Abstract: Aqueous latex of vinylidene chloride copolymer An aqueous latex [latex (L)] of a vinylidene chloride copolymer [copolymer (A)], wherein the copolymer (A) consists essentially of recurring units derived from vinylidene chloride (VDC) in an amount comprised between 89.0 and 91.0 wt % of the copolymer, recurring units derived from methacrylonitrile (MAN) in an amount comprised between 2.00 and 5.50 wt % of the copolymer, recurring units derived from at least one ionic comonomer (ICO) in an amount comprised between 0.5 and 1.4 wt % of the copolymer (A), and recurring units derived from methylmethacrylate (MMA) in an amount such that the total of recurring units of VDC, MAN, ICO and MMA is 100 wt %, and wherein the latex (L) comprises at least one surfactant [surfactant (S)] in an amount comprised between 0.09 and 1.50 wt % of the copolymer (A). Process for the manufacture of the aqueous latex (L), film made therefrom and retort pouch prepared with such film.

Abstract: The invention pertains to an improved PVDC composition including certain dienophiles qualified for food contact, which possess an optimized balance of effectiveness in preventing discoloration upon exposure to radiation, with no negative impact on the barrier properties, in particular sorbate esters of formula (I), wherein R1 is a C1-C12 hydrocarbon group, preferably a C1-C6 alkyl group, to layers made therefrom, to multi-layer assemblies comprising the same, and to the use of said assemblies for packaging, in particular for packaging foodstuffs.

Abstract: The present invention relates to a process for preparing a vinylidene chloride polymer composite comprising a vinylidene chloride polymer and clay materials. The process comprises polymerising vinylidene chloride and clay materials and the resulting vinylidene chloride polymer particle is surrounded by a plurality of clay platelets. The clay materials according to the present invention function as a solid stabilizer in the process for preparing a vinylidene chloride polymer composite of the present invention. The present invention further relates to the vinylidene chloride polymer composite obtainable from the process, to use of the vinylidene chloride polymer composite for the preparation of films, and to films prepared therefrom.

Abstract: Process for the preparation of a vinylidene chloride polymer comprising polymerizing vinylidene chloride and optionally at least one ethylenically unsaturated monomer copolymerizable therewith under the control of a RAFT agent of formula (II).

Abstract: The invention pertains to an improved PVDC composition including certain dienophiles qualified for food contact, which possess an optimized balance of effectiveness in preventing discoloration upon exposure to radiation, with no negative impact on the barrier properties, in particular sorbate esters of formula (I), wherein R1 is a C1-C12 hydrocarbon group, preferably a C1-C6 alkyl group, to layers made therefrom, to multi-layer assemblies comprising the same, and to the use of said assemblies for packaging, in particular for packaging foodstuffs.

Abstract: The invention pertains to an improved PVDC composition including certain cinnamate dienophiles qualified for food contact, which possess an optimized balance of effectiveness in preventing discoloration upon exposure to radiation, with no negative impact on the barrier properties, in particular cinnamates of formula (I), wherein: —each of R1, R2, R3, equal to or different from each other, is H or a C1-C12 hydrocarbon group, to layers made therefrom, to multi-layer assemblies comprising the same, and to the use of said assemblies for packaging, in particular for packaging foodstuffs.

Abstract: The present invention relates to a process for preparing a vinylidene chloride polymer composite comprising a vinylidene chloride polymer and clay materials. The process comprises polymerising vinylidene chloride and clay materials and the resulting vinylidene chloride polymer particle is surrounded by a plurality of clay platelets. The clay materials according to the present invention function as a solid stabilizer in the process for preparing a vinylidene chloride polymer composite of the present invention. The present invention further relates to the vinylidene chloride polymer composite obtainable from the process, to use of the vinylidene chloride polymer composite for the preparation of films, and to films prepared therefrom.

Abstract: Process for the preparation of a vinylidene chloride polymer composite comprising a solid particulate encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a solid particulate material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerizable therewith to said dispersion; and polymerizing vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said solid particulate material.

Abstract: Process for the preparation of a vinylidene chloride polymer composite comprising a solid particulate encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a solid particulate material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerisable therewith to said dispersion; and polymerising vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said solid particulate material.

Abstract: Process for the preparation of a vinylidene chloride polymer composite comprising a clay material encapsulated in the vinylidene chloride polymer. The process comprises providing a dispersion of a clay material in a liquid phase, said dispersion comprising a RAFT/MADIX agent; providing vinylidene chloride and optionally one or more ethylenically unsaturated monomer copolymerisable therewith to said dispersion; and polymerising vinylidene chloride and said optionally present one or more ethylenically unsaturated monomer under the control of said RAFT/MADIX agent to form polymer at the surface of said clay material.

Abstract: A process for preparing a seed latex of an epoxy-containing polymer by radical polymerization in aqueous emulsion of at least one epoxy-containing monomer and optionally at least one comonomer is disclosed. Also disclosed are a process for preparing a vinylidene chloride polymer latex either by radical polymerization in aqueous emulsion of vinylidene chloride and optionally at least one comonomer in the presence of the epoxy-containing polymer seed latex obtained by the process according to the invention; or by mixing the epoxy-containing polymer seed latex with a vinylidene chloride polymer latex obtained separately by radical polymerization in aqueous emulsion.