Patents by Inventor Jerome Leonard Stavinoha, Jr.
Jerome Leonard Stavinoha, Jr. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 12215283Abstract: Recycle content pyoil is cracked in a cracker furnace to make olefins and the coil outlet temperature of the r-pyoil fed coils can be lowered by adding r-pyoil to the cracker feedstock, or alternatively, the coil outlet temperature of the r-pyoil fed tubes can rise if the mass flow rates of the combined cracker stream containing r-pyoil are kept the same or lowered. Further, increasing the hydrocarbon mass flow rate by addition of r-pyoil can be achieved to also increase the output of ethylene and propylene in the cracker effluent. The cracker furnace can accept ethane and/or propane feedstocks in vapor form along with a liquid and/or vapor feed of r-pyoil.Type: GrantFiled: May 22, 2020Date of Patent: February 4, 2025Assignee: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Sllivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20240425765Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.Type: ApplicationFiled: September 5, 2024Publication date: December 26, 2024Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, JR.
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Patent number: 12098338Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.Type: GrantFiled: May 13, 2022Date of Patent: September 24, 2024Assignee: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20240309276Abstract: A predominantly C2 to C4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.Type: ApplicationFiled: May 8, 2024Publication date: September 19, 2024Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, JR.
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Publication number: 20240228888Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically the-pyoil is present in said feedstock in an amount of not more than 20% by weight, based on the total weight of the feedstock.Type: ApplicationFiled: March 20, 2024Publication date: July 11, 2024Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, JR.
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Patent number: 12018220Abstract: A predominantly C2 to C4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.Type: GrantFiled: May 22, 2020Date of Patent: June 25, 2024Assignee: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Patent number: 11946000Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically the-pyoil is present in said feedstock in an amount of not more than 20% by weight, based on the total weight of the feedstock.Type: GrantFiled: May 22, 2020Date of Patent: April 2, 2024Assignee: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220403254Abstract: Processes and systems for making recycle content hydrocarbons, including olefins, from recycled waste material. Recycle waste material may be pyrolyzed to form recycle content pyrolysis oil composition (r-pyoil), at least a portion of which may then be cracked to form a recycle content olefin composition (r-olefin). The r-olefin may then be further separated into product streams in a separation zone downstream of the cracker furnace. In some cases, presence of recycle content hydrocarbons may facilitate more efficient operation of one or more distillation columns in the separation zone, including the debutanizer.Type: ApplicationFiled: October 29, 2020Publication date: December 22, 2022Applicant: Eastman Chemical CompanyInventors: Michael Gary Polasek, Daryl Bitting, David Eugene Slivensky, Xianchun Wu, Carey Dan Ashcroft, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220340821Abstract: A predominantly C2 to C4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.Type: ApplicationFiled: May 22, 2020Publication date: October 27, 2022Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220282163Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.Type: ApplicationFiled: May 13, 2022Publication date: September 8, 2022Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220267679Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically the-pyoil is present in said feedstock in an amount of not more than 20% by weight, based on the total weight of the feedstock.Type: ApplicationFiled: May 22, 2020Publication date: August 25, 2022Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220228071Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly C4-C7 fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.Type: ApplicationFiled: May 22, 2020Publication date: July 21, 2022Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Patent number: 11365357Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.Type: GrantFiled: May 22, 2020Date of Patent: June 21, 2022Assignee: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220186124Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More specifically cracking the cracker feedstock in said cracker furnace to provide an olefin-containing effluent stream; wherein the hydrocarbon composition is predominantly ethane.Type: ApplicationFiled: May 22, 2020Publication date: June 16, 2022Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220154077Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. More particularly cracker feedstock comprises a recycle content pyrolysis oil composition (r-pyoil), wherein the cracker feedstock has a boiling point curve defined the following characteristics (i) through (iii): (i) a 90% boiling point at least 350° C.; (ii) a 10% boiling point of at least 60° C.; and (iii) a 50% boiling point in the range of from 95° C. to 200° C.Type: ApplicationFiled: May 22, 2020Publication date: May 19, 2022Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20220154082Abstract: A predominantly C2 to C4 hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to a first coil while a second cracker feed with none of the r-pyoil or less of the r-pyoil is fed to a second coil, and both are cracked in a cracker furnace to form an olefin-containing effluent stream. Alternatively, the r-pyoil can be fed and distributed across multiple coils along with the non-recycle cracker feed. The furnace can be a gas fed furnace, or split cracker furnace. Further, a first cracker stream with r-pyoil in a first coil can have a lower total molar flow rate than a second cracker stream in a second coil in the same furnace.Type: ApplicationFiled: May 22, 2020Publication date: May 19, 2022Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, Jr.
