Abstract: The present invention relates to a preparation method for and an application of a chiral spirocyclic phosphine-nitrogen-phosphine tridentate ligand SpiroPNP and an iridium catalyst Ir-SpiroPNP thereof. The chiral spirocyclic phosphine-nitrogen-phosphine tridentate ligand is a compound represented by formula I, or a racemate or optical isomer thereof, or a catalytically acceptable salt thereof, and the main structural feature is a phosphine ligand having a chiral spiro indene skeleton and a large sterically hindered substituent. The chiral spirocyclic phosphine-nitrogen-phosphine tridentate ligand can be synthesized into a chiral starting material from a 7-diaryl/alkylphosphino-7?-amino-1,1?-spirodihydroindenyl compound having a spiro ring skeleton. The iridium catalyst of the chiral spirocyclic phosphino-7?-amino-1,1?-spirodihydroindenyl compound having a sprio ring skeleton.

Abstract: The present invention relates to kinetic resolution of racemic ?-hydroxyl ester via asymmetric catalytic hydrogenation and an application thereof. In the presence of chiral spiro pyridyl phosphine ligand Iridium catalyst and base, racemic ?-hydroxyl esters were subjected to asymmetric catalytic hydrogenation to obtain extent optical purity chiral ?-hydroxyl esters and corresponding 1,5-diols. An optically active chiral ?-hydroxyl ester and 1,5-diols can be obtained at very high enantioselectivity and yield with relatively low usage of catalyst. The chiral ?-hydroxyl ester and 1,5-diols obtained by using the method can be used as a critical raw material for asymmetric synthesis of chiral drugs (R)-lisofylline and natural drugs (+)-civet, (?)-indolizidine 167B and (?)-coniine.

Abstract: The present invention relates to a chiral spiro phosphine-nitrogen-sulfur (P—N—S) tridentate ligand, preparation method and application thereof. The P—N—S tridentate ligand is a compound represented by Formula I or Formula II, their racemates, optical isomers, or catalytically acceptable salts thereof. The ligand has a primary structure skeleton characterized as a chiral spiro indan skeleton structure with a thio group. The chiral spiro phosphine-nitrogen-sulfur tridentate ligand can be synthesized by reacting racemic or optical active compound 7-diary/alkyl phosphine-7?-amino-1, 1?-spiro-dihydro-indene compound having a spiro-dihydro-indene skeleton as the starting material. The chiral spiro P—N—S tridentate ligand being complex with transition metal salt can be used in an asymmetric catalytic hydrogenation reaction for catalyzing carbonyl compound.

Abstract: The invention relates to a device for online measurement of gas flowrate and liquid flowrate of a wet gas in a horizontal pipe, comprising the following parts: a horizontal Venturi tube, comprising a truncated cone-shaped inlet pipesection with section area reduced gradually, a cylindrical throat pipesection and a truncated cone-shaped outlet pipesection with section area increased gradually; and a gamma ray monitor, comprising a gamma ray emitter and a gamma ray detector arranged in a manner that gamma rays emitted by the gamma ray emitter can radially pass through the cross section of the throat pipesection to reach the gamma ray detector. The invention also relates to a method for online measurement of gas flowrate and liquid flowrate of a wet gas in a horizontal pipe by using above device.

Abstract: The present invention relates to a chiral spiro phosphine-nitrogen-sulfur (P—N—S) tridentate ligand, preparation method and application thereof. The P—N—S tridentate ligand is a compound represented by Formula I or Formula II, their racemates, optical isomers, or catalytically acceptable salts thereof. The ligand has a primary structure skeleton characterized as a chiral spiro indan skeleton structure with a thio group. The chiral spiro phosphine-nitrogen-sulfur tridentate ligand can be synthesized by reacting racemic or optical active compound 7-diary/alkyl phosphine-7?-amino-1,1?-spiro-dihydro-indene compound having a spiro-dihydro-indene skeleton as the starting material. The chiral spiro P—N—S tridentate ligand being complex with transition metal salt can be used in an asymmetric catalytic hydrogenation reaction for catalyzing carbonyl compound.

Abstract: The present invention relates to kinetic resolution of racemic ?-hydroxyl ester via asymmetric catalytic hydrogenation and an application thereof. In the presence of chiral spiro pyridyl phosphine ligand Iridium catalyst and base, racemic ?-hydroxyl esters were subjected to asymmetric catalytic hydrogenation to obtain extent optical purity chiral ?-hydroxyl esters and corresponding 1,5-diols. The method is a new, efficient, highly selective, economical, desirably operable and environmentally friendly method suitable for industrial production. An optically active chiral ?-hydroxyl ester and 1,5-diols can be obtained at very high enantioselectivity and yield with relatively low usage of catalyst. The chiral ?-hydroxyl ester and 1,5-diols obtained by using the method can be used as a critical raw material for asymmetric synthesis of chiral drugs (R)-lisofylline and natural drugs (+)-civet, (?)-indolizidine 167B and (?)-coniine.

