Abstract: The present disclosure provides methods of compensation for capacity loss resulting from cycle-induced lithium consumption in an electrochemical cell including at least one electrode. Such methods may include adding a lithiation additive to the at least one electrode so as to create a lithium source. The lithium source compensates for cycle-induced lithiation loss such that the electrochemical cell having the lithiation additive experiences total capacity losses of less than or equal to about 5% of an initial capacity prior to cycling of lithium. The lithiation additive includes a lithium silicate represented by the formula LiuHr, where Hr=Liy-uSiOz and where 0?y?3.75 and 0?z?2 and u is a useable portion of y, 0?u?y. The lithium source may include z 4 ? L ? i 4 ? Si ? O 4 and LimSi, where 0?m?4.4.

Abstract: An electrode including an electrode active material and a ceramic hydrofluoric acid (HF) scavenger is provided. The ceramic hydrofluoric acid (HF) scavenger includes M2SiO3, MAlO2, M2O—Al2O3—SiO2, or combinations thereof, where M is lithium (Li), sodium (Na), or combinations thereof. Methods of making the electrode are also provided.

Abstract: Methods of making a solid-state electrochemical cell that cycles lithium ions are provided that include applying a liquid metal composition comprising gallium to a first major surface of either a solid-state electrolyte or a solid electrode (e.g., lithium metal) in the presence of an oxidant and in an environment substantially free of water to reduce surface tension of the liquid metal composition so that it forms a continuous layer over the first major surface. The first major surface having the continuous layer of liquid metal composition is contacted with a second major surface to form a continuous interfacial layer between the solid-state electrolyte and the solid electrode. Solid-state electrochemical cells formed by such methods are also provided, where the metal composition comprising gallium is a liquid in a temperature range of greater than or equal to about 20° C. to less than or equal to about 30° C.

Abstract: A ceramic-coated separator for a lithium-containing electrochemical cell and methods of preparing the ceramic-coated separator are provided. The ceramic-coated separator may be manufactured by preparing a slurry that includes one or more lithiated oxides and a binder and disposing the slurry onto one or more surfaces of a porous substrate. The slurry may be dried to from a ceramic coating on the one or more surfaces of the porous substrate so as to create the ceramic-coated separator. The ceramic coating may include one or more lithiated oxides selected from Li2SiO3, LiAlO2, Li2TiO3, LiNbO3, Li3PO4, Li2CrO4, and Li2Cr2O7.

Abstract: Methods of making a solid-state electrochemical cell that cycles lithium ions are provided that include applying a liquid metal composition comprising gallium to a first major surface of either a solid-state electrolyte or a solid electrode (e.g., lithium metal) in the presence of an oxidant and in an environment substantially free of water to reduce surface tension of the liquid metal composition so that it forms a continuous layer over the first major surface. The first major surface having the continuous layer of liquid metal composition is contacted with a second major surface to form a continuous interfacial layer between the solid-state electrolyte and the solid electrode. Solid-state electrochemical cells formed by such methods are also provided, where the metal composition comprising gallium is a liquid in a temperature range of greater than or equal to about 20° C. to less than or equal to about 30° C.

Abstract: An electrode including an electrode active material and a ceramic hydrofluoric acid (HF) scavenger is provided. The ceramic hydrofluoric acid (HF) scavenger includes M2SiO3, MAlO2, M2O—Al2O3—SiO2, or combinations thereof, where M is lithium (Li), sodium (Na), or combinations thereof. Methods of making the electrode are also provided.

Abstract: The present disclosure provides methods of compensation for capacity loss resulting from cycle-induced lithium consumption in an electrochemical cell including at least one electrode. Such methods may include adding a lithiation additive to the at least one electrode so as to create a lithium source. The lithium source compensates for cycle-induced lithiation loss such that the electrochemical cell having the lithiation additive experiences total capacity losses of less than or equal to about 5% of an initial capacity prior to cycling of lithium. The lithiation additive includes a lithium silicate represented by the formula LiuHr, where Hr=Liy-uSiOz and where 0?y?3.75 and 0?z?2 and u is a useable portion of y, 0?u?y. The lithium source may include z/4 Li4SiO4 and LimSi, where 0?m?4.4.

Abstract: A ceramic-coated separator for a lithium-containing electrochemical cell and methods of preparing the ceramic-coated separator are provided. The ceramic-coated separator may be manufactured by preparing a slurry that includes one or more lithiated oxides and a binder and disposing the slurry onto one or more surfaces of a porous substrate. The slurry may be dried to from a ceramic coating on the one or more surfaces of the porous substrate so as to create the ceramic-coated separator. The ceramic coating may include one or more lithiated oxides selected from Li2SiO3, LiAlO2, Li2TiO3, LiNbO3, Li3PO4, Li2CrO4, and Li2Cr2O7.

Abstract: A composite porous separator for an electrochemical cell of a secondary lithium ion battery includes particles of a lithium ion-exchanged zeolite material. The composite porous separator may be manufactured by preparing a slurry comprising a polymeric binder material and the particles of the lithium ion-exchanged zeolite material, and then depositing the slurry on one or more sides of a porous substrate. Thereafter, the slurry may be dried to form a solid microporous active layer on the one or more sides of the substrate.

Abstract: Electrostatic dry powder spray processes are disclosed for making battery electrodes. The electrodes made by dry powder coating processes are conventional lithium ion battery electrodes and unconventional electrodes of gradient in composition and structure, large thicknesses, free-standing, and flexible.