Abstract: A composite material comprising a plurality of hard particles surrounded by a matrix material comprising a plurality of nanoparticles. Earth boring tools including the composite material and methods of forming the composite material are also disclosed. A polycrystalline material having a catalyst material including nanoparticles in interstitial spaces between inter-bonded crystals of the polycrystalline material and methods of forming the polycrystalline material are also disclosed.

Abstract: Hardfacing materials include a polymer matrix material and particles of hard material embedded within and dispersed throughout the polymer matrix material. Earth-boring tools include a tool body and a hardfacing material on at least a portion of a surface of the body, wherein the hardfacing material includes a polymer matrix material and particles of hard material embedded within and dispersed throughout the polymer matrix material. Methods of applying hardfacing material to an earth-boring tool comprise mixing hard particles with a polymer precursor material to form a paste, applying the paste to a surface of an earth-boring tool, and curing the polymer precursor material to form a hardfacing material on the surface of the earth-boring tool.

Abstract: A multi-layer film for use in forming a layer of hardfacing on a surface of a tool includes a first layer and a second layer covering at least a portion of a surface of the first layer. The layers each include a polymer material and a plurality of particles dispersed throughout the polymer material. An intermediate structure includes a body of an earth-boring tool, a first material layer disposed over a surface of the body, and a second material layer disposed over the first material layer. A method of applying hardfacing includes providing a first material layer on a surface of a body of an earth-boring tool, providing a second material layer adjacent the first material layer, heating the body and removing the polymer material from the body of the earth-boring tool, and heating the body of the earth-boring tool to a higher temperature to form a layer of hardfacing material.

Abstract: A composite material comprising a plurality of hard particles surrounded by a matrix material comprising a plurality of nanoparticles. Earth boring tools including the composite material and methods of forming the composite material are also disclosed. A polycrystalline material having a catalyst material including nanoparticles in interstitial spaces between inter-bonded crystals of the polycrystalline material and methods of forming the polycrystalline material are also disclosed.

Abstract: Binder compositions for use in forming a bit body of an earth-boring bit include at least one of cobalt, nickel, and iron, and at least one melting point-reducing constituent selected from at least one of a transition metal carbide up to 60 weight percent, a transition metal boride up to 60 weight percent, and a transition metal silicide up to 60 weight percent, wherein the weight percentages are based on the total weight of the binder. Earth-boring bit bodies include a cemented tungsten carbide material comprising tungsten carbide and a metallic binder, wherein the tungsten carbide comprises greater than 75 volume percent of the cemented tungsten carbide material.

Abstract: Hardfacing materials include a polymer matrix material and particles of hard material embedded within and dispersed throughout the polymer matrix material. Earth-boring tools include a tool body and a hardfacing material on at least a portion of a surface of the body, wherein the hardfacing material includes a polymer matrix material and particles of hard material embedded within and dispersed throughout the polymer matrix material. Methods of applying hardfacing material to an earth-boring tool comprise mixing hard particles with a polymer precursor material to form a paste, applying the paste to a surface of an earth-boring tool, and curing the polymer precursor material to form a hardfacing material on the surface of the earth-boring tool.

Abstract: A composite material comprising a plurality of hard particles surrounded by a matrix material comprising a plurality of nanoparticles. Earth boring tools including the composite material and methods of forming the composite material are also disclosed. A polycrystalline material having a catalyst material including nanoparticles in interstitial spaces between inter-bonded crystals of the polycrystalline material and methods of forming the polycrystalline material are also disclosed.

Abstract: Methods of fabricating bodies of earth-boring tools include mechanically injecting a powder mixture into a mold cavity, pressurizing the powder mixture within the mold cavity to form a green body, and sintering the green body to a desired final density to form at least a portion of a body of an earth-boring tool. For example, a green bit body may be injection molded, and the green bit body may be sintered to form at least a portion of a bit body of an earth-boring rotary drill bit. Intermediate structures formed during fabrication of an earth-boring tool include green bodies having a plurality of hard particles, a plurality of matrix particles comprising a metal matrix material, and an organic material that includes a long chain fatty acid derivative. Structures formed using the methods of fabrication are also disclosed.

Abstract: A component for a downhole tool includes a rotor and a hardfacing precursor. The hardfacing precursor includes a polymeric material, hard particles, and a metal. A hydraulic drilling motor includes a stator, a rotor, and a sintered hardfacing material on an outer surface of the rotor or an inner surface of the stator. Methods of applying hardfacing to surfaces include forming a paste of hard particles, metal matrix particles, a polymeric material, and a solvent. The solvent is removed from the paste to form a sheet, which is applied to a surface and heated. A component for a downhole tool includes a first hardfacing material, a second hardfacing material over the first hardfacing material and defining a plurality of pores, and a metal disposed within at least some of the pores. The metal has a melting point lower than a melting point of the second hardfacing material.

Abstract: A method of boriding a metal comprises forming a molten electrolyte comprising between about five weight percent and about fifty weight percent boron oxide, and contacting at least a portion of a metal with the molten electrolyte. Electrical current is applied to at least a portion of the metal while maintaining a temperature of the molten electrolyte below about 700° C. to diffuse boron atoms from the molten electrolyte into a surface of the at least a portion of the metal. A downhole tool including at least one borided component is also disclosed.