Abstract: Techniques for identifying stream fingerprints are provided. A stream of data packets may be received. In one aspect, a stream fingerprint may be determined based on the stream of data packets. An application associated with the stream may be determined based on the stream fingerprint. In another aspect, a stream may be partially matched while a fully matched stream fingerprint has not been determined. As additional packets are received, the stream may become fully matched.

Abstract: The invention relates to a device for online measurement of gas flowrate and liquid flowrate of a wet gas in a horizontal pipe, comprising the following parts: a horizontal Venturi tube, comprising a truncated cone-shaped inlet pipesection with section area reduced gradually, a cylindrical throat pipesection and a truncated cone-shaped outlet pipesection with section area increased gradually; and a gamma ray monitor, comprising a gamma ray emitter and a gamma ray detector arranged in a manner that gamma rays emitted by the gamma ray emitter can radially pass through the cross section of the throat pipesection to reach the gamma ray detector. The invention also relates to a method for online measurement of gas flowrate and liquid flowrate of a wet gas in a horizontal pipe by using above device.

Abstract: The present invention relates to a chiral spiro-pyridylamidophosphine ligand compound, synthesis method therefor and application thereof. The chiral spiro-pyridylamidophosphine compound is a compound having a structure of Formula (I), a racemate or optical isomer thereof, or a catalytically acceptable salt thereof, and is mainly characterized by having a chiral spiro-dihydro-indene skeleton in its structure. The chiral spiro-pyridylamidophosphine compound may be synthesized with optical active 7-diaryl/alkylphosphino-7?-amino-1,1?-spiro-dihydro-indene or substituted 7-diaryl/alkylphosphino-7?-amino-1,1?-spiro-dihydro-indene having a spiro-skeleton as chiral starting material. The chiral spiro-pyridylamidophosphine compound may be used as a chiral ligand in asymmetric hydrogenation of a carbonyl compound catalyzed by iridium, in which the reaction activity is very high, the amount of the catalyst may be 0.0001 mol %, and the enantioselectivity of the reaction is up to 99.9% ee.

Abstract: Techniques for identifying stream fingerprints are provided. A stream of data packets may be received. In one aspect, a stream fingerprint may be determined based on the stream of data packets. An application associated with the stream may be determined based on the stream fingerprint. In another aspect, a stream may be partially matched while a fully matched stream fingerprint has not been determined. As additional packets are received, the stream may become fully matched.

Abstract: The present invention relates to a chiral spiro-pyridylamidophosphine ligand compound, synthesis method therefor and application thereof. The chiral spiro-pyridylamidophosphine compound is a compound having a structure of Formula (I), a racemate or optical isomer thereof, or a catalytically acceptable salt thereof, and is mainly characterized by having a chiral spiro-dihydro-indene skeleton in its structure. The chiral spiro-pyridylamidophosphine compound may be synthesized with optical active 7-diaryl/alkylphosphino-7?-amino-1,1?-spiro-dihydro-indene or substituted 7-diaryl/alkylphosphino-7?-amino-1,1?-spiro-dihydro-indene having a spiro-skeleton as chiral starting material. The chiral spiro-pyridylamidophosphine compound may be used as a chiral ligand in asymmetric hydrogenation of a carbonyl compound catalyzed by iridium, in which the reaction activity is very high, the amount of the catalyst may be 0.0001 mol %, and the enantioselectivity of the reaction is up to 99.9% ee.

Abstract: A method and system of enabling VOD systems efficiently caching contents (video programs) on its edge servers or user premises equipment. A new user interface and a new VOD system component are introduced. The new user interface allows viewers to specify not only the name of the video programs, but also the time and date they want to start watching them. The new VOD system component is used to receive and store video requests from users and calculate when is the best time to start caching the video programs requested to edge servers or user premises equipment based on a set of criteria, such as user input from the new user interface, network traffic condition pattern during a day, etc.

Abstract: A method and system of enabling real-time network protocol analysis of network data by a post-time network protocol analyzing software that is incompatible with a real-time protocol analyzing software real-time capturing network data, by controlling the real-time protocol analyzing software and taking over a communication socket opened by the real-time protocol analyzing software, thereby transparently porting the post-time network protocol analyzing software to the real-time protocol analyzing software. Further, a method and system of enabling the post-time network data analyzer software to analyze network data captured concurrently in real-time from two or more of the real-time protocol analyzing software based upon time stamping by the real-time protocol analyzing software of every data frame received over the taken-over sockets.