Abstract: Disclosed is a powdered polymeric lubricant having a multi-layer structure as a processing aid capable of being used to improve processability of a vinyl chloride resin, and a manufacturing method thereof. The powdered polymeric lubricant having multi-layer structure according to the present invention has an excellent ability to prevent its adhesion to a metal surface upon its processing so as to give a long-term workability to extrusion, calendaring, blow molding, injection molding, etc., when a small amount of the powder of the present invention is mixed with a vinyl chloride resin. Accordingly, the present invention provides a powdered polymeric lubricant capable of controlling compatibility with the vinyl chloride resin and minimizing the adhesive property to a metal surface of a processing machine when a vinyl chloride resin is processed with a polymer including a silicone-based polymer.

Abstract: The present invention relates to a silicone-acrylic impact modifier having multi-layer structure and a thermoplastic resin composition containing the same, more precisely a silicone-acrylic impact modifier which is composed of i) silicone rubber seed containing one or more vinyl copolymers; ii) acrylic rubber core covering the seed; and iii) a shell containing one or more vinyl copolymers covering the acrylic rubber core, and a thermoplastic resin composition containing the same. The thermoplastic resin having the silicone-acrylic impact modifier of the present invention has improved impact resistance and colorability.

Abstract: The present invention relates to an acryl-silicon rubber complex polymer which has a seed-core-shell structure wherein vinyl monomer and hydrophilic monomer are cross-linked on the seed; the acryl-silicon complex IPN core having an IPN (interpenetrating network) structure formed by radical polymerization of acryl monomer and hydrosilyation of silicon rubber in which silicon rubber particles are dispersed by being cross-linked to acryl rubber, in a continuous phase, is formed on the seed; and a shell prepared by graft-polymerization of C1-C4 alkyl methacrylate to the acryl-silicon complex IPN core is formed on the core, and a method of preparation and use of the same, thereby having excellent impact resistance, weatherability and gloss, so that it can be effectively used as an impact modifier for vinyl chloride resin.

Abstract: The present invention relates to a methacryl resin composition having excellent impact strength and transmittancy, and more specifically, to a graft copolymer prepared by preparing graft prepolymer by inputting a monomer mixture comprising 60 to 100 wt % of alkyl methacrylate, and 0 to 40 wt % of one or more compound selected from a group consisting of aromatic vinyl compound and alkyl acrylate compound to perform graft polymerization and adding acid, salt, or polymer coagulant when the monomer conversion of the polymerization is 70% to 95% and then continuously performing the polymerization to have an increased particle size to 100 to 500 nm in a graft polymerization process among processes of preparing the graft polymer including a seed-rubber core-graft polymerization process, a preparing method thereof, and a methacryl resin composition including the graft polymer.

Abstract: The present invention relates to an acryl-silicon rubber complex polymer and a method for the preparation and use of the same. More precisely, the present invention relates to an acryl-silicon rubber complex polymer which has a seed-core-shell structure wherein the vinyl monomer and hydrophilic monomer are cross-linked on the seed; the acryl-silicon complex IPN core having an IPN (interpenetrating network) structure in which silicon rubber particles are dispersed by being cross-linked to acryl rubber, in a continuous phase, is formed on the seed; and a shell prepared by graft-polymerization of C1˜C4 alkyl methacrylate to the acryl-silicon complex IPN core is formed on the core, and a method of preparation and use of the same. The acryl-silicon rubber complex polymer of the present invention has excellent impact resistance, weatherability and gloss, so that it can be effectively used as an impact modifier for vinyl chloride resin.

Abstract: The invention relates to an acrylic impact modifier having a core-shell structure that provides an acrylic impact modifier composition comprising (a) a rubber core containing an alkyl acrylate polymer comprising at least two layers having different cross-linking densities, and (b) a shell containing an alkyl methacrylate polymer; to a process for the preparation of the acrylic impact modifier; and to a poly(vinyl chloride) composition comprising it. The acrylic impact modifier imparting excellent impact resistance was invented by employing multi-stage polymerization and at the same time by controlling the swelling index of rubber particles by changing the degree of cross-linking from stage to stage. And the poly(vinyl chloride) comprising the impact modifier of the present invention has good weatherability as well as excellent impact strength.

Abstract: The present invention relates to acryl-silicone hybrid impact modifiers, the method of their manufacture, and vinyl chloride resin compositions containing the above. The acryl-silicone hybrid impact modifier of the present invention is comprised of a) 0.01 to 10 parts by weight of a seed obtained through emulsion copolymerization of vinyl monomers and hydrophilic monomers; b) 60 to 94 parts by weight of an acryl-silicone hybrid rubber core covering the seed in which a polyorganosiloxane rubber phase is dispersed locally onto the inner part and surface of the acrylic rubber core containing alkyl acrylate polymers of which alkyl group has 1 to 8 carbon atoms; and c) 6 to 40 parts by weight of a shell covering the above rubber core and containing alkyl methacrylate polymers of which alkyl group has 1 to 4 carbon atoms. Thermoplastic resins containing the above, particularly by being added to vinyl chloride resins, they have effects of granting superior impact resistance, weatherability, and high gloss.

Abstract: Disclosed are a polymeric lubricant having multi layer structure as a processing aid capable of being used to improve processability of a vinyl chloride resin, and a manufacturing method thereof. The polymeric lubricant having multi layer structure according to the present invention is provided in the form of powder, and has an excellent ability to prevent its adhesion to a metal surface upon its processing so as to give a long-term workability to an extrusion, a calendering, a blow molding, an injection molding, etc. if an small amount of the powder of the present invention is mixed with a vinyl chloride resin. Also, the processing aid of the present invention has good powder properties such as the high-temperature drying and the easy mass-production since it has an excellent flowability at high temperature.

Abstract: The present invention relates to a silicone-acrylic impact modifier having multi-layer structure and a thermoplastic resin composition containing the same, more precisely a silicone-acrylic impact modifier which is composed of i) silicone rubber seed containing one or more vinyl copolymers; ii) acrylic rubber core covering the seed; and iii) a shell containing one or more vinyl copolymers covering the acrylic rubber core, and a thermoplastic resin composition containing the same. The thermoplastic resin having the silicone-acrylic impact modifier of the present invention has improved impact resistance and colorability.

Abstract: The invention relates to an acrylic impact modifier having a core-shell structure that provides an acrylic impact modifier composition comprising (a) a rubber core containing an alkyl acrylate polymer comprising at least two layers having different cross-linking densities, and (b) a shell containing an alkyl methacrylate polymer; to a process for the preparation of the acrylic impact modifier; and to a poly(vinyl chloride) composition comprising it. The acrylic impact modifier imparting excellent impact resistance was invented by employing multi-stage polymerization and at the same time by controlling the swelling index of rubber particles by changing the degree of cross-linking from stage to stage. And the poly(vinyl chloride) comprising the impact modifier of the present invention has good weatherability as well as excellent impact strength.