Abstract: A method for pretreating an EUVL photomask having an exposed ruthenium surface includes subjecting the photomask to surface treatment in an oxidizing and reducing environment. Another method for pretreating an EUVL photomask having an exposed ruthenium surface includes subjecting the photomask to surface treatment in an oxidizing and reducing environment, and cleaning the photomask with a cleaning solution.

Abstract: Methods and etchant solutions for etching silicon nitride on a workpiece are provided. One method generally includes exposing the workpiece to a chemistry mixture including phosphoric acid and a diluent, wherein the chemistry mixture has a water content of less than 10% by volume, and heating at least one of the workpiece and the chemistry mixture to a process temperature to etch silicon nitride from the workpiece.

Abstract: To remove a silicon nitride layer on a silicon wafer, phosphoric acid is applied onto the wafer in a sealed chamber. The phosphoric acid may be atomized and sprayed onto the wafer as a mist or aerosol. The wafer is heated to a processing temperature and then maintained at or near the processing temperature with a coating of phosphoric acid on the wafer. The heating and applying phosphoric acid are then stopped, the wafer is cooled, and then removed from the process chamber. An infrared radiating assembly above the processing chamber may project infrared radiation into the chamber to heat the wafer. The wafer may be cooled by optionally spraying de-ionized water and/or nitrogen gas onto the workpiece. A cooling assembly may be used to cool an infrared radiating assembly. Silicon nitride is rapidly removed using very small amounts of phosphoric acid, and without the risks and disadvantages of conventional hot phosphoric bath techniques.

Abstract: A processing chamber successfully removes hardened photoresist via direct infrared radiation onto the wafer, in the presence of an acid such as sulfuric acid, optionally along with an oxidizer such as hydrogen peroxide. The processing chamber includes a fixture for holding and optionally rotating the wafer. An infrared irradiating assembly has infrared lamps outside of the processing chamber positioned to radiate infrared light into the processing chamber. The infrared lamps may be arranged to irradiate substantially the entire surface of a wafer on the rotor. A cooling assembly can be associated with the infrared radiating assembly to provide a quick cool down and avoid over-processing. Photoresist is removed using small amounts of chemical solutions.