Abstract: The disclosure provides a method for preparing a hollow fiber membrane by melt spinning-stretching and selective swelling, including: preparing a nascent hollow fiber by melt spinning in an inert gas protective atmosphere by using an amphiphilic block copolymer as a film forming material, and stretching the nascent hollow fiber in the cooling process, a stretch rate being controlled at 200-540 mm/min, and a stretch ratio being controlled at 150-600%; immersing the obtained hollow fiber in a swelling solvent, and treating the hollow fiber in a water bath at 65° C. for 1 h; and then transferring the hollow fiber into a long-chain alkane solvent, treating the hollow fiber at the same temperature for 1-12 h, and after the completion of the treatment, immediately taking out the hollow fiber and drying the hollow fiber to obtain the hollow fiber membrane with a bicontinuous porous structure.

Abstract: The disclosure provides a method for preparing a hollow fiber membrane by melt spinning-stretching and selective swelling, including: preparing a nascent hollow fiber by melt spinning in an inert gas protective atmosphere by using an amphiphilic block copolymer as a film forming material, and stretching the nascent hollow fiber in the cooling process, a stretch rate being controlled at 200-540 mm/min, and a stretch ratio being controlled at 150-600%; immersing the obtained hollow fiber in a swelling solvent, and treating the hollow fiber in a water bath at 65° C. for 1 h; and then transferring the hollow fiber into a long-chain alkane solvent, treating the hollow fiber at the same temperature for 1-12 h, and after the completion of the treatment, immediately taking out the hollow fiber and drying the hollow fiber to obtain the hollow fiber membrane with a bicontinuous porous structure.

Abstract: The present invention provides a room-temperature selective swelling method of pore-forming used for preparing separation membranes, comprising: treating a dense membrane of an amphiphilic block copolymer by a composite swelling agent at 15-30° C. for 1 min-24 h, removing the residual solvent, then leaving the membrane at room temperature to dry, so as to obtain an amphiphilic block copolymer separation membrane with a bi-continuous porous structure, wherein the composite swelling agent is composed of 60-96% of a first swelling agent and 4-40% of a second swelling agent, the first swelling agent is an alcohol solvent, the second swelling agent is selected from any one or a mixture of two or more of toluene, styrene, tetrahydrofuran, 1,4-dioxane and so on. In the method of the invention, selective swelling can be achieved at room temperature, abating the energy consumption in membrane-forming process.

Abstract: The present invention provides a room-temperature selective swelling method of pore-forming used for preparing separation membranes, comprising: treating a dense membrane of an amphiphilic block copolymer by a composite swelling agent at 15-30° C. for 1 min-24 h, removing the residual solvent, then leaving the membrane at room temperature to dry, so as to obtain an amphiphilic block copolymer separation membrane with a bi-continuous porous structure, wherein the composite swelling agent is composed of 60-96% of a first swelling agent and 4-40% of a second swelling agent, the first swelling agent is an alcohol solvent, the second swelling agent is selected from any one or a mixture of two or more of toluene, styrene, tetrahydrofuran, 1,4-dioxane and so on. In the method of the invention, selective swelling can be achieved at room temperature, abating the energy consumption in membrane-forming process.