Abstract: The present invention provides a single-crystal high-nickel positive electrode material and a preparation method therefor and an application thereof. The preparation method comprises the following steps: (1) mixing a precursor, a lithium source, and a nano oxide, and performing primary sintering treatment in an oxygen-containing atmosphere to obtain a primary sintered material; and (2) mixing the primary sintered material obtained in step (1) with a titanium source and a cobalt source, and performing secondary sintering treatment in an oxygen-containing atmosphere to obtain the single-crystal high-nickel positive electrode material. The present invention uses a Ti/Co co-coating method, the residual alkali amount of the prepared single-crystal high-nickel positive electrode material can be greatly reduced, and the capacity and the rate capability can also be kept at a high level, so that the technological process is reduced, and the cost is reduced.

Abstract: A composite material and a preparation method therefor and a lithium-ion battery positive electrode material. The preparation method for the composite material comprises the following steps: performing first calcination treatment on a mixture of a manganese source, a nickel source, a lithium source and a cobalt source to obtain cobalt-doped lithium nickel manganese oxide; and performing second calcination treatment on a mixture of the cobalt-doped lithium nickel manganese oxide and silicon dioxide.

Abstract: Provided are a cobalt-free positive electrode material, a preparation method thereof and a lithium ion battery. The preparation method includes: first sintering step is performed on a lithium source material and a cobalt-free precursor, to obtain a sintered product; the sintered product is crushed to 1 to 2 ?m, to obtain a cobalt-free single crystal material; and second sintering step is performed on the cobalt-free single crystal material, a boron coating agent and a carbon coating agent, to obtain the cobalt-free positive electrode material. The cobalt-free positive electrode material prepared by the above method has advantages of stable structure, high electric capacity, excellent current rate performance and good cycle performance and the like.

Abstract: The present disclosure provides a boron oxide-coated quaternary cathode electrode material and a preparation method and application thereof. The boron oxide-coated quaternary cathode electrode material includes a quaternary cathode electrode material matrix and a boron oxide coating layer, the boron oxide coating layer is arranged on the surface of the quaternary cathode electrode material matrix, and the quaternary cathode electrode material matrix, is LiaNixCoyMnzAl(1-x-y-z)O2, herein a=1-1.06, x=0.8-0.9, y=0.01-0.1, and z=0.01-0.1.

Abstract: A positive electrode material, a preparation method therefor and a lithium ion battery. The positive electrode material has a core-shell structure, the core layer comprises a cobalt-free single crystal positive electrode active material, and the shell layer comprises LiAlO2 and LiFePO4. By coating the surface of the cobalt-free single crystal positive electrode active material with LiAlO2 and LiFePO4, the conductivity of the cobalt-free single crystal layered positive electrode material is improved, thereby improving the capacity, the rate and the cyclability of the material.

Abstract: Provided are a lithium nickel manganese oxide composite material, a preparation method thereof and a lithium ion battery. The preparation method includes: a first calcining process is performed on a nano-oxide and a nickel-manganese precursor, to obtain an oxide-coated nickel-manganese precursor; and a second calcining process is performed on the precursor and a lithium source material, to obtain the lithium nickel manganese oxide, and a temperature of the first calcining process is lower than the second calcining process. At a lower temperature, the nano-oxide may be melted, a denser nano-oxide coating layer is formed on the surface of the precursor, so the oxide-coated nickel-manganese precursor is obtained. At a higher temperature, the nano-oxide, a nickel-manganese material and a lithium element may be more deeply combined. A problem that the nano-oxide layer is easy to fall off is solved, and cycle performance of the lithium nickel manganese oxide is greatly improved.

Abstract: A cobalt-free layered positive electrode material, a preparation method thereof, and a lithium-ion battery are provided. The method includes: preparing a layered lithium nickel manganese oxide matrix material; mixing the layered lithium nickel manganese oxide matrix material with a coating agent to obtain a first mixed material; and forming a coating layer on a surface of the layered lithium nickel manganese oxide matrix material by performing a first sintering treatment on the first mixed material to obtain the cobalt-free layered positive electrode material. The coating agent includes a first coating agent including ceramic oxide, and a second coating agent including at least one of phosphate and silicate.

Abstract: Provided are a cobalt-free positive electrode material for a lithium ion battery, a preparation method therefor and a lithium ion battery. The method for preparing the cobalt-free positive electrode material for the lithium ion battery comprises: mixing lithium nickel manganese oxide with sulfate, so as to obtain a first mixture; and reacting the first mixture at a predetermined temperature, so as to obtain the cobalt-free positive electrode material. The cobalt-free positive electrode material comprises lithium nickel manganese oxide and a cladding layer of an outer surface thereof, and the cladding layer comprises lithium sulphate. The lithium ion battery comprises the cobalt-free positive electrode material. The cobalt-free positive electrode material has a relatively high electrical performance and a relatively low alkali content.