Abstract: Coupling members for coupling an earth-boring drill tool to a drill string, drilling tools including a coupling member attached to a body of an earth-boring drill tool, methods for forming drilling tools including a coupling member, and methods for forming coupling members are disclosed. A coupling member may include a distal region comprising a first material composition and a proximal region comprising a second, different material composition. A drilling tool may include a body that is attached to a coupling member with a varied material composition for coupling the body to a drill string.

Abstract: Articles comprising at least a portion of an earth-boring tool include at least one insert and a solidified eutectic or near-eutectic composition including a metal phase and a hard material phase. Other articles include a solidified eutectic or near-eutectic composition including a metal phase, a hard material phase and a coating material in contact with the solidified eutectic or near-eutectic composition.

Abstract: Articles comprising at least a portion of an earth-boring tool include at least one insert and a solidified eutectic or near-eutectic composition including a metal phase and a hard material phase. Other articles include a solidified eutectic or near-eutectic composition including a metal phase, a hard material phase and a coating material in contact with the solidified eutectic or near-eutectic composition.

Abstract: Binder compositions for use in forming a bit body of an earth-boring bit include at least one of cobalt, nickel, and iron, and at least one melting point-reducing constituent selected from at least one of a transition metal carbide up to 60 weight percent, a transition metal boride up to 60 weight percent, and a transition metal silicide up to 60 weight percent, wherein the weight percentages are based on the total weight of the binder. Earth-boring bit bodies include a cemented tungsten carbide material comprising tungsten carbide and a metallic binder, wherein the tungsten carbide comprises greater than 75 volume percent of the cemented tungsten carbide material.

Abstract: Binder compositions for use in forming a bit body of an earth-boring bit include at least one of cobalt, nickel, and iron, and at least one melting point-reducing constituent selected from at least one of a transition metal carbide up to 60 weight percent, a transition metal boride up to 60 weight percent, and a transition metal silicide up to 60 weight percent, wherein the weight percentages are based on the total weight of the binder. Earth-boring bit bodies include a cemented tungsten carbide material comprising tungsten carbide and a metallic binder, wherein the tungsten carbide comprises greater than 75 volume percent of the cemented tungsten carbide material.

Abstract: Binder compositions for use in forming a bit body of an earth-boring bit include at least one of cobalt, nickel, and iron, and at least one melting point-reducing constituent selected from at least one of a transition metal carbide up to 60 weight percent, a transition metal boride up to 60 weight percent, and a transition metal silicide up to 60 weight percent, wherein the weight percentages are based on the total weight of the binder. Earth-boring bit bodies include a cemented tungsten carbide material comprising tungsten carbide and a metallic binder, wherein the tungsten carbide comprises greater than 75 volume percent of the cemented tungsten carbide material.

Abstract: A method of boriding a metal comprises forming a molten electrolyte comprising between about five weight percent and about fifty weight percent boron oxide, and contacting at least a portion of a metal with the molten electrolyte. Electrical current is applied to at least a portion of the metal while maintaining a temperature of the molten electrolyte below about 700° C. to diffuse boron atoms from the molten electrolyte into a surface of the at least a portion of the metal. A downhole tool including at least one borided component is also disclosed.

Abstract: Hardfacing compositions include grains of hard material embedded within a cobalt-based metal alloy that includes ruthenium. Earth-boring tools include such hardfacing compositions on one or more surfaces thereof. Methods of applying hardfacing to an earth-boring tool include embedding grains of hard material in a molten cobalt-based metal alloy including ruthenium on a surface of an earth-boring tool, and cooling and solidifying the molten cobalt-based metal alloy with the grains of hard material embedded therein.

Abstract: Methods of fabricating earth-boring tools include forming an outer portion of an earth-boring tool from a powder mixture comprising hard particles and matrix particles comprising a metal matrix material, disposing a molten material at least partially within the outer portion of the earth-boring tool, and forming the molten material into another portion of the earth-boring tool. Methods of fabricating a bit body of an earth-boring rotary drill bit include forming an outer portion comprising a plurality of hard particles and a plurality of matrix particles comprising a metal matrix material and casting a molten material at least partially within the outer portion of the bit body to form another portion of the bit body. Earth-boring tools include a body for engaging a subterranean borehole having an outer portion and an inner portion comprising at least one material solidified within a cavity formed within the outer portion.

Abstract: A method for applying a non-magnetic, abrasive, wear-resistant hardfacing material to a surface of a drill string member includes providing a non-magnetic drill string member formed of a non-magnetic material, the drill string member having an outer surface. It also includes providing a non-magnetic hardfacing precursor material comprising a plurality of non-magnetic, sintered carbide pellets and a non-magnetic matrix material; heating a portion of the non-magnetic hardfacing precursor material to a temperature above the melting point of the matrix material to melt the matrix material. It further includes applying the molten non-magnetic matrix material and the plurality of non-magnetic, sintered carbide pellets to the exterior surface of the drill string member; and solidifying the molten non-magnetic matrix material to form a layer of a non-magnetic hardfacing material having a plurality of non-magnetic, sintered carbide pellets dispersed in the hardfacing material.