Abstract: Rotational molding processes for producing hollow articles include the steps of: a) filling a mold with a polymer composition comprising: i) an organic polymer; and ii) a rotational molding densification accelerator (RMDA) selected from the group consisting of alkoxylated fatty alcohols, alkoxylated fatty esters, alkoxylated fatty amines, alkoxylated fatty amides, and combinations thereof; b) rotating the mold around at least one axis while heating the mold in an oven, thereby fusing the composition and spreading it to the walls of the mold; c) cooling the mold; and d) opening the mold; and e) removing the hollow article from the mold. The rotational molding processes using such polymer composition results in faster densification, which allows for reduction in overall cycle times for making the hollow articles.

Abstract: Stabilizer compositions having a stabilizing amount of at least one co-active agent; an ultraviolet light absorber chosen from an ortho-hydroxy benzophenone, and/or an ortho-hydroxyphenyl benzotriazole; and a hindered amine light stabilizer, are provided herein, along with masterbatch concentrates containing same, and processes for using same for stabilizing polymeric organic materials to protect against light and thermal degradation due to exposure to UV irradiation.

Abstract: Polymer compositions for making a stabilized polymeric articles that are resistant to discoloration upon exposure to UV-C light having: (i) an organic polymeric material; and (ii) a hindered phenol, organic phosphite, or a combination thereof, with the provisos that: (a) the OH group on the aromatic ring of the hindered phenol is flanked by two tertiary hydrocarbyl groups, and (b) the organic phosphite does not have any-OAr group linked directly to the P atom of the phosphite, wherein Ar represents an unsubstituted or substituted aryl group, are provided herein. Reduced discoloration is associated with the use of specific hindered phenols and the organic phosphites compared to other hindered phenols and organic phosphites, even in the absence of other polymer additives including UV absorbers, hindered amine light stabilizers (HALS), metal oxides and/or barium salts.

Abstract: Stabilized compositions having an organic material to be stabilized and a resin masterbatch system provided as closed end pellets are provided herein, along with processes for producing stabilized articles.

Abstract: Coating compositions having a polymeric binder and a stabilizer composition including at least one of a UV absorber, a hindered amine light stabilizer (HALS), or an inorganic UV blocker are provided herein, wherein said coating compositions are more resistant to discoloration when exposed to UV-C (190-280 nm) light compared to the coating compositions in the absence of the stabilizer composition. Thus, a method of stabilizing a coating composition against the deleterious effects of UV-C (190-280 nm) light includes adding to the coating composition an effective amount of such a stabilizer composition, wherein the coating composition is made more resistant to discoloration when exposed to UV-C (190-280 nm) light compared to the coating composition in the absence of the stabilizer composition. Coated articles can be made from the coating composition, and methods of making stabilized coating films include adding the stabilizer composition to the coating composition.

Abstract: Polymer compositions for making stabilized polymeric articles that are resistant to at least one deleterious effect of discoloration, cracking, or crazing upon exposure to UV-C (190-280 nm) light are provided herein, wherein the polymer compositions include: (i) an organic polymeric material; and (ii) a stabilizer composition comprising: an antioxidant selected from the group consisting of hindered phenols, phosphites and phosphonites, and mixtures thereof; and a light stabilizer selected from the group consisting of hindered amine light stabilizers (HALS), UV absorbers (UVA), hindered benzoates, and mixtures thereof, even where barium compounds (such as barium salts) are absent from the stabilizer composition, and with the proviso that the HALS is not bis(2,2,6,6,-tetramethyl-4-piperidyl) sebacate (TINUVIN™ 770) alone.

Abstract: Polymer compositions for making a stabilized polymeric articles that are resistant to discoloration upon exposure to UV-C light having: (i) an organic polymeric material; and (ii) a hindered phenol, organic phosphite, or a combination thereof, with the provisos that: (a) the OH group on the aromatic ring of the hindered phenol is flanked by two tertiary hydrocarbyl groups, and (b) the organic phosphite does not have any —OAr group linked directly to the P atom of the phosphite, wherein Ar represents an unsubstituted or substituted aryl group, are provided herein. Reduced discoloration is associated with the use of specific hindered phenols and the organic phosphites compared to other hindered phenols and organic phosphites, even in the absence of other polymer additives including UV absorbers, hindered amine light stabilizers (HALS), metal oxides and/or barium salts.

Abstract: Stabilized compositions having an organic material to be stabilized and a resin masterbatch system provided as closed end pellets are provided herein, along with processes for producing stabilized articles.

Abstract: Resin masterbatch compositions are provided as closed end pellets having a core including at least one additive and an outer layer comprising a polymer encapsulating the core, in which the thickness of the outer layer if from 0.001 mm to 1 cm. A stabilized composition is prepared from an organic material to be stabilized and the resin masterbatch composition. A process for producing the resin masterbatch composition includes co-extruding in tubular form a core material encapsulated by an outer layer, wherein the core material comprises at least one additive, and the outer layer comprises a polymer, to form a filled tube; passing the filled tube into a sealing device that cuts the filled tube into multiple discrete segments seals and simultaneously seals each end of each discrete segment, thereby forming closed end pellets; and cooling the closed end pellets.

Abstract: A process for producing a stabilized molded article including: combining a stabilizing amount of a thermal and ultraviolet (UV) light stabilizer composition with an organic material subject to degradation induced by light, heat or oxidation to form a stabilized organic material; and forming the stabilized organic material into a molded article, wherein the stabilizer composition comprises an ortho-hydroxyl tris-aryl-s-triazine compound; a hindered amine light stabilizer compound; a hindered hydroxybenzoate compound; an acid scavenger; a phosphite compound; a hindered phenol antioxidant compound; and a thioester compound.

Abstract: Resin masterbatch compositions are provided as closed end pellets having a core including at least one additive and an outer layer comprising a polymer encapsulating the core, in which the thickness of the outer layer if from 0.001 mm to 1 cm. A stabilized composition is prepared from an organic material to be stabilized and the resin masterbatch composition. A process for producing the resin masterbatch composition includes co-extruding in tubular form a core material encapsulated by an outer layer, wherein the core material comprises at least one additive, and the outer layer comprises a polymer, to form a filled tube; passing the filled tube into a sealing device that cuts the filled tube into multiple discrete segments seals and simultaneously seals each end of each discrete segment, thereby forming closed end pellets; and cooling the closed end pellets.

Abstract: A process for producing a stabilized molded article including: combining a stabilizing amount of a thermal and ultraviolet (UV) light stabilizer composition with an organic material subject to degradation induced by light, heat or oxidation to form a stabilized organic material; and forming the stabilized organic material into a molded article, wherein the stabilizer composition comprises an ortho-hydroxyl tris-aryl-s-triazine compound; a hindered amine light stabilizer compound; a hindered hydroxybenzoate compound; an acid scavenger; a phosphite compound; a hindered phenol antioxidant compound; and a thioester compound

Abstract: Stabilizer compositions for stabilizing materials against degradation due to thermal and ultraviolet light exposure are disclosed herein. In some instances, the stabilizer compositions include an ortho-hydroxyl tris-aryl-s-triazine compound; a hindered amine light stabilizer compound; a hindered hydroxybenzoate compound; a phosphite compound, an acid scavenger and/or thioester; and a hindered phenol antioxidant compound.

Abstract: Stabilizer compositions for stabilizing materials against degradation due to thermal and ultraviolet light exposure are disclosed herein.