Abstract: The disclosed is a carbon fibrous conjunct in a granule form which comprises carbon fibrous structures and a binder by which the carbon fibrous structures are bound together, wherein mean diameter of the carbon fibrous conjunct is in the range of 0.03 mm-5 mm, and density of the carbon fibrous conjunct is in the range of 0.003-0.5 g/cm3, and wherein each of the carbon fibrous structures comprises carbon fibers each having an outside diameter of 15-100 nm and a carbon granular part with which the carbon fibers are bound in the state that the carbon fibers extend outwardly from the granular part to form a three dimensional network of the carbon fibers, and wherein the granular part and the carbon fibers are bound together by carbon-carbon bonds.

Abstract: Disclosed is a fine carbon fibrous structure which comprises carbon fibers and granular parts, wherein at least two granular parts connect by at least one of the carbon fibers; wherein the fine carbon fibrous structure have a D2/D1 ratio of 1.3 to 10, wherein the D1 is the median diameter of outer diameters of the carbon fibers and the D2 is the area-based circle-equivalent median diameter of the particles; wherein the granular parts have a D2 of 0.05 to 0.4 ?m; wherein the carbon fibers have a median length of not more than 20 ?m; wherein the granular parts are produced in a growth process of the carbon fibers; and wherein at least a graphene layer which exists on and constitutes the surface of each granular part is continued on a graphene layer which exists on and constitutes the surface of the carbon fiber which connects between the granular parts.

Abstract: A method for forming a carbon fibrous structure having a plurality of granular parts, to which a plurality of carbon fibers are bound, includes heating a mixture of a carbon source and a catalyst at a temperature between 800 ° C. and 1300 ° C. to produce aggregates of a first intermediate, heating the aggregates of the first intermediate to remove hydrocarbons, at a temperature between 800 ° C. and 1200 ° C. to produce aggregates of a first product, heating the aggregates of the first product at a temperature between 2400 ° C. and 3000 ° C. to produce aggregates of a final product; and pulverizing the aggregates of the final product such that area-based circle-equivalent mean diameter of each aggregate of the carbon fibrous structure of the product is 50-100 ?m, bulk density of the carbon fibrous structure is 0.0001-0.02 g/cm3, and powder resistance under pressed density of 0.8g/cm3 is not more than 0.02 ?·cm.

Abstract: An composite material is disclosed, which includes carbon fibrous structures which are capable of being included in a relatively large amount in the composite material, and which are capable of improving the physical properties, such as electric, mechanical, or thermal properties. The carbon fibrous structure comprises (a) carbon fibrous structures each of which comprises a three dimensional network of carbon fibers, each of the carbon fibers having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part, at which the carbon fibers are bound in a state that the carbon fibers are extended outwardly therefrom, and wherein the granular part is produced in a growth process of the carbon fibers, and (b) an material other than the carbon fibrous structures, wherein the amount of carbon fibrous structures added is more than 30% and not more than 100% by weight of the total weight of the composite.

Abstract: An composite material is disclosed, which includes carbon fibrous structures which are capable of being included in a relatively large amount in the composite material, and which are capable of improving the physical properties, such as electric, mechanical, or thermal properties. The carbon fibrous structure comprises (a) carbon fibrous structures each of which comprises a three dimensional network of carbon fibers, each of the carbon fibers having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part, at which the carbon fibers are bound in a state that the carbon, fibers are extended outwardly therefrom, and wherein the granular part is produced in a growth process of the carbon fibers, and (b) an material other than the carbon fibrous structures, wherein the amount of carbon fibrous structures added is more than 30% and not more than 100% by weight of the total weight of the composite.

Abstract: Disclosed is a carbon fibrous structure which comprises a granular part and 2-20 pieces of carbon fibers each of which has an outside diameter of 15-100 nm and which are extend outwardly from the granular part, wherein the granular part is produced in a growth process of the carbon fibers, wherein the size of granular part is 1.3 or more of times larger than the outside diameter of the carbon fibers, and wherein the mean length of the carbon fibers is not more than 20 ?m. The carbon fibrous structure improves the physical properties of the matrix, such as electric, mechanical, or thermal properties, while maintaining the other properties of the matrix, even when added at a small amount.