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Publication number: 20210363432Abstract: A hydrocarbon cracker stream is combined with recycle content pyrolysis oil to form a combined cracker stream and the combined cracker stream is cracked in a cracker furnace to provide an olefin-containing effluent. The r-pyoil can be fed to the cracker feed. Alternatively, the r-pyoil with a predominantly c8+ fraction can be fed to the cracker feed. The furnace can be a gas fed furnace, or split cracker furnace.Type: ApplicationFiled: May 22, 2020Publication date: November 25, 2021Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, JR.
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Publication number: 20200369966Abstract: A cracker stream is provided that contains a recycle content pyrolysis oil composition, a predominantly C5 to C22 hydrocarbon composition, and steam at a steam-to-hydrocarbon ratio of at least 0.60:1. The method for making olefins includes: (a) combining a predominantly C5 to C22 hydrocarbon stream with a recycle content pyrolysis oil composition (r-pyoil) to provide a combined cracker stream; and (b) cracking the combined cracker stream in a cracker furnace to provide an olefin-containing effluent stream, wherein the combined cracker stream contains steam at a steam-to-hydrocarbon ratio greater than 0.60:1. There is also provided a cracker stream including r-pyoil), a predominantly C2 to C4 hydrocarbon composition, and steam at a steam-to-hydrocarbon ratio of at least 0.20:1. Olefins can be made from this cracker stream as well.Type: ApplicationFiled: May 22, 2020Publication date: November 26, 2020Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, JR.
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Publication number: 20200369965Abstract: Olefins are made by passing a cracker stream through a convection section of a cracker furnace; introducing steam and a stream comprising a recycle content pyrolysis oil into the cracker stream to form a combined stream, and the steam, r-pyoil stream, or both are introduced downstream of the inlet to the convection section, such as between the inlet to the coils and the radiant zone, or at the cross-over. Additionally, dilution steam can be added to a stream of r-pyrolysis to form a steam-diluted r-pyoil stream which is then introduced into a cracker furnace at any location, such as downstream of the inlets to the convection box or at a cross-over.Type: ApplicationFiled: May 22, 2020Publication date: November 26, 2020Applicant: Eastman Chemical CompanyInventors: Daryl Bitting, Kenny Randolph Parker, Michael Gary Polasek, David Eugene Slivensky, Xianchun Wu, Jerome Leonard Stavinoha, JR.
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Patent number: 10544087Abstract: Disclosed is a process for performing a reductive amination of a first functional group in an organic feed substrate, which feed substrate comprises at least one further functional group containing a halogen atom, in the presence of hydrogen, a nitrogen-containing compound, and a catalyst, wherein the presence of the nitrogen-containing compound, expressed in a molar ratio relative to the first functional group in the organic feed substrate, at least during the reaction as long as the conversion of the organic feed substrate has not yet reached 80%, is maintained below a level of 1.3. Further disclosed is a composition of the invention comprising at least 98.0% wt of 2-chloro-benzyl-dimethylamine, at most 0.60% wt of the meso-o-Cl-BDMA dimer and at least 1 ppm wt of the (+/?)-o-Cl-BDMA dimer and any use therefor.Type: GrantFiled: September 10, 2019Date of Patent: January 28, 2020Assignee: Taminco BVBAInventors: Kristof Moonen, Kim Dumoleijn, Kristof Weyne, Jerome Leonard Stavinoha, Jr., Zhufang Liu