHU, Jens Martin PAULSEN, Gyeong-Ok KIM
  • Publication number: 20200020944
    Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni0.5Mn0.5)yCox)1?kAk)1+aO2, wherein A comprises at least one element of the group consisting of: Mg, Al, Ca, Si, B, W, Zr, Ti, Nb, Ba, and Sr, with 0.05?x?0.40, 0.25?z?0.85, x+y+z=1, 0?k?0.10, and 0?a?0.053, wherein said crystalline precursor powder has a crystalline size L, expressed in nm, with 15?L?36.
    Type: Application
    Filed: September 6, 2019
    Publication date: January 16, 2020
    Inventors: Areum PARK, JiHye KIM, Song-Yi HAN, Jens Martin PAULSEN, Kyung-Tae LEE, Randy De Palma
  • Publication number: 20200006762
    Abstract: A crystalline precursor compound for manufacturing a lithium transition metal based oxide powder usable as an active positive electrode material in lithium-ion batteries, the precursor having a general formula Li1?a((Niz(Ni1/2 Mn1/2)yCox)1?k Ak)1+aO2, wherein x+y+z=1, 0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.03?a?0.35, wherein the precursor has a crystalline size L expressed in nm, with 15?L?36. Also a method is described for manufacturing a positive electrode material having a general formula Li1+a?M?1?a?O2, with M?=(Niz(Ni1/2 Mn1/2)yCOx)1?k Ak, wherein x+y+z=1. 0.1?x?0.4, 0.25?z?0.52, A is a dopant, 0?k?0.1, and 0.01?a??0.10, by sintering the lithium deficient precursor powder mixed with either one of LiOH, LiOH.H2O, in an oxidizing atmosphere at a temperature between 800 and 1000° C., for a time between 6 and 36 hrs.
    Type: Application
    Filed: February 14, 2018
    Publication date: January 2, 2020
    Inventors: Areum PARK, JiHye KIM, Song-Yi HAN, Jens Martin PAULSEN, Kyung-Tae LEE, Randy De Palma
  • Patent number: 9608266
    Abstract: Disclosed are a cathode active material and a method to produce the same at low cost. The cathode powder comprises modified doped LiCoO2 carrying a secondary phase having either one of space groups Fm-3m or Fd-3mS. The modified LiCoO2 is Ni and Mn bearing and has regions of low and high manganese content, where regions with high manganese content are located in islands on the surface. The cathode material has high cycling stability, a very high rate performance and good high temperature storage properties.
    Type: Grant
    Filed: October 29, 2015
    Date of Patent: March 28, 2017
    Assignee: Umicore
    Inventors: Jens Martin Paulsen, Maxime Blangero
  • Publication number: 20160099469
    Abstract: Disclosed are a cathode active material and a method to produce the same at low cost. The cathode powder comprises modified doped LiCoO2 carrying a secondary phase having either one of space groups Fm-3m or Fd-3 mS. The modified LiCoO2 is Ni and Mn bearing and has regions of low and high manganese content, where regions with high manganese content are located in islands on the surface. The cathode material has high cycling stability, a very high rate performance and good high temperature storage properties.
    Type: Application
    Filed: October 29, 2015
    Publication date: April 7, 2016
    Inventors: Jens Martin Paulsen, Maxime BLANGERO
  • Patent number: 9177689
    Abstract: Disclosed is a cathode active material and a method to produce the same at low cost. The cathode powder comprises modified LiCoO2, and possibly a second phase which is LiM?O2 where M? is Mn, Ni, Co with a stoichiometric ratio Ni:Mn?1. The modified LiCoO2 is Ni and Mn bearing and has regions of low and high manganese content, where regions with high manganese content are located in islands on the surface. The cathode material has high cycling stability, a very high rate performance and good high temperature storage properties.
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: November 3, 2015
    Assignee: Umicore
    Inventors: Jens Martin Paulsen, Hyunjoo Je, Maxime Blangero
  • Patent number: 8785042
    Abstract: Disclosed is a cathode active material and a method to produce the same at low cost. The cathode powder comprises modified LiCoO2, and possibly a second phase which is LiM?O2 where M? is Mn, Ni, Co with a stoichiometric ratio Ni:Mn?1. The modified LiCoO2 is Ni and Mn bearing and has regions of low and high manganese content, where regions with high manganese content are located in islands on the surface. The cathode material has high cycling stability, a very high rate performance and good high temperature storage properties.
    Type: Grant
    Filed: January 17, 2008
    Date of Patent: July 22, 2014
    Assignee: Umicore
    Inventors: Jens Martin Paulsen, Thomas Lau
  • Patent number: 8703337
    Abstract: A lithium cobalt oxide powder for use as an active positive electrode material in lithium-ion batteries, the lithium cobalt oxide powder having a Ti content of between 0.1 and 0.25 mol %, and the lithium cobalt oxide powder having a density PD in g/cm3 dependent on the powder particle size expressed by the D50 value in ?m, wherein PD?3.63+[0.0153*(D50?17)].
    Type: Grant
    Filed: November 23, 2011
    Date of Patent: April 22, 2014
    Assignee: Umicore
    Inventors: Robert Ellenwood, Jens Martin Paulsen, JaeRyoung Lee