Abstract: A three dimensional network of carbon fibrous structure includes a granular part formed by thermal decomposition of carbon in peripheral directions of a catalyst; and a plurality of carbon fibers each having an outside diameter of 15-100 nm and bound to the granular part and extending outwardly from the granular part, wherein an outside diameter of the granular part is larger than an outside diameter of each carbon fiber, and wherein the plurality of carbon fibers are fused together at the granular part during the formation of the carbon fibrous structure. The granular part may look like a knot of the plurality of carbon fibers. The carbon fibers may be tubular carbon fibers that are bound to the granular part, but are not entangled with each other.

Abstract: A composition for injection molding by which a reactive injection molded article of good mechanical strength and electrical conductivity is prepared is provided. The disclosed is a composition for injection molding which includes carbon fibrous structures in a liquid curing resin composition, at a rate of 0.1-20% by weight based on the total weight of the composition, wherein the carbon fibrous structure comprises a three dimensional network of carbon fibers each having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part with which the carbon fibers are tied together in the state that the concerned carbon fibers are externally elongated therefrom, and wherein the granular part is produced in a growth process of the carbon fibers.

Abstract: A method for forming a carbon fibrous structure having a granular part, to which a plurality of carbon fibers are bound, includes heating a mixture of a carbon source and a catalyst at a temperature between 800 and 1300° C. to produce a first intermediate, and heating the first intermediate to remove hydrocarbons, at a temperature between 800 and 1200° C. to produce a first product. The method further includes heating the first product at a temperature between 2400 and 3000° C. to produce a final product. The carbon source includes at least two compounds having different decomposition temperatures or a compound that can produce, when heated at a temperature between 800 and 1300° C., at least two components having different decomposition temperatures. The catalyst may include an iron-containing catalyst, which may be introduced into a reaction chamber in a gaseous state, without being deposited on a substrate.

Abstract: The disclosed is an electrically conductive sheet which includes carbon fibrous structures in polymer matrix, at a rate of 0.01-30% by weight based on the total weight of the sheet, wherein the carbon fibrous structure comprises a three dimensional network of carbon fibers each having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part with which the carbon fibers are tied together in the state that the concerned carbon fibers are externally elongated therefrom, and wherein the granular part is produced in a growth process of the carbon fibers. The electrically conductive sheet shows a high electrical conductivity while possessing a good film strength.

Abstract: An recycled composite material is disclosed, which is prepared by using as a raw material a waste composite material which comprises a matrix component and carbon fibrous structures added to the matrix, and adding an additional matrix component which is homogeneous and/or heterogeneous with the matrix of the spent composite material, and then kneading them together; wherein the carbon fibrous structure comprises a three dimensional network of carbon fibers, each carbon fiber having an outside diameter of 15-100 nm, and a granular part, at which the fibers are bound in a state that the carbon fibers extend outwardly therefrom, and wherein the granular part is produced in a growth process of the carbon fibers. The recycled composite material performs much the same with the original composite material, and is produced briefly at a low cost.

Abstract: Disclosed is a carbon fibrous structure which comprises a granular part and 2-20 pieces of carbon fibers each of which has an outside diameter of 15-100 nm and which are extend outwardly from the granular part, wherein the granular part is produced in a growth process of the carbon fibers, wherein the size of granular part is 1.3 or more of times larger than the outside diameter of the carbon fibers, and wherein the mean length of the carbon fibers is not more than 20 ?m. The carbon fibrous structure improves the physical properties of the matrix, such as electric, mechanical, or thermal properties, while maintaining the other properties of the matrix, even when added at a small amount.

Abstract: The disclosed is a conductive coating material which includes an organic binder component and carbon fibrous structures, wherein the carbon fibrous structure comprises a three dimensional network of carbon fibers each having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part with which the carbon fibers are tied together in the state that the concerned carbon fibers are externally elongated therefrom, and wherein the granular part is produced in a growth process of the carbon fibers; and wherein the carbon fibrous structures are contained at a rate of 0.01-50% by weight based on the total weight of the coating material. The conductive coating material gives a coated film which shows a high electrical conductivity and a good film strength, and also coordinates its color as an intended one easily.

Abstract: The disclosed is a colored polymer composition which includes carbon fibrous structures and a coloring agent in a polymer matrix, wherein the carbon fibrous structure comprises a three dimensional network of carbon fibers each having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part with which the carbon fibers are tied together in the state that the concerned carbon fibers are externally elongated therefrom, and wherein the granular part is produced in a growth process of the carbon fibers. It is the colored polymer composition which includes novel carbon fibrous structures having preferable physical properties as a filler for composite material, and of being able to improve electrical, mechanical and thermal properties of a matrix while maintaining other properties of the matrix, in a small adding amount, and which can show a color as pleases.

