Abstract: Provided are methods of modifying the surface stress-activated reactivity of proppant particulates used in subterranean operations. In one embodiment, the methods comprise: providing a plurality of particulates, at least one of which comprises a mineral surface; providing a surface-treating reagent capable of modifying the stress-activated reactivity of a mineral surface of a particulate; and allowing the surface-treating reagent modify the stress-activated reactivity of at least a portion of the mineral surface of at least one particulate. In other embodiments, the methods comprise the use of particulates comprising a modified mineral surface in fluids introduced into subterranean formations.

Abstract: Treating fluid production and subterranean formation treating methods as well as treating fluid compositions that reuse at least part of a prior treating fluid, particularly a fluid having one or more constituents that can be relinked. This includes conditioning a selected at least partially delinked flow-back fluid recovered from a first treating fluid pumped into a well, such that the conditioned selected at least partially delinked flow-back fluid provides a constituent for a second treating fluid. Also included are pricing considerations. A composition for a treating fluid includes a treating fluid residual recovered from a well, preferably a conditioned treating fluid residual. Examples of such compositions include fracturing fluids and gravel pack fluids.

Abstract: Methods that comprise: providing a carrier fluid comprising a delayed breaker; providing a plurality of proppant aggregates comprising a binder fluid and a filler material; suspending the plurality of proppant aggregates in the carrier fluid; introducing the carrier fluid into the subterranean formation at or above a pressure sufficient to create or enhance at least one fracture, the carrier fluid comprising the plurality of proppant aggregates suspended therein; allowing the carrier fluid to break so as to reduce the viscosity of the carrier fluid; and recovering at least a portion of the carrier fluid from the at least one fracture wherein at least a substantial portion of the plurality of proppant aggregates remains in the at least one fracture so as to create a high porosity propped fracture.

Abstract: Provided are methods of modifying the stress-activated reactivity of subterranean fracture faces and other surfaces in subterranean formations. In one embodiment, the methods comprise: providing a treatment fluid that comprises a base fluid and a surface-treating reagent capable of modifying the stress-activated reactivity of a mineral surface in a subterranean formation; introducing the treatment fluid into a subterranean formation; and allowing the surface-treating reagent to modify the stress-activated reactivity of at least a portion of a mineral surface in the subterranean formation.

Abstract: Provided are methods of modifying the surface stress-activated reactivity of proppant particulates used in subterranean operations. In one embodiment, the methods comprise: providing a plurality of particulates, at least one of which comprises a mineral surface; providing a surface-treating reagent capable of modifying the stress-activated reactivity of a mineral surface of a particulate; and allowing the surface-treating reagent modify the stress-activated reactivity of at least a portion of the mineral surface of at least one particulate. In other embodiments, the methods comprise the use of particulates comprising a modified mineral surface in fluids introduced into subterranean formations.

Abstract: A method comprising: providing at least one encaged treatment chemical that comprises a treatment chemical and a polymer carrier; placing the encaged treatment chemical into a portion of a subterranean formation; and allowing the treatment chemical to diffuse out of the encaged treatment chemical and into a portion of the subterranean formation or an area adjacent thereto.

Abstract: One embodiment of the present invention provides a method of treating a subterranean formation comprising: providing a treatment fluid comprising a sulfonated polysaccharide gelling agent wherein the sulfonated polysaccharide gelling agent is produced by reacting a cyclic sultone with a polysaccharide; and, introducing the treatment fluid into a portion of a subterranean formation. Another embodiment provides a method of treating a subterranean formation, comprising: providing a treatment fluid comprising a carboxylated polysaccharide gelling agent wherein the carboxylated polysaccharide gelling agent is produced by reacting a polysaccharide with at least one of the following: a cyclic lactone or a cyclic phosphonate acid; and introducing the treatment fluid into a portion of a subterranean formation. Another embodiment provides a method of derivatizing a polysaccharide comprising reacting a polysaccharide with at least one of the following: a cyclic sultone, a cyclic lactone, or a cyclic phosphonate acid.

Abstract: The present invention relates to high porosity propped fractures and methods of creating high porosity propped fractures in portions of subterranean formations. Another embodiment of the present invention provides a method of forming a high porosity propped fracture in a subterranean formation, comprising providing a slurry comprising a fracturing fluid and proppant particulates coated with an adhesive substance; introducing the slurry into a portion of a fracture within the subterranean formation; and, depositing the proppant particulates into the portion of the fracture within the subterranean formation so as to form a high porosity propped fracture. Another embodiment of the present invention provides a high porosity propped fracture comprising proppant particulates substantially coated with an adhesive substance wherein the propped fracture has a porosity of at least about 50%.

Abstract: Treating fluid production and subterranean formation treating methods as well as compositions for treating fluids reuse at least part of a prior treating fluid, particularly a fluid having one or more constituents that can be relinked. This includes conditioning a selected at least partially delinked flow-back fluid, recovered from a first treating fluid pumped into a well, such that the conditioned selected at least partially delinked flow-back fluid provides a constituent for a second treating fluid. Also included are pricing considerations. A composition for a treating fluid includes a treating fluid residual recovered from a well, preferably conditioned as described. Examples of such fluids include fracturing fluids and gravel pack fluids.

