Abstract: The invention relates to a nanostructured material. The material is a nanostructured carbonaceous material composed of agglomerates of small needles of Li1+?V3O8 and of ?-LixV2O5 (0.1 ???0.25 and 0.03 ?×?0.667) surrounded by a noncontinuous layer of spherical carbon particles. It is obtained by a process consisting in preparing a carbonaceous precursor gel by bringing carbon, ?-V2O5 and a Li precursor into contact in amounts such that the ratio of the [V2O5]/[Li] concentrations is between 1.15 and 1.5 and that the (carbon)/(carbon+V2O5+Li precursor) ratio by weight is from 10 to 15 and in subjecting the gel to a heat treatment comprising a 1st stage at 80° C.-150° C. for 3-12 h and a 2nd stage between 300° C. and 350° C. for 10 min to 1 hour, under an nitrogen or argon atmosphere. Applications: positive electrode active material.