Abstract: In one aspect, the present disclosure relates to an improved method of preparing concentrated MnO2 ink with increased efficiency and cost effectiveness. The method involves mixing KMnO4 solution with highly crystalline carbon particles (HCCPs) with average diameters less than 800 nm at 30-60° C. for at least 8 hours. The present disclosure further relates to a symmetric supercapacitor device comprising MnO2 coated electrodes and a solid state ionic liquid as electrolyte, as well as an interdigital transparent SC (IT-SC) device comprising aqueous MnO2 ink.

Abstract: In one aspect, the present disclosure relates to an improved method of preparing concentrated MnO2 ink with increased efficiency and cost effectiveness. The method involves mixing KMnO4 solution with highly crystalline carbon particles (HCCPs) with average diameters less than 800 nm at 30-60° C. for at least 8 hours. The present disclosure further relates to a symmetric supercapacitor device comprising MnO2 coated electrodes and a solid state ionic liquid as electrolyte, as well as an interdigital transparent SC (IT-SC) device comprising aqueous MnO2 ink.

Abstract: Methods are provided for vapor deposition coating of hydrophobic materials and applications thereof. The method for making a hydrophobic material includes providing a natural mineral, providing a silicone-based material, heating the silicone-based material to release vaporous molecules of the silicone-based material, and depositing the vaporous molecules of the silicone-based material to form a layer of the silicone-based material on surfaces of the natural mineral.

Abstract: Methods are provided for vapor deposition coating of hydrophobic materials and applications thereof. The method for making a hydrophobic material includes providing a natural mineral, providing a silicone-based material, heating the silicone-based material to release vaporous molecules of the silicone-based material, and depositing the vaporous molecules of the silicone-based material to form a layer of the silicone-based material on surfaces of the natural mineral.

Abstract: The present invention relates to coated, absorbent, freestanding assemblies comprising inorganic nanowires, articles of manufacture comprising the same, processes of producing the same and methods of use thereof. The assemblies of this invention are useful in various applications, including removal of organics or hydrophobic materials, and waterproofing applications.

Abstract: Methods are provided for vapor deposition coating of hydrophobic materials and applications thereof. The method for making a hydrophobic material includes providing a natural mineral, providing a silicone-based material, heating the silicone-based material to release vaporous molecules of the silicone-based material, and depositing the vaporous molecules of the silicone-based material to form a layer of the silicone-based material on surfaces of the natural mineral.

Abstract: Nanowires, films, and membranes comprising ordered porous manganese oxide-based octahedral molecular sieves and methods of making the same are disclosed. A method for forming nanowires includes hydrothermally treating a chemical precursor composition in a hydrothermal treating solvent to form the nanowires, wherein the chemical precursor composition comprises a source of manganese cations and a source of counter cations, and wherein the nanowires comprise ordered porous manganese oxide-based octahedral molecular sieves.

Abstract: The present invention relates to coated, absorbent, freestanding assemblies comprising inorganic nanowires, articles of manufacture comprising the same, processes of producing the same and methods of use thereof. The assemblies of this invention are useful in various applications, including removal of organics or hydrophobic materials, and waterproofing applications.

Abstract: Nanowires, films, and membranes comprising ordered porous manganese oxide-based octahedral molecular sieves and methods of making the same are disclosed. A method for forming nanowires includes hydrothermally treating a chemical precursor composition in a hydrothermal treating solvent to form the nanowires, wherein the chemical precursor composition comprises a source of manganese cations and a source of counter cations, and wherein the nanowires comprise ordered porous manganese oxide-based octahedral molecular sieves.

Abstract: Nanowires, films, and membranes comprising ordered porous manganese oxide-based octahedral molecular sieves, and methods of making, are disclosed. A single crystal ultra-long nanowire includes an ordered porous manganese oxide-based octahedral molecular sieve, and has an average length greater than about 10 micrometers and an average diameter of about 5 nanometers to about 100 nanometers. A film comprises a microporous network comprising a plurality of single crystal nanowires in the form of a layer, wherein a plurality of layers is stacked on a surface of a substrate, wherein the nanowires of each layer are substantially axially aligned. A free standing membrane comprises a microporous network comprising a plurality of single crystal nanowires in the form of a layer, wherein a plurality of layers is aggregately stacked, and wherein the nanowires of each layer are substantially axially aligned.

Abstract: Nanowires, films, and membranes comprising ordered porous manganese oxide-based octahedral molecular sieves, and methods of making, are disclosed. A single crystal ultra-long nanowire includes an ordered porous manganese oxide-based octahedral molecular sieve, and has an average length greater than about 10 micrometers and an average diameter of about 5 nanometers to about 100 nanometers. A film comprises a microporous network comprising a plurality of single crystal nanowires in the form of a layer, wherein a plurality of layers is stacked on a surface of a substrate, wherein the nanowires of each layer are substantially axially aligned. A free standing membrane comprises a microporous network comprising a plurality of single crystal nanowires in the form of a layer, wherein a plurality of layers is aggregately stacked, and wherein the nanowires of each layer are substantially axially aligned.

Abstract: Processes for making multinary bulk and thin film alloys with nanometer-scale grains are disclosed. An electroless process includes contacting a substrate with a bath within a sealed pressure vessel; and heating the sealed pressure vessel for a time and at a temperature under an autogeneous pressure effective for plating a film of an alloy with nanometer-scale grains onto a contacted portion of the substrate; wherein the bath is formed from one or more salts comprising each constituent element of the alloy, an organic medium, and a reducing agent. The bulk and thin film alloys may be useful in applications requiring high surface area materials or protection from corrosion such as for catalysts and battery cathodes.