Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.

Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.

Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.

Abstract: A gas separation and detection tool for performing in situ analysis of borehole fluid is described. The tool operates by introducing a reagent to a test sample and causing the resulting mixture to flow through a microfluidic channel where optical testing is performed. The optical testing detects a change in a characteristic of the reagent in response to expose to one or more particular substances in the test sample. The test sample may be borehole fluid, a mixture of borehole fluid and scrubbing fluid subsequently mixed with reagent, a mixture of reagent and gas separated from borehole fluid, or a mixture of scrubbing fluid and gas separated from borehole fluid which is subsequently mixed with reagent. A membrane may be employed to separate one or more target gasses from the borehole fluid.

Abstract: Embodiments of the present invention provide systems and methods for detection and/or measurement of gaseous components of multiphase mixtures containing one or more hydrocarbons that may be retrieved down a wellbore or may be being transported in a pipeline. More specifically, but not by way of limitation, embodiments of the present invention may provide for separation of the gaseous components from the multiphase mixtures and detection and/or measurement of the separated gaseous components by direct oxidation or reduction.

Abstract: A gas separation and detection tool for performing in situ analysis of borehole fluid is described. A separation system such as a membrane is employed to separate one or more target gasses from the borehole fluid. The separated gas may be detected by reaction with another material or spectroscopy. When spectroscopy is employed, a test chamber defined by a housing is used to hold the gas undergoing test. Various techniques may be employed to protect the gas separation system from damage due to pressure differential. For example, a separation membrane may be integrated with layers that provide strength and rigidity. The integrated membrane separation may include one or more of a water impermeable layer, gas selective layer, inorganic base layer and metal support layer. The gas selective layer itself can also function as a water impermeable layer. The metal support layer enhances resistance to differential pressure. Alternatively, the chamber may be filled with a liquid or solid material.

Abstract: Methods and related apparatuses and mixtures are described for detecting hydrogen sulfide in a formation fluid downhole. A detection mixture is combined with the formation fluid downhole. The detection mixture includes metal ions for reacting with hydrogen sulfide forming a metal sulfide, and charged nanoparticles sized so as to inhibit significant aggregation of the metal sulfide so as to enable spectroscopic detection of the metal sulfide downhole. The combined mixture and formation fluid is then spectroscopically interrogated so as to detect the presence of the metal sulfide thereby indicating the presence of hydrogen sulfide in the formation fluid. The mixture also includes chelating ligands for sustaining thermal endurance of the mixture under downhole conditions.

Abstract: An electrochemical sensor for measuring contents of a fluid or gas at high pressure and/or high temperature, for use, for example, in a wellbore for hydrocarbon applications, is provided. The sensor includes: a bulkhead-like electrode assembly including a cylindrical housing and a cylindrical electrode structure. The cylindrical electrode structure includes a cylindrical conductive pin extending from a high pressure region to a low pressure region and an electrode connected to one end of the pin at the high pressure region and having an electrode surface for exposure to a flow path of the fluid or gas in the high pressure region. At least a part of the surface of the pin is protected from direct contact with the fluid or the gas by an insulating coating impermeable to the fluid or gas. The pin may include an alternating pattern of protruding and receded portions.

Abstract: An electrochemical sensor for measuring contents of a fluid or gas at high pressure and/or high temperature, for use, for example, in a wellbore for hydrocarbon applications, is provided. The sensor includes: a bulkhead-like electrode assembly including a cylindrical housing and a cylindrical electrode structure. The cylindrical electrode structure includes a cylindrical conductive pin extending from a high pressure region to a low pressure region and an electrode connected to one end of the pin at the high pressure region and having an electrode surface for exposure to a flow path of the fluid or gas in the high pressure region. At least a part of the surface of the pin is protected from direct contact with the fluid or the gas by an insulating coating impermeable to the fluid or gas. The pin may include an alternating pattern of protruding and receded portions.

Abstract: The present invention generally relates to a method and apparatus for connecting a first tubular with a second tubular. The apparatus includes a gripping member for engaging the first tubular and a conveying member for positioning the gripping member. The apparatus also includes a spinner for rotating the first tubular. In one embodiment, the spinner includes a motor and one or more rotational members for engaging the first tubular. In another embodiment, the apparatus includes a rotation counting member biased against the first tubular. In another aspect, the present invention provides a method of connecting a first tubular to second tubular. The method includes engaging the first tubular using a gripping member connected to a conveying member and positioning the gripping member to align the first tubular with the second tubular. Thereafter, the first tubular is engaged with the second tubular, and the first tubular is rotated relative to the second tubular using the gripping member.

Abstract: A pressure transducer for high-pressure measurements comprising a housing and a piezoelectric resonator located in the housing, wherein the resonator comprises double rotation cut piezoelectric material configured or designed for vibrating in the fundamental tone of dual modes of the fast and slow thickness-shear vibrations.

Abstract: The present invention provides a hydrocarbon-based polymer for use in an electrolyte membrane of a fuel cell having high durability, an electrolyte membrane of a fuel cell using the polymer, a fuel cell using the electrolyte membrane.

Abstract: An apparatus is provided with position sensors. When the apparatus has moved one tubular into alignment with another tubular a button on a remote control console is pressed to memorize the position. After the next tubular has been gripped by the apparatus a “recall” button is pressed and the apparatus automatically moves the next tubular to the memorized position. This saves vital seconds in joining tubulars and also reduces the likelihood of threads being damaged due to misalignment of the tubulars.

Abstract: An apparatus is provided with position sensors. When the apparatus has moved one tubular into alignment with another tubular a button on a remote control console is pressed to memorise the position. After the next tubular has been gripped by the apparatus a “recall” button is pressed and the apparatus automatically moves the next tubular to the memorised position. This saves vital seconds in joining tubulars and also reduces the likelihood of threads being damaged due to misalignment of the tubulars.

Abstract: There is provided a method of testing a joint formed by bonding of two tubulars, which method comprises the steps of holding a first tubular; applying a force to displace a second tubular relative to the first tubular; and removing the force. The final position of the second tubular is then compared with the position which it occupied prior to the application of the force by means of a sensor mounted remotely from the second tubular.

Abstract: An apparatus is provided with position sensors. When the apparatus has moved one tubular into alignment with another tubular a button on a remote control console is pressed to memorize the position. After the next tubular has been gripped by the apparatus a “recall” button is pressed and the apparatus automatically moves the next tubular to the memorized position. This saves vital seconds in joining tubulars and also reduces the likelihood of threads being damaged due to misalignment of the tubulars.