Abstract: Treating fluid production and subterranean formation treating methods as well as compositions for treating fluids reuse at least part of a prior treating fluid, particularly a fluid having one or more constituents that can be relinked. This includes conditioning a selected at least partially delinked flow-back fluid, recovered from a first treating fluid pumped into a well, such that the conditioned selected at least partially delinked flow-back fluid provides a constituent for a second treating fluid. Also included are pricing considerations. A composition for a treating fluid includes a treating fluid residual recovered from a well, preferably conditioned as described. Examples of such fluids include fracturing fluids and gravel pack fluids.

Abstract: This invention is directed to treating fluid production and subterranean formation treating methods as well as compositions for treating fluids that reuse at least part of a prior treating fluid, particularly a fluid having one or more constituents that can be relinked. This includes conditioning a selected at least partially delinked flow-back fluid, recovered from a first treating fluid pumped into a well, such that the conditioned selected at least partially delinked flow-back fluid provides a constituent for a second treating fluid. Also included are pricing considerations. A composition for a treating fluid includes a treating fluid residual recovered from a well, preferably conditioned as described. Examples of such fluids include fracturing fluids and gravel pack fluids.

Abstract: One embodiment of the present invention provides a treatment fluid comprising water, a crosslinking agent, and a substantially fully hydrated depolymerized polymer having a C* of at least about 0.27. Another embodiment of the present invention provides a method of treating a portion of a subterranean formation comprising preparing a treatment fluid comprising water, a crosslinking agent, and a substantially fully hydrated depolymerized polymer having a C* of at least about 0.27; and, contacting the portion of the subterranean formation with the treatment fluid. Another embodiment of the present invention provides a method of fracturing a subterranean formation comprising preparing a treatment fluid comprising water, a crosslinking agent, and a substantially fully hydrated depolymerized polymer having a C* of at least about 0.27; and, placing the treatment fluid into the subterranean formation at a pressure sufficient to create or extend at least one fracture therein.

Abstract: The present invention relates to methods of determining the source of a particular fluid or particulate, and to novel tracer matrixes that may be used in such methods. In one embodiment, the present invention provides a method of detecting particulate or fluid flow from a first location to a second location comprising the steps of: introducing a tracer matrix comprising a polymeric material and a photoactive material to the first location; and detecting the photoactive material at the second location. In another embodiment, the present invention provides a method of detecting flow from a first zone and a second zone in a multizonal well in a subterranean formation comprising the steps of: introducing a first photoactive tracer into the first zone; introducing a second photoactive tracer into the second zone; and detecting the first and the second photoactive tracers in the return flow from the first and second zones.

Abstract: Environmentally safe viscous well treating fluids and methods are provided by the present invention. The treating fluids are basically comprised of water, a viscosity producing polymer, a boron cross-linking agent for cross-linking the polymer, and a delayed cross-link delinker that comprises polysuccinimide and polyaspartic acid.

Abstract: Improved methods of coating dry proppant particles with a hardenable resin composition, suspending the coated proppant particles in a fracturing fluid and consolidating the proppant particles after being placed in fractures into high strength permeable masses are provided. As the fractures are formed, a liquid hardenable resin component is mixed with a liquid hardening agent component to form a hardenable resin composition. The hardenable resin composition is coated onto dry proppant particles conveyed from a source thereof to form resin composition coated proppant particles, and the resin composition coated proppant particles are suspended in the fracturing fluid.

Abstract: Treating fluid production and subterranean formation treating methods as well as compositions for treating fluids reuse at least part of a prior treating fluid, particularly a fluid having one or more constituents that can be relinked. This includes conditioning a selected at least partially delinked flow-back fluid, recovered from a first treating fluid pumped into a well, such that the conditioned selected at least partially delinked flow-back fluid provides a constituent for a second treating fluid. Also included are pricing considerations. A composition for a treating fluid includes a treating fluid residual recovered from a well, preferably conditioned as described. Examples of such fluids include fracturing fluids and gravel pack fluids.

Abstract: Improved methods of coating dry proppant particles with a hardenable resin composition, suspending the coated proppant particles in a fracturing fluid and consolidating the proppant particles after being placed in fractures into high strength permeable masses are provided. As the fractures are formed, a liquid hardenable resin component is mixed with a liquid hardening agent component to form a hardenable resin composition. The hardenable resin composition is coated onto dry proppant particles conveyed from a source thereof to form resin composition coated proppant particles, and the resin composition coated proppant particles are suspended in the fracturing fluid.

Abstract: Methods and compositions for removing gelled and dehydrated drilling fluid and filter cake from the walls of wellbores are provided. The methods basically include contacting the drilling fluid and filter cake with a removal composition comprised of an aqueous sugar solution for a period of time sufficient to cause the disintegration of the drilling fluid and filter cake. The composition, having the disintegrated drilling fluid and filter cake dispersed therein, is then displaced from the wellbore.