Abstract: An electron emission Source is disclosed, in which the fine carbon fibers included are uniformly dispersed as compared with those in the conventionally known electron emission sources, and the manufacturing of which is also easy. The electron emission source is manufactured by preparing a carbon fibrous structures' dispersion which comprises at least carbon fibrous structures and a binder resin, wherein carbon fibrous structure comprises a three dimensional network of carbon fibers, each of which having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part, at which two or more carbon fibers are bound in a state that the carbon fibers extend outwardly therefrom, and wherein the granular part is produced in a growth process of the carbon fibers; applying the carbon fibrous structures' dispersion onto the substrate; and solidifying the applied carbon fibrous structures' dispersion.

Abstract: A thermoplastic elastomeric composition which have an improved compression set and good electrical properties is provided. The disclosed is thermoplastic elastomeric composition which includes 0.1-30 parts by weight of carbon fibrous structures per 100 parts by weight of a thermoplastic elastomer, wherein the carbon fibrous structure comprises a three dimensional network of carbon fibers each having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part with which the carbon fibers are tied together in the state that the concerned carbon fibers are externally elongated therefrom, and wherein the granular part is produced in a growth process of the carbon fibers.

Abstract: Disclosed is a fine carbon fibrous structure which comprises carbon fibers and granular parts, wherein at least two granular parts connect by at least one of the carbon fibers; wherein the fine carbon fibrous structure have a D2/D1 ratio of 1.3 to 10, wherein the D1 is the median diameter of outer diameters of the carbon fibers and the D2 is the area-based circle-equivalent median diameter of the particles; wherein the granular parts have a D2 of 0.05 to 0.4 ?m; wherein the carbon fibers have a median length of not more than 20 ?m; wherein the granular parts are produced in a growth process of the carbon fibers; and wherein at least a graphene layer which exists on and constitutes the surface of each granular part is continued on a graphene layer which exists on and constitutes the surface of the carbon fiber which connects between the granular parts.

Abstract: Disclosed is a method for manufacturing carbon fibrous structures each of which comprises a three dimensional network of carbon fibers, which is characterized in that, in the procedure of carbon fiber vapor phase deposition utilizing decomposition of organic carbon compound, at least two kinds of organic carbon compounds as carbon sources are in existence at least at predetermined thermal decomposition reaction temperature range in a reaction furnace and partial pressures of gases of these compounds are regulated so that these compounds are decomposed at mutually different decomposition temperatures, and/or a raw material gas supplied into the reaction furnace is forced to form a turbulent flow. It is possible to obtain efficiently the carbon fibrous structures each of which comprises a three dimensional network of carbon fibers and which are suitable as additives to be added to solid materials, such as resin, ceramics, metal, etc.

Abstract: Disclosed is a method for manufacturing fine carbon fibers' aggregates having a median diameter of not more than 30 ?m, which comprises a pulverization step where a composition which includes (a) fine carbon fibers' aggregates having a median diameter of not less than 30 ?m and (b) a dispersion medium undergoes acceleration in order to form a turbulent flow and/or collision flow, thereby shearing force and/or impacting force exert on the (a) component included in the composition and thus the (a) component is pulverized, wherein the value of [ID/IG of fine carbon fibers' aggregates after pulverization of the (a) component]/[ID/IG of fine carbon fibers' aggregates before pulverization of the (a) component] (wherein the ID/IG is calculated from measurement values determined by Raman spectroscopic analysis using 514 nm light of the argon laser) is in the range of 0.7 to 1.5.

Abstract: Carbon fibrous conjunct is provided by adding to carbon fibrous structures, which each comprises a three dimensional network of carbon fibers each having an outside diameter of 15-100 nm, wherein the carbon fibrous structure further comprises a granular part with which the carbon fibers are bound in the state that the carbon fibers extend outwardly from the granular part, a binder for binding the carbon fibrous structures. The fine carbon fibrous structures having such unique configuration and also bearing physical properties suitable for a filler for a composite material can be provided with a good handleability by this carbon fibrous conjunct. Composite material is prepared by adding to the matrix the carbon fibrous conjuncts, at an amount of 0.1 to 30% by weight based on the total weight of the composite material.