Abstract: A composite positive electrode material for a lithium ion battery, a preparation method therefor, and a use thereof. The composite positive electrode material comprises a positive electrode material core and a halide coating layer that is coated on the surface of the positive electrode material core, wherein halide comprises Li3YX6, and X is at least one among halogens. By means of the coating of the halide coating layer, the ionic conductivity and structural stability of the positive electrode material are greatly increased, which reduces the surface impedance of the material.

Abstract: A cobalt-free single crystal composite material, and a preparation method therefor and a use thereof. The cobalt-free single crystal material is of a core-shell structure, the core layer is the cobalt-free single crystal material, and the shell layer is prepared from TiNb2O7 and conductive lithium salt. The TiNb2O7 and the conductive lithium salt are selected as materials of the shell layer to coat the cobalt-free single crystal material, thereby improving the lithium ion conductivity of the cobalt-free single crystal material, and further improving the capacity and the first effect of the material.

Abstract: A gradient doped cobalt-free positive electrode material and a preparation method therefor, a lithium-ion battery positive electrode, and a lithium battery. The positive electrode material consists of LiNixMnyAzO2. The content of element A in the positive electrode material decreases in a direction from a surface layer of the positive electrode material to the center, and A is one or more of Al, Zr, Ti, B, and W. The preparation method is easy to implement, simplifies roasting condition requirements, and provides a cobalt-free positive electrode material having good cycle performance.

Abstract: A cobalt-free positive electrode material and a preparation method therefor, a lithium ion battery positive electrode, and a lithium ion battery, relating to the technical field of lithium ion batteries. The positive electrode material comprises a core and a shell covering the core, the core being a cobalt-free positive electrode material, the chemical formula of the core being LiNixMnyO2, wherein 0.55?x?0.95 and 0.05?y?0.45, and the shell is a coating agent and carbon. The present method can improve the dispersibility of the cobalt-free positive electrode material during the coating process, and can also improve the conductivity of the cobalt-free positive electrode material.

Abstract: The present disclosure provides a cobalt-free cathode material of a lithium ion battery, a method for preparing the cobalt-free cathode material, and the lithium ion battery. A general formula of the cobalt-free cathode material is LixNiaMnbRcO2, wherein, 1?x?1.15, 0.5?a?0.95, 0.02?b?0.48, 0<c?0.05, and R is aluminum or tungsten. Therefore, as the cobalt-free cathode material is free of metal cobalt, the cost of the cathode material can be lowered effectively. Aluminum or tungsten in the cobalt-free cathode material can stabilize a crystal structure of the cathode material better, such that the lithium ion battery has excellent rate capability and cycle performance, and furthermore, good cycling stability of the lithium ion battery can be still maintained under a high-temperature and high-pressure testing condition.

Abstract: The present disclosure provides a cobalt-free lamellar cathode material and a method for preparing the cobalt-free lamellar cathode material, and a lithium ion battery. The cobalt-free lamellar cathode material is of a core-shell structure, and a material forming an outer shell of the core-shell structure comprises titanium nitride and a material forming an inner core of the core-shell structure does not comprise cobalt and is of a monocrystal structure. According to the cobalt-free lamellar cathode material provided by the present disclosure, the surface of the cobalt-free inner core is coated with highly conductive titanium nitride, such that while the price cost of the cathode material is lowered, the rate capability of the cathode material can be improved, and thus the rate capability of the cobalt-free cathode material is better.

Abstract: The present disclosure provides a cobalt-free lamellar cathode material of a lithium ion battery, a method for preparing the cobalt-free lamellar cathode material, and a lithium ion battery. The cobalt-free lamellar cathode material comprises lamellar nickel lithium manganate of monocrystal morphology and zinc oxide coated onto a surface of the nickel lithium manganate, wherein a general formula of the nickel lithium manganate is LiNixMn1?xO2, and 0.95. Therefore, manganese ions in nickel lithium manganate can be effectively prevented from being dissolved by an electrolyte of the lithium ion battery by coating the surface of the lamellar nickel lithium manganate of monocrystal morphology with zinc oxide, such that the specific capacity, the first time charge efficiency (first efficiency for short) and the cycle performance of the lithium ion battery can be further effectively improved.

Abstract: The present disclosure provides a cobalt-free lamellar cathode material and a method for preparing the cobalt-free lamellar cathode material, a cathode piece and a lithium ion battery. The cobalt-free lamellar cathode material comprises a LiNixMnyO2 crystal, wherein x+y=1, 0.55?x?0.95, 0.05?y?0.45; and a lithium ion conductor, the lithium ion conductor being attached to at least part of a surface of the LiNixMnyO2 crystal. The cobalt-free lamellar cathode material has the advantages of low cost, low surface impedance and good conductivity. Lithium ions have high diffusion velocity and electrochemical activity in the cobalt-free lamellar cathode material. A lithium ion battery manufactured by the cobalt-free lamellar cathode material has the advantages of high charge specific capacity, high discharge specific capacity, high first effect, good cycle performance and good rate capability.