Patents by Inventor Jerome H. Krekeler

Jerome H. Krekeler has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4260706
    Abstract: Olefin polymerization catalysts are prepared by depositing an organophosphoryl chromium product and an aluminum acetyl acetonate on an inorganic support material, and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C. up to the decomposition temperature of the support material.
    Type: Grant
    Filed: June 21, 1979
    Date of Patent: April 7, 1981
    Assignee: National Petro Chemicals Corp.
    Inventors: Louis J. Rekers, Stanley J. Katzen, Jerome H. Krekeler
  • Patent number: 4234453
    Abstract: Olefin polymerization catalysts are prepared by depositing an organophosphoryl chromium product and an aluminum compound on an inorganic support material, and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C. up to the decomposition temperature of the support material.
    Type: Grant
    Filed: September 20, 1976
    Date of Patent: November 18, 1980
    Assignee: National Petro Chemicals Corporation
    Inventors: Louis J. Rekers, Stanley J. Katzen, Jerome H. Krekeler
  • Patent number: 4192775
    Abstract: Olefin polymerization catalysts are prepared by depositing an organophosphoryl chromium product and an aluminum acetyl acetonate on an inorganic support material, and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C. up to the decomposition temperature of the support material.
    Type: Grant
    Filed: July 17, 1978
    Date of Patent: March 11, 1980
    Assignee: National Petro Chemicals Corporation
    Inventors: Louis J. Rekers, Stanley J. Katzen, Jerome H. Krekeler
  • Patent number: 4184028
    Abstract: Olefin polymerization catalysts are prepared by depositing an organophosphoryl chromium product and an aluminum compound on an inorganic support material, and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C. up to the decomposition temperature of the support material.
    Type: Grant
    Filed: June 29, 1977
    Date of Patent: January 15, 1980
    Assignee: National Petro Chemicals Corporation
    Inventors: Louis J. Rekers, Stanley J. Katzen, Jerome H. Krekeler
  • Patent number: 4053565
    Abstract: Silica xerogels having pore volumes greater than about 2.0 cc/g., the major portion of which volumes are provided by pores having pore diameters ranging from 300 to 600 A, and surface areas ranging from 200 to 500 m.sup.2 /g. Xerogels having such cumulative pore volume, pore diameter distribution, and surface area characteristics are useful as supports for stereospecific catalysts for particle form olefin polymerization reactions effecting the production of low molecular weight, high melt index polyolefins.
    Type: Grant
    Filed: January 28, 1974
    Date of Patent: October 11, 1977
    Assignee: National Petro Chemicals Corporation
    Inventors: Jerome H. Krekeler, William Kirch, Henri A. Aboutboul
  • Patent number: 4049896
    Abstract: Olefin polymerization catalysts are prepared by depositing a chromium compound and an aluminum compound on an inorganic support material and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree. C up to the decomposition temperature of the support material. The supported chromium and aluminum compound is then combined with a metallic and/or non-metallic reducing agent, to provide a catalyst system useful in the polymerization of 1-olefins.
    Type: Grant
    Filed: August 20, 1976
    Date of Patent: September 20, 1977
    Assignee: National Petro Chemicals Corporation
    Inventors: Louis J. Rekers, Stanley J. Katzen, Jerome H. Krekeler
  • Patent number: 3984351
    Abstract: Olefin polymerization catalysts are prepared by depositing a chromium compound and an aluminum compound on an inorganic support material and heating the support material in a non-reducing atmosphere at a temperature above about 300.degree.C up to the decomposition temperature of the support material. The supported chromium and aluminum compound is then combined with a metallic and/or non-metallic reducing agent, to provide a catalyst system useful in the polymerization of 1-olefins.
    Type: Grant
    Filed: March 14, 1975
    Date of Patent: October 5, 1976
    Assignee: National Petro Chemicals Corporation
    Inventors: Louis J. Rekers, Stanley J. Katzen, Jerome H. Krekeler
  • Patent number: 3978002
    Abstract: An olefin polymerization catalyst comprising a silica xerogel support having a pore volume greater than about 2.0 cc/g, the major portion of which volume is provided by pores having pore diameters ranging from 300 to 600 A and a surface area ranging from 200 to 500 m.sup.2 /g, and having deposited thereon a metal-containing catalytic material, such as chromium oxide, or other metal oxide. Further, a polymerization process utilizing such a catalyst for the preparation of polyolefins having relatively low molecular weights and high melt indexes without loss of catalyst activity, especially a process for the preparation of polymers and copolymers of 1-olefins having a maximum of 8 carbon atoms in the chain and having no branching nearer the double bond than the 4-position, e.g., ethylene polymers.
    Type: Grant
    Filed: July 9, 1974
    Date of Patent: August 31, 1976
    Assignee: National Petro Chemicals Corporation
    Inventors: Henri A. Aboutboul, William Kirch, Jerome H. Krekeler
  • Patent number: 3960826
    Abstract: An olefin polymerization process for the preparation of polyolefins having relatively low molecular weights and high melt indexes without loss of catalyst activity, utilizing a catalyst comprising a silica xerogel support having a pore volume greater than about 2.0 cc/g, the major portion of which volume is provided by pores having pore diameters ranging from 300 to 600 A and a surface area ranging from 200 to 500 m.sup.2 /g, and having deposited thereon a metal-containing catalytic material, such as chromium oxide, or other metal oxide. The process is designed for the preparation of polymers and copolymers of 1-olefins having a maximum of 8 carbon atoms in the chain and having no branching nearer the double bond than the 4-position, e.g., ethylene polymers.
    Type: Grant
    Filed: August 12, 1974
    Date of Patent: June 1, 1976
    Assignee: National Petro Chemicals Corporation
    Inventors: Henri A. Aboutboul, William Kirch, Jerome H. Krekeler